Photochromic Jun glaze and preparation method thereof

A photochromic and Jun porcelain technology, applied in the field of glazes, can solve the problems of low yield of photochromic glazes, instability, and poor stability of photochromic powders, etc., to achieve high yields, strong jade texture, The effect of less pores on the glaze surface

Inactive Publication Date: 2018-12-21
张丹丹
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the case of strictly controlling the temperature and atmosphere of glaze firing, the colorants in the glaze play a decisive role in the color development, and the most commonly used colorants are oxides such as copper oxide and iron oxide. The color is fixed. Although this kind of glaze is very beautiful, it can no longer satisfy people's pursuit of a higher level of Jun porcelain art. Therefore, it is imminent to study new functional Jun porcelain glazes. At present, the research on functional glazes The research mainly focuses on the color-changing glaze. The color-changing enamel glaze is prepared by adding the color-changing glaze into the Jun porcelain glaze, so that it can show different color effects under different light sources. However, the photochromic glaze currently fired The yield of the material is low, and the stability of the photochromic powder is poor at high temperature, and it cannot exist stably

Method used

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  • Photochromic Jun glaze and preparation method thereof
  • Photochromic Jun glaze and preparation method thereof
  • Photochromic Jun glaze and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] A photochromic Jun enamel, which is prepared from the following raw materials in parts by weight: 13-19 parts of feldspar, 25-31 parts of quartz, 9-15 parts of calcite, 2-4 parts of Suzhou soil, and 17-23 parts of this medicine , 13-19 parts of nano-tungsten oxide, 1.5-2.5 parts of nano-titanium oxide, and 0.5-1.5 parts of nano-zinc oxide.

[0023] The preparation method of the above-mentioned photochromic Jun enamel is characterized in that it comprises the following steps:

[0024] (1) Preparation of tungsten oxide-titanium oxide-zinc oxide color-changing powder: Weigh the above-mentioned nano-tungsten oxide, nano-titanium oxide, and nano-zinc oxide, add absolute ethanol and ball mill for 20-40min, dry, at 1300-1320℃ Calcined at low temperature for 30-40 minutes to obtain tungsten oxide-titanium oxide-zinc oxide discoloration powder;

[0025] (2) Preparation of glaze slurry: mix the above-mentioned feldspar, quartz, calcite, Suzhou soil, this medicine with tungsten o...

Embodiment 2

[0039] A photochromic Jun enamel, which is prepared from the following raw materials in parts by weight: 16 parts of feldspar, 28 parts of quartz, 12 parts of calcite, 3 parts of Suzhou soil, 20 parts of this medicine, 16 parts of nano-tungsten oxide, 2 parts of titanium, 1 part of nano zinc oxide.

[0040] The preparation method of the above-mentioned photochromic Jun enamel is characterized in that it comprises the following steps:

[0041] (1) Preparation of tungsten oxide-titanium oxide-zinc oxide color-changing powder: Weigh the above-mentioned nano-tungsten oxide, nano-titanium oxide, and nano-zinc oxide, add absolute ethanol and ball mill for 30 minutes, dry, and calcinate at 1310°C for 35 minutes. Obtain tungsten oxide-titanium oxide-zinc oxide discoloration powder;

[0042] (2) Preparation of glaze slurry: mix the above-mentioned feldspar, quartz, calcite, Suzhou soil, this medicine with tungsten oxide-titanium oxide-zinc oxide discoloration powder, pulverize, ball m...

Embodiment 3

[0053] A photochromic Jun enamel, which is prepared from the following raw materials in parts by weight: 15 parts of feldspar, 27 parts of quartz, 14 parts of calcite, 2 parts of Suzhou soil, 23 parts of this medicine, 15 parts of nano-tungsten oxide, and 15 parts of nano-oxidized tungsten 2.5 parts of titanium, 1.5 parts of nano zinc oxide.

[0054] The preparation method of the above-mentioned photochromic Jun enamel is characterized in that it comprises the following steps:

[0055] (1) Preparation of tungsten oxide-titanium oxide-zinc oxide color-changing powder: Weigh the above-mentioned nano-tungsten oxide, nano-titanium oxide, and nano-zinc oxide, add absolute ethanol and ball mill for 40 minutes, dry, and calcinate at 1320°C for 30 minutes. Obtain tungsten oxide-titanium oxide-zinc oxide discoloration powder

[0056] (2) Preparation of glaze slurry: mix the above-mentioned feldspar, quartz, calcite, Suzhou soil, this medicine with tungsten oxide-titanium oxide-zinc ox...

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Abstract

The invention provides photochromic Jun glaze and a preparation method thereof. The photochromic Jun glaze is prepared from raw materials in parts by weight as follows: 13-19 parts of melilite, 25-31parts of quartz, 9-15 parts of calcite, 2-4 parts of Suzhou clay, 17-23 parts of glarizonae, 13-19 parts of nano-tungsten oxide, 1.5-2.5 parts of nano-titanium oxide and 0.5-1.5 parts of nano-zinc oxide. The photochromic Jun glaze has the photochromic function, fewer air holes are formed in the glaze surface, the phenomenon of sagging is eliminated, the jade texture is great, and rate of finishedproducts is high.

Description

technical field [0001] The invention relates to the technical field of glazes, in particular to a photochromic enamel glaze and a preparation method thereof. Background technique [0002] Jun Porcelain is one of the five famous kiln porcelains in Song Dynasty in my country. The secret of "kiln transformation" lies in its glaze firing mechanism. The composition of Jun porcelain glaze is complex. During the glaze firing process, slight changes in the temperature and atmosphere in the kiln may trigger different chemical reactions, and promote the ever-changing color of Jun porcelain. . In the case of strictly controlling the temperature and atmosphere of glaze firing, the colorants in the glaze play a decisive role in the color development, and the most commonly used colorants are oxides such as copper oxide and iron oxide. The color is fixed. Although this kind of glaze is very beautiful, it can no longer satisfy people's pursuit of a higher level of Jun porcelain art. There...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C8/00C04B41/86
CPCC03C8/00C04B41/5022C04B41/86C04B41/4539C04B41/0072
Inventor 张丹丹
Owner 张丹丹
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