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Surface modified carbon fiber prepreg based on graphene oxide and preparation method of carbon fiber prepreg

A carbon fiber prepreg and surface modification technology, which is applied in the field of graphene oxide-based surface modified carbon fiber prepreg and its preparation, can solve the problems of increasing process difficulty and cost, agglomeration affecting material performance, and low surface activity. The effect of improved interface performance, good wettability, and good toughness

Inactive Publication Date: 2018-06-29
XIAMEN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the irregular structure of graphene and low surface activity, it is usually necessary to chemically modify the surface of graphene in the modification process of carbon fiber / resin-based prepregs and composite materials to increase its surface active groups. Bonding between graphene and resin matrix, carbon fiber
Patent [Zhao Donglin et al., China Patent of Invention, application number 201610339876.8] grafting -NH2 on the surface or edge of graphene, patent [Zhao Donglin et al., China Patent of Invention, application number 201610339807.7] and [Zhao Yang et al., China Invention Patent, application number 201710031321.1 ] Not only to chemically modify graphene, but also to form a binary reinforcement material with carbon nanotubes, which undoubtedly increases the difficulty and cost of the process, and the use of carbon nanotubes can easily cause agglomeration and affect the performance of the material

Method used

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  • Surface modified carbon fiber prepreg based on graphene oxide and preparation method of carbon fiber prepreg
  • Surface modified carbon fiber prepreg based on graphene oxide and preparation method of carbon fiber prepreg
  • Surface modified carbon fiber prepreg based on graphene oxide and preparation method of carbon fiber prepreg

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preparation example Construction

[0035] The preparation method of the surface-modified carbon fiber prepreg based on graphene oxide comprises the following steps:

[0036] 1) Preparation of carbon fiber prepreg: The carbon fiber prepreg is a mixed system composed of graphene oxide, epoxy resin, and organic solvent. The graphene oxide aqueous solution is obtained by the Hummers method, and the degree of oxidation is controlled to realize the control of graphene oxide. The total content of oxygen-containing groups is between oxygen atom / carbon atom (O / C)=(1 / 2)~(1 / 10) (atom number ratio), and the number of dispersion layers in acetone solvent is controlled to be 1~ 10 layers; at the same time, use ultrasonic dispersion to control the number of dispersed layers of graphene oxide in acetone solvent to be between 1 and 10 layers; filter the graphene oxide aqueous solution to remove water, then directly dissolve it in acetone solution, and centrifuge at low speed The precipitate was removed to obtain the upper liqui...

Embodiment 1

[0043] The graphene oxide aqueous solution is obtained by the Hummers method, wherein by controlling the degree of oxidation, the total content of the oxygen-containing groups of the graphene oxide is controlled at oxygen atom / carbon atom (O / C)=(1 / 2)~(1 / 10 ) (ratio of atomic number). At the same time, ultrasonic dispersion is used to control the number of dispersion layers of the graphene oxide in the acetone solvent to be between 1 and 10 layers. The graphene oxide aqueous solution was suction filtered to remove water, then directly dissolved in the acetone solution, and the precipitate was removed by low-speed centrifugation to obtain the graphene oxide acetone solution as the upper liquid. The concentration of the graphene oxide acetone solution can be controlled to be 6-8 mg / mL by rotary evaporation and other technical methods.

[0044] Prepare an acetone solution of graphene oxide, ultrasonic 10min, to obtain mixed solution A; dissolve the epoxy resin in the acetone solu...

Embodiment 2

[0047] The graphene oxide aqueous solution is obtained by the Hummers method, wherein by controlling the degree of oxidation, the total content of the oxygen-containing groups of the graphene oxide is controlled at oxygen atom / carbon atom (O / C)=(1 / 2)~(1 / 10 ) (ratio of atomic number). At the same time, ultrasonic dispersion is used to control the number of dispersion layers of the graphene oxide in the acetone solvent to be between 1 and 10 layers. The graphene oxide aqueous solution was suction filtered to remove water, then directly dissolved in the acetone solution, and the precipitate was removed by low-speed centrifugation to obtain the graphene oxide acetone solution as the upper liquid. The concentration of the graphene oxide acetone solution can be controlled to be 6-8 mg / mL by rotary evaporation and other technical methods.

[0048] Prepare an acetone solution of graphene oxide, ultrasonic 10min, to obtain mixed solution A; dissolve the epoxy resin in the acetone solu...

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Abstract

The invention discloses a surface modified carbon fiber prepreg based on graphene oxide and a preparation method of the carbon fiber prepreg and relates to preparation of the carbon fiber prepreg. Thesurface modified carbon fiber prepreg based on graphene oxide is prepared from, in parts by mass, 100 parts of carbon fiber and a prepreg solution containing 40%-60% of resin, wherein the prepreg solution is prepared from, in parts by mass, 100 parts of epoxy resin, 50-150 parts of acetone and 0.05-5 parts of graphene oxide. Graphene oxide is uniformly dispersed in an epoxy resin prepreg solution, carbon fiber is soaked in the epoxy resin prepreg solution containing graphene oxide, and a graphene oxide / epoxy resin infiltration layer is formed on the surface of the carbon fiber, the purpose ofimproving the interface performance of the carbon fiber and an epoxy resin matrix is achieved, and a graphene oxide / carbon fiber / epoxy resin prepreg and a composite product thereof are obtained and are convenient to operate, require simple equipment and are suitable for industrial production.

Description

technical field [0001] The invention relates to the preparation of a carbon fiber prepreg, in particular to a graphene oxide-based surface-modified carbon fiber prepreg and a preparation method thereof. Background technique [0002] Carbon fiber reinforced resin matrix composites are widely used in the fields of aerospace, automobiles and sports equipment due to their advantages such as high specific strength, designability of performance, good structural and dimensional stability, and ease of large-area integral molding. Carbon fiber prepreg refers to the product obtained by impregnating the resin matrix with carbon fiber or its fabric under certain conditions. It is a semi-finished product of fiber reinforced composite material that can be stored. It has the advantages of easy use, stable performance, low porosity, and clean process. Applications in composite materials are becoming more and more common. [0003] However, due to the structure of carbon fiber itself, the su...

Claims

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Application Information

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IPC IPC(8): C08L63/00C08K7/00C08K7/06C08J5/24
CPCC08J5/24C08J2363/00C08K7/00C08K7/06
Inventor 胡晓兰代少伟白华张莹王菁菁
Owner XIAMEN UNIV
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