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Gypsum-based composite binding material for extruded 3D printing and preparation method thereof

A composite gel material and 3D printing technology, which is applied in the direction of manufacturing tools, additive processing, ceramic molding machines, etc., can solve the problems of poor printing accuracy, obstruction of extrusion printing, and inability to obtain early strength, etc., to achieve proper setting time , setting time control, and the effect of easy operation and construction

Inactive Publication Date: 2018-08-10
深圳市明远建筑科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The existing gelling materials for printing have a long or too short bonding time, and the setting time cannot be freely adjusted to meet the requirements of printing and curing laminates, or they are solidified at the extrusion head during the printing process and cause blockage; fluidity and extrusion Extrusion-type printing is not coordinated, too large or too small will cause varying degrees of obstruction to extrusion-type printing; it is impossible to obtain early strength in a short time during the printing process, and it is difficult to ensure the continuation of printing; printing accuracy is poor, and high-precision buildings cannot be printed member

Method used

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  • Gypsum-based composite binding material for extruded 3D printing and preparation method thereof
  • Gypsum-based composite binding material for extruded 3D printing and preparation method thereof
  • Gypsum-based composite binding material for extruded 3D printing and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] Prepare the following substances in parts by weight:

[0039]

[0040] Preparation method: Weigh the raw materials according to the formula, add gypsum powder (resin gypsum powder), pre-excitation material (carbonate slag), mineral additives (P.O42.5 white Portland cement), Plasticized water reducer (melamine), retarder (sodium gluconate) and fiber (polyvinyl alcohol fiber), fully stirred evenly, so as to obtain powdery gypsum-based composite gelling material;

[0041] Measure 25 parts of water, add waterproofing agent (sodium stearate), crystallization habit modifier (succinic acid), crystallization stabilizer (glycerin), dispersant (ethylene bisstearamide), Thickening water-retaining agent (hydroxypropyl methylcellulose ether), binder 1 (polyvinyl alcohol), binder 2 (vinyl acetate), defoamer (polyether silicone oil), crystallization agent (sodium citrate ) and lubricant (water-soluble emulsified silicone oil), stirred evenly to obtain a mixed solution.

[0042] A...

Embodiment 2

[0045] Prepare the following substances in parts by weight:

[0046]

[0047]

[0048] Preparation method: Weigh raw materials according to the formula, add gypsum powder 1 (resin gypsum powder), gypsum powder 2 (citric acid gypsum powder), pre-excitation material 1 (aluminum slag powder), pre-excitation material 2 ( aluminate slag), mineral additive 1 (silicon powder), mineral additive 2 (first-class fly ash), plasticizing water reducer (melamine sulfonated polycondensate), retarder (citric acid monohydrate ) and fibers (polyimide fibers), fully stirred evenly, so as to obtain powdery gypsum-based composite cementitious material;

[0049] Measure 30 parts of water, add waterproofing agent (magnesium stearate), crystallization habit modifier (sodium dodecylbenzenesulfonate), crystallization stabilizer (sodium isobutyrate), dispersant ( acrylic acid), thickener (carboxymethyl hydroxyethyl cellulose), binder (epoxy resin), defoamer (high carbonic acid), crystallization ag...

Embodiment 3

[0053] Prepare the following substances in parts by weight:

[0054]

[0055]

[0056] Preparation method: Weigh the raw materials according to the formula, add gypsum powder 1 (citric acid gypsum powder), gypsum powder 2 (desulfurized gypsum powder), pre-excitation material (aluminum slag powder), mineral additive 1 (a grade fly ash), plasticizing water reducer (sulfamic acid polycondensate), retarder (citric acid monohydrate) and fiber (polyvinyl alcohol fiber), fully stir evenly to obtain powdery gypsum-based composite adhesive Concrete material;

[0057] Measure 30 parts of water, add waterproofing agent 1 (sodium stearate), waterproofing agent 2 (potassium stearate), crystallization habit modifier 1 (sodium dodecylbenzenesulfonate), crystallization Habit modifier 2 (succinic acid), crystallization stabilizer (sodium citrate), dispersant (polyoxyethylene), thickener and water retaining agent (sodium propylene sulfonate), binder (vinyl acetate), defoaming agent agen...

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Abstract

The invention discloses a gypsum-based composite binding material for extruded 3D printing and a preparation method thereof and relates to the field of civil engineering / 3D printing materials. Aimingat defects in the prior art, the invention provides the gypsum-based composite binding material for extruded 3D printing. The binding material is prepared from the following components: gypsum, pre-excited material, mineral additives, a plasticized water reducing agent, a waterproof agent, a crystal habit improver, a cystallizing stabilizer, a retarder, a dispersing agent, a water-retentive and thickening admixture, an adhesive, an antifoaming agent, a crystal modifier, a lubricating agent and fibers. The binding material disclosed by the invention has the beneficial effects that the preparedgypsum-based composite binding material for extruded 3D printing is wide in source, excellent in liquidity and environmentally friendly and has excellent extrusion continuity, constructability, mechanical property, water seepage resistance and cracking resistance.

Description

technical field [0001] The invention relates to the field of civil engineering / 3D printing materials, in particular to a gypsum-based composite gelling material for extrusion 3D printing and a preparation method thereof. Background technique [0002] 3D printing is a technology of manufacturing three-dimensional products by adding materials layer by layer through 3D printing equipment based on the designed 3D model. This layer-by-layer accumulation forming technology is also called additive manufacturing. 3D printing integrates cutting-edge technologies in many fields such as digital modeling technology, electromechanical control technology, information technology, material science and chemistry. It is a kind of rapid prototyping technology and is known as the core technology of the "third industrial revolution". Compared with traditional manufacturing technology, 3D printing does not need to make molds in advance, remove a large amount of material during the manufacturing p...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/14B33Y70/00B28B1/00
CPCB28B1/001B33Y70/00C04B28/14C04B28/144C04B2111/00181C04B24/307C04B24/26C04B7/02C04B22/10C04B24/128C04B24/085C04B24/04C04B24/02C04B24/10C04B24/124C04B24/383C04B24/2623C04B24/42C04B24/06C04B16/0641C04B22/04C04B22/0093C04B18/08C04B24/166C04B24/20C04B24/281C04B24/34C04B16/0691C04B24/32C04B24/16C04B22/147
Inventor 黄明洋曹香鹏卢乐成
Owner 深圳市明远建筑科技有限公司
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