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Reforming hydrogen production reactor, conversion furnace, and reforming hydrogen production reaction method

A reforming hydrogen production and reactor technology, applied in chemical instruments and methods, hydrogen, inorganic chemistry, etc., can solve the problems of increasing the energy consumption of the raw gas compressor, increasing the number of catalyst active centers, and the catalyst being prone to carbon deposition and deactivation. , to achieve the effect of total reduction, long service life, and not easy carbon deposition and inactivation

Active Publication Date: 2019-04-30
SINOPEC ENG +1
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  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The existing hydrogen production conversion furnace is filled with a nickel-based catalyst of a certain particle size and shape in the furnace tube, which often causes uneven loading, causing the raw material gas to drift, resulting in a low conversion rate of the raw material, and the catalyst is prone to carbon deposition and deactivation. operating cycle
In addition, the catalyst with smaller particle size is loaded in the furnace tube, although it can increase the loading amount of the catalyst, increase the number of catalyst active centers, and improve the processing capacity and conversion rate of raw materials to a certain extent, the disadvantage is that the smaller the catalyst size, the furnace The larger the pipe pressure drop, the higher the energy consumption of the feed gas compressor

Method used

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  • Reforming hydrogen production reactor, conversion furnace, and reforming hydrogen production reaction method
  • Reforming hydrogen production reactor, conversion furnace, and reforming hydrogen production reaction method
  • Reforming hydrogen production reactor, conversion furnace, and reforming hydrogen production reaction method

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Embodiment 1

[0091] like figure 1 , figure 2 , image 3 As shown, the reforming hydrogen production reactor adopted in this embodiment includes a pressure-bearing shell 12 comprising a first straight pipe 11 and a second straight pipe 14 at the lower end. 19×1000mm heat exchange tubes 6 constitute a heat exchange area 15 (not all shown in the figure) and a catalytic reaction area 13, the first straight pipe 11 is provided with an air inlet 1, and the lower part of the second straight pipe 14 is provided with an air outlet 2. The catalytic reaction zone is composed of a flat micro-catalytic reaction plate 10, the angle between the flat plate and the horizontal direction is 90°, the micro-catalytic reaction plate 10 is spirally distributed around the central tube, the central tube 6, the catalytic reaction zone 13, the heat exchange zone 15 and the The housing 12 is coaxially arranged; the micro-catalytic reaction plate 10 of the catalytic reaction zone 13 is connected and fixed with th...

Embodiment 2

[0102] like Figure 4 , Figure 5 , image 3 As shown, the reforming hydrogen production reactor and the reforming furnace of the present embodiment are the same as the reactor size of the embodiment 1, the distance between two adjacent catalytic reaction plates, the distance between the annular gaps, the substrate material of the micro-reaction plate and the active component per unit area NiO The payload parameters are the same. The difference from Example 1 is that the micro-catalysis reaction plate 10 of the present embodiment takes the central tube 6 as the center of a circle, and the micro-catalysis reaction plate 10 is radially and evenly arranged around the central tube 6, and the micro-catalysis reaction plate 10 is respectively placed on the top of the catalytic reaction zone. The sealing plate 5 and the sealing plate 8 at the bottom of the catalytic reaction zone are connected and fixed. The reforming hydrogen production reactor and reformer of this embodiment are...

Embodiment 3

[0107] like Image 6 , Figure 7 , image 3 As shown, the reforming hydrogen production reactor and the reforming furnace of the present embodiment are the same as the reactor size of the embodiment 2, the distance between two adjacent catalytic reaction plates, the distance between the ring gaps, the matrix material of the micro-reaction plate and the active component NiO per unit area. The payload parameters are the same. The difference from Example 1 is that the micro-catalytic reaction plate 10 is cylindrical and includes an upper catalytic reaction plate and a lower catalytic reaction plate coaxially arranged alternately at intervals, and the micro-catalytic reaction plate 10 is in the same shape as the housing 12 and the central tube 6. The axis is set, the upper micro catalytic reaction plate is vertically sealed and fixed with the top sealing plate 5 of the catalytic reaction zone, and the lower micro catalytic reaction plate is vertically sealed and fixed with the b...

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Abstract

The present invention relates to a reforming hydrogen production reactor, a conversion furnace, and a reforming hydrogen production reaction method. According to the present invention, the reforming hydrogen production reactor and the conversion furnace adopt micro-catalytic reaction plates, wherein a catalytic active component is loaded on the reaction plate, such that the consumption of catalytic active metals is reduced, the catalyst is not easily subjected to carbon deposition deactivation, the diffusion distance of the reaction gas to the catalytic active center is shortened, the mass transfer resistance and the pressure drop of the reactor are reduced, and the conversion rate of the hydrogen production reaction is increased; the reaction gas flows outward from the center in the reactor, the flow channel area is gradually increased, and the temperature of the reaction plate is gradually increased, such that the conversion rate of the hydrogen production reaction as volume increaseand endothermic reaction is easily increased; the heat exchange zone is arranged in the reforming reactor, such that the temperature of the raw material gas entering the reaction zone is increased, the temperature of the product at the outlet of the reactor is reduced, the reaction rate is easily improved, and the material requirements on the downstream pipelines and equipment are easily reduced;and the reforming hydrogen production reactor has wide use range, and the furnace tube as the hydrogen production conversion furnace can be used for different types of conversion furnaces.

Description

technical field [0001] The disclosure relates to the field of reforming hydrogen production, and in particular, to a reforming hydrogen production reactor, a reformer, and a method for reforming hydrogen production reaction. Background technique [0002] Hydrogen is not only an important chemical raw material, but also a clean fuel. Hydrogen plays an increasingly important role in modern industry, especially petrochemical industry, fuel cell and other national economies. Under the multiple pressures of increasing crude oil quality and inferior quality in the world, increasing demand for clean oil products, continuously improving quality standards, and increasingly stringent environmental regulations, the demand for hydrogen is also increasing, and the demand for hydrogen production is also increasing. Devices also put forward higher requirements. [0003] Hydrogen production processes mainly include water electrolysis, light hydrocarbon steam reforming, partial oxidation a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B3/40
CPCC01B3/40C01B2203/0233C01B2203/0811C01B2203/1035C01B2203/1047C01B2203/1058C01B2203/1235C01B2203/1241
Inventor 张旭戴文松蒋荣兴
Owner SINOPEC ENG
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