Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

9-naphthanthracene derivative monomolecular white light material as well as preparation and application thereof

A derivative and single-molecule technology, applied in the field of 9-naphthalene anthracene derivative single-molecule white light materials and its preparation and application, can solve the problems of unstable light color and complicated preparation of single-molecule white light materials, and achieve low cost and stable The effect of white light emission and warm white light emission

Active Publication Date: 2018-05-25
HUAZHONG UNIV OF SCI & TECH +1
View PDF1 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the above defects or improvement needs of the prior art, the purpose of the present invention is to provide a 9-naphththracene derivative monomolecular white light material and its preparation and application, wherein the key chemical structure of the 9-naphthalene anthracene derivative, And the preparation process (including the parameters used in each step in the preparation process, and reaction conditions, etc.) was improved, and a new type of 9-naphthalene anthracene derivative single-molecule white light material with an intermolecular charge transfer state combined with an excimer was obtained. , and the 9-naphthalene anthracene derivative can be synthesized by a simple synthesis method, and can be used as an electroluminescent material, thereby solving the technical problems of the existing single-molecule white light materials such as complex preparation and unstable light color

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • 9-naphthanthracene derivative monomolecular white light material as well as preparation and application thereof
  • 9-naphthanthracene derivative monomolecular white light material as well as preparation and application thereof
  • 9-naphthanthracene derivative monomolecular white light material as well as preparation and application thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0042] The chemical reaction principles based on the preparation methods of these compounds can be summarized into three types:

[0043] The first:

[0044]

[0045] The second type:

[0046]

[0047] The third type:

[0048]

Embodiment 1

[0051] The structural formula of the 9-naphthalene anthracene derivative in this example is shown in formula 4, that is, 6,12-bis[10-(1-naphthyl)-9-anthracene)]-chrysene.

[0052]

[0053] The main chemical reactions that its preparation method takes place are as follows:

[0054]

[0055] Specifically: under nitrogen protection, 9-(1-naphthalene) anthracene-10-boronic acid (13mmol, 4.5g), 6,12-dibromochrome (5.4mmol, 2.1g), tetrakistriphenylphosphine palladium ( 0.3mmol, 0.4g), toluene (200mL), ethanol (100ml) and potassium carbonate aqueous solution (100mL, 2M) were put into a 500ml three-necked round bottom flask and stirred, and the mixture was heated to 90°C for 12 hours under the protection of nitrogen flow. After the reaction was completed, it was naturally cooled to room temperature, and suspended solids were precipitated. The precipitates were filtered out, washed with water, ethanol, and acetone respectively, placed in a vacuum drying oven for drying, and subli...

Embodiment 2

[0059] The structural formula of the 9-naphthalene anthracene derivative in this example is shown in formula 5, that is, 6,12-bis[10-(2-naphthyl)-9-anthracene)]-chrysene.

[0060]

[0061] Its preparation method is as follows: 9-(2-naphthalene) anthracene-10-boronic acid (13mmol, 4.5g), 6,12-dibromochrome (5.4mmol, 2.1g), tetrakis(triphenyl Phosphine) palladium (0.3mmol, 0.4g), toluene (200mL), ethanol (100ml) and potassium carbonate (100mL, 2M) were dropped into a 500ml three-necked round-bottomed flask and stirred, and the mixture was heated to 90°C under the protection of a nitrogen stream to react 12 Hour. After the reaction was completed, it was naturally cooled to room temperature, and suspended solids were precipitated. The precipitates were filtered out, washed with water, ethanol, and acetone respectively, placed in a vacuum drying oven for drying, and sublimated with a high-vacuum sublimator to obtain 3.9 g of a light yellow powder. The yield was : 87%.

[0062]...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a 9-naphthanthracene derivative. The 9-naphthanthracene derivative uses a dianthracene group as a center and uses the effect of the naphthaline group on molecular arrangement,so that the molecules show the typical blue light emission of the anthracene group in the monomolecular state, forms the intermolecular charge transfer state during the molecular accumulation, shows the green light emission, and forms yellow light emission with excimers; through the three joint effects, the compound is the monomolecular white light material. Through the improvement on the key chemical structure of the 9-naphthanthracene derivative and the preparation process, a novel intermolecular charge transfer state combining excimer 9-naphthanthracene derivative monomolecular white lightmaterial is obtained; the 9-naphthanthracene derivative can be synthesized by a simple synthesis method, and can be used as an electroluminescent material, so that the technical problems of preparation complexity, light color instability and the like of the existing monomolecular white light material are solved.

Description

technical field [0001] The invention belongs to the technical field of preparation and application of organic photoelectric materials, and more specifically relates to a single-molecule white light material of 9-naphthalene anthracene derivative and its preparation and application. The 9-naphthalene anthracene derivative is a kind of The monomolecular white light material combined with the excimer can be used as an organic light-emitting material. Background technique [0002] Since Kodak first reported Organic Light Emitting Diode (OLED) in 1987 (Pope M., Kallmann.H.P., Magnante.P., Electroluminescence in Organic Crystals. The Journal of Chemical Physics 1963,38(8): 2042-2043), by continuously synthesizing new materials and optimizing device structures, the research of OLEDs has made major breakthroughs, showing attractive industrialization prospects in the next generation of flat-panel displays and lighting sources. Subsequently, in 1990, the University of Cambridge in th...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C07C15/38C07C1/32C09K11/06H01L51/50H01L51/54
CPCC09K11/06C07C1/321C07C15/38C09K2211/1011H10K85/622H10K85/615H10K85/626H10K50/11Y02B20/00
Inventor 王磊向松坡
Owner HUAZHONG UNIV OF SCI & TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com