A kind of anti-blue light resin lens and preparation method thereof
A resin lens and anti-blue light technology, which is applied in optics, optical components, optical components, etc., can solve the problems of high cost of lenses, low pass rate of lenses, and low output, etc., to increase the three-dimensional network structure and increase the absorption rate of blue light , Improve the effect of cross-linking degree
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Embodiment 1
[0028] Diethylene glycol allyl carbonate and its polymer mixture (manufactured by ACOMN, product code RAV7NG) are selected as the resin monomer, and 2-hydroxy-4-methoxybenzophenone (UV-9) is selected as the blue light absorber , the polymerization initiator is tert-butyl peroxide 2-ethylhexyl carbonate, the modifier A is polyurethane acrylate, and the modifier B is trimethylolpropane trimethacrylate (HANNONGCHEMICAL CO., LTD, CAS No. 3290-92-4).
[0029] Weigh 20Kg of RAV7NG monomer, 200g of 2-hydroxy-4-methoxybenzophenone (UV-9), mix well, heat up to 60°C, add 2-ethylhexyl peroxide after the blue light absorber is completely dissolved 300g of tert-butyl carbonate, 200g of urethane acrylate, and 300g of trimethylolpropane trimethacrylate. Stir for 2 hours at room temperature and a vacuum of 0.1MPa, continue stirring for 10 minutes after filtering through a 0.1μm filter element, vacuumize for 40 minutes under a vacuum of 0.1MPa, and pour the prepared material into the containe...
Embodiment 2
[0031] Diethylene glycol allyl carbonate and its polymer mixture (manufactured by ACOMN, product code RAV7NG) are selected as resin monomers, and benzophenone-based ultraviolet absorbers 2,2'-dihydroxy-4, 4'-dimethoxybenzophenone (BP-6) and indole blue light absorber 2-cyano-3-(1-methyl-2-phenylmethylacrylate) indole, polymerization initiator Use tert-amyl peroxide 2-ethylhexyl carbonate, epoxy acrylate as modifier A, and pentaerythritol triacrylate (HANNONG CHEMICAL CO., LTD, CAS No. 3524-68-3) as modifier B.
[0032] Weigh 20Kg of RAV7NG monomer, 280g of 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-cyano-3-(1-methyl-2-phenylacrylate methyl ester ) Indole 20g, mix well, heat up to 60°C, after the blue light absorber is completely dissolved, add 400g of tert-butyl peroxide 2-ethylhexyl carbonate, 160g of polyurethane acrylate, and 180g of trimethylolpropane triacrylate. Stir evenly under vacuum at room temperature and at room temperature and a vacuum of 0.1MPa for 2 hours, fi...
Embodiment 3
[0034] Resin monomer selects diethylene glycol allyl carbonate and its multimer mixture (PPG company, product code name is LS), and benzophenone UV absorber selects 2-hydroxyl-4-octyloxybenzophenone ( UV-531), polymer initiator selects tert-amyl peroxide 2-ethylhexyl carbonate, modifier A selects epoxy acrylate, modifier B selects trimethylolpropane triacrylate (HANNONGCHEMICAL CO., LTD, CAS No. 15625-89-5).
[0035]Weigh 20Kg of LS monomer, 240g of 2-hydroxy-4-octyloxybenzophenone (UV-531), mix well, heat up to 60°C, add 420g of 2-ethyl peroxide after the blue light absorber is completely dissolved Hexyl tert-amyl carbonate, 180g of epoxy acrylate, 260g of trimethylolpropane triacrylate, stir evenly in a sealed vacuum at room temperature, stir for 2 hours at room temperature and a vacuum of 0.1MPa, filter through a 0.1μm filter element and continue stirring 10 minutes, evacuated for 40 minutes under the condition of vacuum degree of 0.1MPa, poured vertically, poured the prep...
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