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Seawater desalination de-foaming agent as well as preparation method and application thereof

A defoamer and emulsifier technology, applied in the field of seawater desalination defoamer and its preparation, can solve the problems of high cost of use, poor foam suppression ability, low foam breaking rate, etc., to achieve non-corrosive, easy to operate, stable good sex effect

Pending Publication Date: 2018-09-07
自然资源部天津海水淡化与综合利用研究所 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Although oil defoamers are cheap, they have poor antifoaming ability, low defoaming rate, are not easy to disperse in the water phase, and have narrow application areas, so they have been gradually eliminated by the market; polyether defoamers have good water solubility, Strong antifoaming ability, but low foam breaking rate, once a large amount of foam is generated, it cannot be effectively eliminated at once, and the cost of use is high; silicone defoamer is a kind of defoaming agent with low toxicity and strong foam breaking ability However, due to its poor water solubility, its use in water systems is limited; with the development of defoamers, those low-grade defoamers with a single component structure and poor economic benefits will gradually be replaced by multifunctional , high-efficiency compound open-type defoamer to replace, the development of compound defoamer with strong applicability, less dosage and high stability is the current development trend of the industry

Method used

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  • Seawater desalination de-foaming agent as well as preparation method and application thereof
  • Seawater desalination de-foaming agent as well as preparation method and application thereof
  • Seawater desalination de-foaming agent as well as preparation method and application thereof

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preparation example Construction

[0051]In view of the need to improve the environmental performance and use efficiency of the current defoamer, the present invention provides a high-efficiency seawater desalination defoamer and its preparation method and application.

[0052] In a preferred embodiment, the high-efficiency seawater desalination defoamer of the present invention includes the components described in Table 1:

[0053] Table 1 Seawater desalination defoamer components

[0054] silicone paste

5~20%

Polyether modified silicone

10~30%

Emulsifier

2~10%

thickener

0.5~2%

fungicide

0.01~0.05%

water

margin

The total proportion of each component

100%

[0055] The preparation method of the silicone paste comprises: adding simethicone, gas-phase silicon dioxide, and a catalyst into a reaction kettle in proportion, and reacting at 100-150° C. for 4-6 hours to prepare the silicone paste. Further, the viscosity of the simethicone oil...

Embodiment 1

[0074] 1.1 Preparation of silicone paste

[0075] A total of 35 g of simethicone, fumed silica, and catalyst (KOH solution, concentration: 4 wt%) were added into the reaction kettle in proportion, and reacted at 100° C. for 6 hours to prepare a silicone paste. Wherein, the viscosity of the simethicone oil is 500mPa·s; the fumed silica is a hydrophobic fumed silica with a specific surface area of ​​400mPa. 2 / g; the mass ratio of the three components is simethicone:fumed silica:catalyst=97.5:2:0.5.

[0076] 1.2 Preparation of polyether modified silicone

[0077] Add 0.05 g of 2,4-di-tert-butyl p-cresol to 56 g of allyl alcohol polyether toluene solution (the concentration of allyl alcohol polyether is 82.14%), and add isopropanol-dissolved chloroplatinum under nitrogen atmosphere Acid solution catalyst (the concentration of chloroplatinic acid is 1%), chloroplatinic acid accounts for 40 μg / g of the total reactants; start stirring, and slowly add low hydrogen-containing silico...

Embodiment 2

[0085] 2.1 Preparation of silicone paste

[0086] A total of 70 g of simethicone, fumed silica, and catalyst (KOH solution, concentration: 2 wt%) were added to the reaction kettle in proportion, and reacted at 150° C. for 4 hours to prepare a silicone paste. Wherein, the viscosity of the simethicone oil is 1000mPa·s; the fumed silica is a hydrophobic fumed silica with a specific surface area of ​​200mPa. 2 / g; the mass ratio of the three components is simethicone:fumed silica:catalyst=93:5:2.

[0087] 2.2 Preparation of polyether modified silicone

[0088] Add 0.03g hydroquinone in the allyl alcohol polyether isopropanol solution (the concentration of allyl alcohol polyether is 70.59%) in 34g, add the chloroplatinic acid solution catalyst (chloroplatinum chloride) that isopropanol dissolves under nitrogen protection acid concentration is 1%), chloroplatinic acid accounted for 20 μg / g of the total reactant; start stirring, slowly add low hydrogen-containing silicone oil, wher...

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Abstract

The invention relates to a seawater desalination de-foaming agent as well as a preparation method and application thereof. The de-foaming agent is prepared from silicon paste, polyether modified organic silicon, an emulsifier, a thickening agent and water, wherein the mass percent of the silicon paste is 5 to 20 percent, the mass percent of the polyether modified organic silicon is 10 to 30 percent, the mass percent of the emulsifier is 2 to 10 percent and the mass percent of the thickening agent is 0.5 to 2 percent. The preparation method comprises the following steps: (1) weighing the silicon paste, the polyether modified organic silicon and the emulsifier according to the mass percent and mixing at 70 to 80 DEG C to obtain a mixture; (2) preparing the thickening agent into a water solution; (3) injecting 1 / 3 or less of the thickening agent water solution into the mixture of step (1); after uniformly mixing, adding the residual thickening agent water solution in batches to obtain thede-foaming agent. The de-foaming agent provided by the invention has the characteristics of high stability, rapid de-foaming speed, good foam inhibition performance, good compatibility with a scale inhibitor and the like and has good environment-friendly performance and a wide application prospect.

Description

technical field [0001] The invention relates to the field of defoamers, in particular to a seawater desalination defoamer and its preparation method and application. Background technique [0002] Seawater usually contains a lot of organic matter, and it is easy to generate foam under the working conditions of low-temperature multi-effect seawater desalination. If no measures are taken to suppress it, it will lead to unstable control of the seawater level and affect the normal operation of the device. During the actual operation of the low-temperature multi-effect seawater desalination plant, the way of adding defoamer is usually used to control the formation of foam. [0003] Although oil defoamers are cheap, they have poor antifoaming ability, low defoaming rate, are not easy to disperse in the water phase, and have narrow application areas, so they have been gradually eliminated by the market; polyether defoamers have good water solubility, Strong antifoaming ability, but...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D19/04C02F1/20C02F103/08
CPCB01D19/0409C02F1/20C02F2103/08C02F2303/12
Inventor 胡明明徐旭胡楠沈忱王维珍尹建华
Owner 自然资源部天津海水淡化与综合利用研究所
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