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A kind of high-efficiency reinforced flame-retardant functional masterbatch for direct injection molding of polypropylene and preparation method thereof

An injection molding and functional masterbatch technology, which is applied in the field of high-efficiency reinforced flame-retardant functional masterbatch and its preparation, can solve the problems of mutual loss of modification performance, etc., and achieve improved interface adhesion, enhanced reinforcement efficiency, and large fiber length. The effect of diameter ratio

Active Publication Date: 2021-11-12
江苏万纳普新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In order to solve the problem of mutual loss of modification performance existing in the preparation process of existing glass fiber reinforced flame retardant polypropylene special materials, the present invention provides a high-efficiency enhanced flame retardant functional masterbatch that can be directly applied to injection molding processing of polypropylene plastic products and its preparation method

Method used

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  • A kind of high-efficiency reinforced flame-retardant functional masterbatch for direct injection molding of polypropylene and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] A high-efficiency reinforced flame-retardant functional masterbatch for polypropylene direct injection molding, including A masterbatch and B masterbatch, and the raw material quality ratio of the A masterbatch is as follows:

[0036] glass fiber 70.0 kg High Flow Polypropylene 15.0kg Sodium ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 8.0 kg Atactic polypropylene 4.0 kg Maleic anhydride grafted polypropylene 1.0 kg PTFE powder 1.7kg antioxidant 300.0 g

[0037] The antioxidant is preferably triethylene glycol bis-β-(3-tert-butyl-4-hydroxyl-5-methylphenyl) propionate (trade name Antioxidant 245) and bis(2,4-di-tert Butylphenyl) pentaerythritol diphosphite (trade name: Antioxidant 626) is a compound composed of 1:1 mass ratio.

[0038] The mass ratio of the raw materials of the B masterbatch is as follows:

[0039] Decabromodiphenylethane 40.0 kg Ethyl-bis(tetrabromophthalimide) ...

Embodiment 2

[0043] A high-efficiency reinforced flame-retardant functional masterbatch for polypropylene direct injection molding, including A masterbatch and B masterbatch, and the raw material quality ratio of the A masterbatch is as follows:

[0044] glass fiber 50.0kg High Flow Polypropylene 35.0kg Zinc ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 7.0kg Atactic polypropylene 5.0 kg Maleic anhydride grafted polypropylene 1.5 kg PTFE powder 1.2kg antioxidant 300.0 g

[0045] The antioxidant is preferably triethylene glycol bis-β-(3-tert-butyl-4-hydroxyl-5-methylphenyl) propionate (trade name Antioxidant 245) and bis(2,4-di-tert Butylphenyl) pentaerythritol diphosphite (trade name: Antioxidant 626) is a compound composed of 1:1 mass ratio.

[0046] The mass ratio of the raw materials of the B masterbatch is as follows:

[0047] Decabromodiphenylethane 35.0kg brominated polystyrene 20.0kg A...

Embodiment 3

[0051] A high-efficiency reinforced flame-retardant functional masterbatch for polypropylene direct injection molding, including A masterbatch and B masterbatch, and the raw material quality ratio of the A masterbatch is as follows:

[0052] glass fiber 60.0 kg High Flow Polypropylene 28.0kg Calcium ion crosslinked ethylene–acrylic acid copolymer elastic ionomer 5.7kg Atactic polypropylene 3.0 kg Maleic anhydride grafted polypropylene 2.0 kg PTFE powder 1.0 kg antioxidant 300.0 g

[0053] The antioxidant is preferably triethylene glycol bis-β-(3-tert-butyl-4-hydroxyl-5-methylphenyl) propionate (trade name Antioxidant 245) and bis(2,4-di-tert Butylphenyl) pentaerythritol diphosphite (trade name: Antioxidant 626) is a compound composed of 1:1 mass ratio.

[0054] The mass ratio of the raw materials of the B masterbatch is as follows:

[0055] Decabromodiphenylethane 40.0 kg Ethyl-bis(tetrabromophthalimide)...

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Abstract

The invention belongs to the technical field of plastic modification and processing, and in particular relates to a high-efficiency enhanced flame-retardant functional masterbatch which can be directly applied to injection molding processing of polypropylene products and a preparation method thereof; The mass percentage composition of A masterbatch is as follows: glass fiber 50.0-70.0 wt.%, high-flow polypropylene 15.0-35.0 wt.%, elastic ionomer 5.0-10.0 wt.%, atactic polypropylene 3.0 ~6.0 wt.%, maleic anhydride grafted polypropylene 1.0~3.0 wt.%, polytetrafluoroethylene powder 1.0~3.0 wt.%, antioxidant 0.1~0.3 wt.%; the functional masterbatch of the present invention has It is easy to disperse and process, and can be simply mixed with polypropylene resin according to the ratio and then injection molded.

Description

technical field [0001] The invention belongs to the technical field of plastic modification and processing, and in particular relates to a high-efficiency enhanced flame-retardant functional masterbatch which can be directly applied to injection molding processing of polypropylene products and a preparation method thereof. Background technique [0002] Using twin-screw extruder to implement melt blending is a traditional method for plastic modification. Using the high-efficiency and excellent mixing performance of co-rotating twin-screw extruders, thermoplastics and various modified additives can be continuously melt-blended and extruded After granulation, the prepared modified special material will be used again for injection or extrusion processing to form various products. This technical route not only effectively improves the physical and mechanical properties of plastic products such as strength, toughness, stiffness, creep resistance, and flexure resistance, but also e...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/26C08L51/06C08L27/18C08L23/06C08L83/04C08K13/04C08K7/14C08K5/134C08K5/526C08K5/09C08K5/20C08K5/03C08K3/22C08K3/38C08J3/22
CPCC08J3/226C08J2323/12C08J2423/06C08J2423/26C08J2427/18C08J2451/06C08J2483/04C08K3/2279C08K5/03C08K5/09C08K5/1345C08K5/20C08K5/526C08K7/14C08K13/04C08K2003/387
Inventor 李翰卿汪晓东孙艳军邱小龙曹津津
Owner 江苏万纳普新材料科技有限公司
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