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Alkali-resistant aqueous binder and preparation method thereof, and beer label aqueous ink prepared by using alkali-resistant aqueous binder

A technology of alkali resistance and linking material, which is applied in the ink field to achieve good alkali resistance, reduce emulsifier hydrophilicity, and improve compactness

Active Publication Date: 2018-09-28
GUANGDONG YINGKE GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Another object of the present invention is to provide an application of an alkali-resistant water-based vehicle in beer label water-based inks. The beer label water-based ink prepared with alkali-resistant water-based vehicle has good alkali resistance, freezing resistance, and Dry and wet friction and other advantages solve the problem of water-based beer label inks on the market

Method used

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  • Alkali-resistant aqueous binder and preparation method thereof, and beer label aqueous ink prepared by using alkali-resistant aqueous binder
  • Alkali-resistant aqueous binder and preparation method thereof, and beer label aqueous ink prepared by using alkali-resistant aqueous binder
  • Alkali-resistant aqueous binder and preparation method thereof, and beer label aqueous ink prepared by using alkali-resistant aqueous binder

Examples

Experimental program
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Effect test

Embodiment 1

[0037] An alkali-resistant water-based binder, made of the following raw materials in parts by weight: 15 parts of modified epoxy resin, 20 parts of acrylic mixed monomer, 10 parts of vinyl silane, 5 parts of mixed emulsifier, initiator A0. 5 parts, 0.1 part of defoamer A, 0.1 part of leveling agent, 0.5 part of neutralizer and 100 parts of water; wherein, the mixed emulsifier is made of PA emulsifier, epoxy emulsifier and reactive emulsifier with A mixture composed of a weight ratio of 0.5:0.8:1.

[0038] The PA emulsifier is made from the following raw materials in parts by weight: 40 parts of methacrylic acid, 30 parts of butyl acrylate, 10 parts of styrene and 0.4 parts of initiator B; wherein, the initiator B is benzyl peroxide Acyl;

[0039] The preparation method of the PA emulsifier is as follows: add methacrylic acid, butyl acrylate and styrene into the reaction kettle and stir, heat to 100°C, then add initiator B, react to a suitable viscosity state, 10min, cool dow...

Embodiment 2

[0049] An alkali-resistant water-based binder, made of the following raw materials in parts by weight: 18 parts of modified epoxy resin, 22 parts of acrylic mixed monomer, 15 parts of vinyl silane, 6 parts of mixed emulsifier, initiator A0. 6 parts, 0.2 part of defoamer A, 0.2 part of leveling agent, 0.8 part of neutralizer and 110 parts of water; Wherein, described mixed emulsifier is made of PA emulsifier, epoxy emulsifier and reactive emulsifier A mixture composed of a weight ratio of 0.8:0.9:1.

[0050] The PA emulsifier is prepared from the following raw materials in parts by weight: 45 parts of methacrylic acid, 35 parts of butyl acrylate, 12 parts of styrene and 0.5 parts of initiator B; wherein, the initiator B is azobisiso Nitrile;

[0051] The preparation method of the PA emulsifier is as follows: add methacrylic acid, butyl acrylate and styrene into the reaction kettle and stir, heat to 110°C, then add initiator B, react to a suitable viscosity state, 15min, and co...

Embodiment 3

[0061] An alkali-resistant water-based binder, made of the following raw materials in parts by weight: 20 parts of modified epoxy resin, 30 parts of acrylic mixed monomer, 15 parts of vinyl silane, 6 parts of mixed emulsifier, initiator A0. 6 parts, 0.3 part of defoamer A, 0.3 part of leveling agent, 1 part of neutralizing agent and 110 parts of water; Wherein, described mixed emulsifier is made of PA emulsifier, epoxy emulsifier and reactive emulsifier A mixture composed of a weight ratio of 1:1:1.

[0062] The PA emulsifier is made from the following raw materials in parts by weight: 50 parts of methacrylic acid, 40 parts of butyl acrylate, 10 parts of styrene and 0.5 part of initiator B; wherein, the initiator B is benzyl peroxide Acyl;

[0063] The preparation method of the PA emulsifier is as follows: add methacrylic acid, butyl acrylate and styrene into the reaction kettle and stir, heat to 120°C, then add initiator B, react to a suitable viscosity state, 25min, cool do...

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Abstract

The invention relates to the technical field of inks, particularly to an alkali-resistant aqueous binder and a preparation method thereof, and a beer label aqueous ink prepared by using the alkali-resistant aqueous binder, wherein the alkali-resistant aqueous binder is prepared from the following raw materials by weight: 15-30 parts of a modified epoxy resin, 20-30 parts of an acrylic mixing monomer, 10-30 parts of vinyl silane, 5-10 parts of a mixed emulsifier, 0.5-0.8 part of an initiator A, 0.1-0.5 part of a defoamer A, 0.1-0.5 part of a leveling agent, 0.5-1.5 parts of a neutralizing agent, and 100-130 parts of water, wherein the mixed emulsifier comprises a PA emulsifier, an epoxy emulsifier and a reactive emulsifier. According to the present invention, the alkali-resistant aqueous binder is alkali-resistant acrylic acid-epoxy emulsion, and has advantages of good alkali resistance, good water resistance, low / no VOC, fast drying, simple preparation, low cost and the like.

Description

technical field [0001] The invention relates to the technical field of inks, in particular to an alkali-resistant water-based binder, a preparation method thereof and a beer label water-based ink prepared by using the same. Background technique [0002] In recent years, wine labels made of vacuum aluminum-coated paper have been widely used, and most of the beer labels are printed with solvent-based inks, such as POP inks and TSP inks. When the beer label requires beer bottles to be recycled, the ink printed on the surface of the label cannot fall off in the bottle washing tank when the recycled bottle is washed with lye, so that the label will not be deinked. There is an urgent need for a water-based beer label ink to replace traditional solvent-based inks in the market, but ordinary acrylic emulsions are not alkali-resistant, so it is of great significance to develop an alkali-resistant water-based binder that meets market demand. [0003] For example, Chinese patent CN102...

Claims

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Application Information

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IPC IPC(8): C09D11/107C08F283/10C08F230/08C08F220/14C08F212/08C08G59/14
CPCC08F283/105C08G59/1477C09D11/107C08F230/08
Inventor 刘润林连坤鹏钟细志金伟师
Owner GUANGDONG YINGKE GRP CO LTD
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