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Preparation method of green wallpaper adhesive

An adhesive and wallpaper technology, which is applied in the field of preparation of green wallpaper adhesives, can solve problems such as poor peeling strength, and achieve the effects of reducing stringiness, reducing costs, and enhancing stability.

Inactive Publication Date: 2019-01-08
安徽古耐家居有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Existing Chinese patent document (notification number: CN106753224B) discloses a kind of environment-friendly wallpaper adhesive and preparation method thereof, comprises A agent and B agent; A agent is processed by the raw material of following weight part: modified defatted soybean powder 60-80 parts of paste, 6-8 parts of water-soluble dextran, 4-6 parts of leveling agent, 2-3 parts of organic bentonite, 1-3 parts of additives, the additives are flame retardant powder, nano negative ion powder and anti A mixture of at least two of the electrostatic agents; agent B is processed from the following raw materials in parts by weight: 8-15 parts of propolis powder, 1-3 parts of antioxidant, 30-40 parts of matrix, 1-2 parts of emulsifier, volume Fraction 75-85% ethanol solvent 40-60 parts, the adhesive has good peel strength at room temperature, but the peel strength will become worse when the temperature increases, so it is necessary to prepare an adhesive with good stability

Method used

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  • Preparation method of green wallpaper adhesive
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Examples

Experimental program
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Effect test

Embodiment 1

[0026] A kind of preparation method of green wallpaper adhesive of the present embodiment comprises the following steps:

[0027] Step 1, according to the parts by weight, weigh 44 parts of modified graphene and add it to the reaction kettle, adjust the temperature to 55 ° C, react for 15 minutes, then add 62 parts of 40% hydrochloric acid solution by mass fraction to it, and prepare modified graphite Then add 12 parts of hydroxypropyl starch and 16 parts of ethanol solution to it, stir for 15 minutes, then add 8 parts of layered hypophosphite, and carry out ultrasonic dispersion for 15 minutes to obtain premix A;

[0028] Step 2, adding casein to 6 times its weight in deionized water, stirring evenly, ultrasonically dispersing for 3 minutes, then adding an organic alcohol amine compound accounting for 2% of the mass of the mixed solution to adjust the pH value to 7-8, and stirring for 30 minutes to obtain casein plain solution; then mix the casein solution and epoxy resin in ...

Embodiment 2

[0041] A kind of preparation method of green wallpaper adhesive of the present embodiment comprises the following steps:

[0042] Step 1, according to the parts by weight, weigh 48 parts of modified graphene and add it to the reaction kettle, adjust the temperature to 65 ° C, react for 25 minutes, then add 68 parts of 50% hydrochloric acid solution by mass fraction to it, and prepare modified graphite Then add 16 parts of hydroxypropyl starch and 22 parts of ethanol solution to it, stir for 25 minutes, then add 14 parts of layered hypophosphite, and carry out ultrasonic dispersion for 25 minutes to obtain premix A;

[0043] Step 2: Add casein to 8 times its weight in deionized water, stir evenly, disperse by ultrasonic for 5 minutes, then add an organic alcohol amine compound accounting for 4% of the mass of the mixed solution to adjust the pH value to 7-8, and stir for 45 minutes to obtain casein Plain solution; then mix the casein solution and epoxy resin according to the we...

Embodiment 3

[0056] A kind of preparation method of green wallpaper adhesive of the present embodiment comprises the following steps:

[0057] Step 1, according to the parts by weight, weigh 46 parts of modified graphene and add it to the reactor, adjust the temperature to 60 ° C, react for 20 minutes, then add 65 parts of 45% hydrochloric acid solution by mass fraction to it, and prepare modified graphite Then add 14 parts of hydroxypropyl starch and 19 parts of ethanol solution to it, stir for 20 minutes, then add 11 parts of layered hypophosphite, and carry out ultrasonic dispersion for 20 minutes to obtain premix A;

[0058] Step 2: Add casein to 7 times its weight in deionized water, stir evenly, disperse by ultrasonic for 4 minutes, then add 3% organic alcohol amine compound accounting for the mass of the mixed liquid to adjust the pH value to 7-8, and stir for 37 minutes to obtain casein Vegetable solution; then mix the casein solution and epoxy resin according to the weight ratio o...

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Abstract

The invention discloses a preparation method of a green wallpaper adhesive. The preparation method comprises the following steps: preparing a premix A, preparing a tackifying auxiliary agent, and enabling the premix A, the tackifying auxiliary agent, natural glue juice, tripoli powder and an auxiliary agent to be subjected to a stirring reaction to obtain the green wallpaper adhesive. According tothe wallpaper adhesive disclosed by the invention, graphene is used as a base material, and the graphene is subjected to oxidation modification, so that the activity of the graphene is improved, andfurther the action force between the graphene and raw materials can be strengthened; besides, rare earth oxide, mica powder and layered hypophosphite are subjected to ultrasonic dispersion to be inserted into modified graphene, a formed system is stable in structure, further characteristics of adhesiveness, weather resistance and the like are strengthened, the added hydroxypropyl starch has the thickening effect, the added tackifying auxiliary agent effectively improves the caking property and the film formation property of the adhesive, construction of the adhesive is facilitated, and the tripoli powder can further promote mixing between the raw materials and strengthen the stabilizing effect of the system.

Description

technical field [0001] The invention relates to the technical field of wallpaper adhesive preparation, in particular to a preparation method of a green wallpaper adhesive. Background technique [0002] Adhesives for wallpaper bonding. The adhesives are divided into water-based and powder-based. Water-based adhesives are further divided into water-soluble adhesives and emulsion adhesives. Powdered wallpaper adhesives are instant, odorless, and non-toxic. , non-mold characteristics, water-soluble adhesives include soluble starch glue, carboxymethyl cellulose glue, denatured soluble starch glue, polyvinyl alcohol, etc., emulsion-type adhesives include polyvinyl acetate emulsion, acrylate emulsion, epoxy Resin emulsion, etc., powdered starch and its derivatives, cellulose and its derivatives, resins, wallpaper adhesives have a large polarity, can be bonded well, have good fluidity, and have heat resistance , with water resistance, poly alkali resistance. [0003] Existing Chin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J189/00C09J163/00C09J175/06C09J11/04C08G59/50
Inventor 袁东
Owner 安徽古耐家居有限公司
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