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Low-odor sterilizing micro-foaming spray-free polypropylene composite material and preparation method thereof

A composite material and micro-foaming technology, which is applied in the field of micro-foaming spray-free polypropylene composite material and its preparation, can solve the problem of adding limit and the like, and achieves low saturated water absorption, excellent mechanical properties and good adhesion. Effect

Inactive Publication Date: 2018-04-20
DONGGUAN JISU PLASTIC TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Chinese invention patent application CN106147019A discloses a low-VOC glass fiber-reinforced polypropylene halogen-free flame-retardant composite material and its application; the application uses gas adsorbents and nano-photocatalysts to absorb and decompose low-VOC harmful gases, and has a bactericidal effect, but nano-materials are common The characteristic is that it is easy to reunite, and the amount of addition is limited

Method used

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  • Low-odor sterilizing micro-foaming spray-free polypropylene composite material and preparation method thereof
  • Low-odor sterilizing micro-foaming spray-free polypropylene composite material and preparation method thereof
  • Low-odor sterilizing micro-foaming spray-free polypropylene composite material and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0046] (1) First, antistatic agent (PELESTAT 300), low-volatile matter adsorbent (nano-silica, zeolite molecular sieve and calcined diatomaceous earth are mixed in a mass ratio of 1:2:1), and encapsulation treatment decomposing enzyme and nano photocatalyst were dried separately for use.

[0047] (2) 83.8 parts of high crystalline polypropylene and 6 parts of cycloolefin copolymer (COC), 1.5 parts of dried low-volatile matter adsorbent, antioxidant (antioxidant 1010, DSTP and high molecular weight sulfide The mass ratio of ester 412S is 0.2:0.1:0.1 mixed composition) 0.4 parts, UV770 anti-ultraviolet additive 0.3 parts, dried antistatic agent (PELESTAT 300) 5 parts, lubricant (silicone masterbatch) 1 part , added to the high mixer one by one, and mixed for 6 minutes to get the mixture A, referred to as component A.

[0048] (3) Mix 0.5 part of the decomposing enzyme of the dried package shoe treatment and 0.3 part of the nano photocatalyst together to obtain the mixture B, re...

Embodiment 2

[0052] (1) Antistatic agent (bis(β-hydroxyethyl) cocoamine), low-volatile matter adsorbent (nano-silica, zeolite molecular sieve and calcined diatomite are mixed in a mass ratio of 0.5:3:1.5) Mixed composition), packaged decomposing enzymes, and nano photocatalysts were dried separately for use.

[0053] (2) 82.7 parts of high crystalline copolymerized polypropylene and 6 parts of cycloolefin copolymer (COC), 1.7 parts of dried low-volatile matter adsorbent, antioxidant (antioxidant 1010, DSTP and high molecular weight sulfur Substitute ester 412S (mixed by mass ratio 0.2:0.:0.2) 0.4 parts, UV788 anti-ultraviolet additive 0.3 parts, dried antistatic agent (bis(β-hydroxyethyl) cocoamine) 5 parts, Add 1 part of lubricant (calcium stearate) into the high-speed mixer in sequence, and mix for 6 minutes to obtain compound A, referred to as component A.

[0054] (3) Mix 0.8 part of the decomposing enzyme and 0.5 part of the nano-photocatalyst that have been dried to obtain the mixtu...

Embodiment 3

[0058] (1) First, antistatic agent (PELESTAT 300), low volatile matter adsorbent (nano-silica, zeolite molecular sieve and calcined diatomaceous earth are mixed at a mass ratio of 1.5:1:0), and the package is decomposed Enzymes and nanophotocatalysts were dried separately for use.

[0059] (2) 81.7 parts of high crystalline polypropylene and 6 parts of cycloolefin copolymer (COC), 2 parts of dried low-volatile matter adsorbent, antioxidant (antioxidant 1010, DSTP and high molecular weight sulfide The mass ratio of ester 412S is 0.2:0.1:0.1 mixed composition) 0.4 parts, UV770 anti-ultraviolet additive 0.3 parts, dried antistatic agent (PELESTAT 300) 5 parts, lubricant (silicone masterbatch) 1 part , added into the high mixer one by one, and mixed for 8 minutes to get the mixture A, referred to as component A.

[0060] (3) Mix 1 part of the decomposing enzyme for bag-shoe treatment that has been dried and 0.6 part of the nano-photocatalyst together to obtain the mixture B, refe...

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Abstract

The invention discloses a low-odor sterilizing micro-foaming spray-free polypropylene composite material and a preparation method thereof. The polypropylene composite material is prepared from high crystalline polypropylene, micro-ball foaming agent, scratch-resistant resin, low volatile substance adsorbent, encapsulated enzyme, nano photocatalyst, a lubricant, and antioxidant according to parts by weight. The low volatile substance adsorbent has very strong adsorption and can effectively prevent forming parts of the composite material from generating low volatile harmful gases; the encapsulated enzyme and nano photocatalyst can decompose the low volatile harmful gases of the material into harmless carbon dioxide and water; and the high crystalline polypropylene has lower density, higher elasticity and proper rigidity after micro-ball foaming treatment. The material prepared by the method has good mechanical property, is light, resists heat and aging, is weather resistant, scratch resistant, and antistatic, has low odor, and contains low TVOC, thereby being applied to fields like automotive interior and high-grade decoration.

Description

technical field [0001] The invention relates to the technical field of modification of polypropylene materials, in particular to a micro-foaming spray-free polypropylene composite material with low odor and bactericidal function and a preparation method thereof. Background technique [0002] High crystalline polypropylene (HCPP) is a high-performance special resin with high surface hardness, low density, 0.9-0.91 g / cm3, isotacticity of 98%-99%, crystallinity of more than 70%, and high strength. , high heat resistance, high rigidity, excellent gloss, wear resistance, good bending fatigue resistance, performance close to engineering plastics. Since the crystallization temperature of HCPP is higher than that of ordinary polypropylene products, the product molding cycle can be greatly shortened, and the extremely low density makes it easy to make the manufactured products thinner and lighter. The disadvantage is that the shrinkage rate is large and it is relatively not scratch-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L45/00C08L83/04C08K13/06C08K9/10C08K3/36C08K3/34C08K5/134C08K5/372C08K5/098C08J9/32
CPCC08J9/32C08J2323/12C08K2201/011C08L23/12C08L2201/08C08L2203/14C08L2205/03C08L45/00C08L83/04C08K13/06C08K9/10C08K3/36C08K3/34C08K3/346C08K5/1345C08K5/372C08K5/098
Inventor 汪品洋
Owner DONGGUAN JISU PLASTIC TECH
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