Porous spherical adsorbent for printing and dyeing sewage treatment and preparation method thereof
A printing and dyeing sewage and adsorbent technology, which is applied in water/sewage treatment, adsorption water/sewage treatment, water/sludge/sewage treatment, etc., can solve the problems such as poor treatment effect of printing and dyeing sewage and cannot meet the actual use, and achieve Reduced energy consumption, improved adsorption and removal performance, and high adsorption activity
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Embodiment 1
[0028] A preparation method of a porous spherical adsorbent for printing and dyeing sewage treatment is as follows:
[0029] Add tapioca starch to deionized water, add a sodium hydroxide solution with a mass concentration of 15% to adjust the pH to 8-10, heat to 92°C and stir for 70 minutes, then cool to 48°C and then add hydrogen peroxide and ferric sulfate (ferric sulfate The mass ratio of the quality and tapioca starch is 1:30), continue to stir for 2.5h, sodium trimetaphosphate and polyethylene glycol 6000 (mass ratio of polyethylene glycol 6000 and tapioca starch is 1:20) are added and stirred for 18min Finally, add sodium alginate and Span80, continue to stir for 10 minutes, then let it stand for 6 hours, slowly pour it into a calcium chloride solution with a mass concentration of 2.5%, react for 6 hours, collect the obtained solid, wash with water and ethanol, and dry at 55°C , to obtain material A; grind almandine into powder and pass through a 400-mesh sieve, add it t...
Embodiment 2
[0031] A preparation method of a porous spherical adsorbent for printing and dyeing sewage treatment is as follows:
[0032] Add tapioca starch to deionized water, add a sodium hydroxide solution with a mass concentration of 20% to adjust the pH to 8-10, heat to 90° C. and stir for 60 minutes, then cool to 40° C. and then add hydrogen peroxide and ferric sulfate (ferric sulfate The mass ratio of the quality and tapioca starch is 1:30), continue to stir 3h, sodium trimetaphosphate and polyethylene glycol 6000 (mass ratio of polyethylene glycol 6000 and tapioca starch is 1:20) add after stirring 15min , add sodium alginate and Span80, continue to stir for 10 minutes, then let it stand for 7 hours, slowly pour it into a calcium chloride solution with a mass concentration of 1.5%, react for 6 hours, collect the obtained solid, wash with water and ethanol, and dry at 50°C. Obtain material A; grind almandine into powder and pass through a 400-mesh sieve, add it to an ethanol solutio...
Embodiment 3
[0034]A preparation method of a porous spherical adsorbent for printing and dyeing sewage treatment is as follows:
[0035] Tapioca starch is added to deionized water, adding a mass concentration of 5% sodium hydroxide solution to adjust the pH to 8-10, heating to 95°C and stirring for 80min, then cooling to 50°C and then adding hydrogen peroxide and ferric sulfate (ferric sulfate The mass ratio of the mass of polyethylene glycol 6000 and tapioca starch is 1:20), continue stirring for 1h, sodium trimetaphosphate and polyethylene glycol 6000 (mass ratio of polyethylene glycol 6000 and tapioca starch is 1:20) is added after stirring for 18min , add sodium alginate and Span80, continue to stir for 15 minutes, then let it stand for 10 hours, slowly pour it into a calcium chloride solution with a mass concentration of 0.5%, react for 8 hours, collect the obtained solid, wash with water and ethanol, and then dry it at 50°C. Obtain material A; grind almandine into powder and pass thr...
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