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A method for preparing strontium-rich activated carbon by hydrothermal method

A technology of activated carbon and strontium-enriched technology, which is applied in the field of deep processing and preparation of activated carbon, can solve the problems of weak combination of active components and carriers, blockage of active component microcrystals, and reduced pore volume, so as to achieve the goal of increasing added value and reducing production costs Effect

Active Publication Date: 2020-12-29
XIAMEN QUANJIALE NEW MATERIAL TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The strontium-loaded activated carbon prepared by impregnation, co-precipitation and other modification methods has problems such as active component crystallites blocking the micropores, reducing pore volume and adsorption capacity; the active component and the carrier are not firmly combined and easy to fall off.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0021] 1. Preparation of strontium-rich activated carbon by impregnation-hydrothermal method, including the following steps:

[0022] (a) Preprocessing process:

[0023] Place the proportioned activated carbon in a hydrochloric acid solution with a concentration of (4-10) wt% and heat while stirring, heat and boil the charcoal for 30-60 minutes, let it stand for 0.5 hours, then filter it with suction, and then wash the proportioned activated carbon repeatedly with pure water , Wash off the residual acid on the surface, boil it with pure water for 0.5-1 hour, rinse until the pH value is 6.5-8.5, and finally dry it at 105-120°C for use.

[0024] (b) Dip loading process:

[0025] Take an appropriate amount of activated carbon after pretreatment, place it in an excess sodium silicate solution with a concentration of 0.1-0.3 mol / L, immerse and stir for 10-20 minutes, and then add a strontium salt solution with a concentration of 0.05-0.5 mol / L in the impregnation solution, Mix an...

example 1

[0033] Take by weight 50 g of proportioning activated carbon above 150 mesh, and the mass proportioning ratio is 3:2. Place in a 3L beaker, slowly add 70g of diluted edible hydrochloric acid with a concentration of 4wt% into it while stirring, after stirring for 10 minutes, start heating, stir while heating, until the activated carbon solution boils for 40 minutes, and then suction filter after cooling for 0.5 hours. Then use pure water to wash the activated carbon repeatedly to remove the residual acid on the surface; then boil it with pure water for 0.5 hours, filter and rinse until the pH value is 6.5-8.5, that is, complete the process of hydrochloric acid deashing, and finally in the Dry at 105-120°C for later use.

[0034] Weigh 4 g of proportioned activated carbon after hydrochloric acid impurity removal pretreatment, place it in 600 mL of sodium silicate solution with a concentration of 0.2 mol / L and stir for 10 minutes, and then add 150 mL of chlorine with a concentrat...

example 2

[0037] Take by weight 50 g of proportioning activated carbon above 150 mesh, and the mass proportioning ratio is 3:2. Place in a 3L beaker, slowly add 70g of diluted edible hydrochloric acid with a concentration of 4wt% into it while stirring, after stirring for 10 minutes, start heating, stir while heating, until the activated carbon solution boils for 40 minutes, and then suction filter after cooling for 0.5 hours. Then use pure water to wash the activated carbon repeatedly to remove the residual acid on the surface; then boil it with pure water for 0.5 hours, filter and rinse until the pH value is 6.5-8.5, that is, complete the process of hydrochloric acid deashing, and finally in the Dry at 105-120°C for later use.

[0038] Weigh 4 g of proportioned activated carbon after hydrochloric acid impurity removal pretreatment, place it in 600 mL of sodium silicate solution with a concentration of 0.2 mol / L and stir for 10 minutes, and then add 150 mL of chlorine with a concentrat...

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PUM

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Abstract

The invention discloses a method for preparing strontium-rich activated carbon by the aid of hydrothermal processes. The method includes steps of a), pretreating activated carbon, to be more specific,placing the proportioned activated carbon in diluted edible hydrochloric acid solution, heating the proportioned activated carbon in the diluted edible hydrochloric acid solution, carrying out impurity removal cleaning, further carrying out suction filtration, repeatedly washing the activated carbon, washing off surface residual acid liquid, boiling the activated carbon by water, then repeatedlyrinsing the activated carbon until the pH (potential of hydrogen) value of the activated carbon is 6.5-8.5, placing the activated carbon in drying ovens and drying the activated carbon for standby application; b), impregnating and loading strontium salt, to be more specific, slowly adding the pretreated proportioned activated carbon into impregnation liquid with diffusing agents and coupling agents, impregnating and stirring the activated carbon for 10 min, then adding strontium salt solution into the impregnation liquid and uniformly mixing and stirring the strontium salt solution and the activated carbon with each other in the impregnation liquid; c), carrying out hydrothermal reaction procedures, to be more specific, placing impregnated activated carbon solution in hydrothermal reactionkettles, keeping the temperatures constant for 2-6 hours after the hydrothermal reaction temperatures are increased and reach 130-250 DEG C and the pressures of the reaction kettles reach approximately 1MPa, carrying out still standing and temperature reduction after reaction is completely carried out, carrying suction filtration and cleaning, washing off surface residual impregnation liquid, then placing reaction products in drying ovens, and drying the reaction products at the temperatures of 120-150 DEGC to obtain the impregnated-hydrothermal strontium-rich activated carbon.

Description

technical field [0001] The invention belongs to the technical field of deep processing and preparation of activated carbon and its application. It specifically relates to the application of strontium-rich activated carbon in the field of drinking water. Background technique [0002] It is well known that water is the most important component of the human body, yet its nutritional contribution to the human body has often been overlooked over the years. Natural water contains calcium, magnesium, sodium, potassium, bicarbonate, sulfate, silicon, zinc, iodine, fluorine, chromium, lithium, molybdenum, selenium, cobalt, vanadium and other soluble mineral ions, which are biologically usable It is a good source of high-quality minerals, so drinking an appropriate amount of natural mineral water is good for the body, and can supplement some trace elements for the human body. An appropriate amount of the mineral element strontium is beneficial to human health. Strontium can regulate...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01B32/354C02F1/68
CPCC02F1/68C01B32/354
Inventor 蒋俊勇李培政汪印李智伟
Owner XIAMEN QUANJIALE NEW MATERIAL TECH CO LTD
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