Environment-friendly adhesive
An adhesive and environmentally friendly technology, applied in the directions of adhesive additives, adhesive types, starch-derived adhesives, etc. Cohesive, fast drying effect
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Embodiment 1
[0018] A kind of environmental protection adhesive, comprises the following steps:
[0019] (1) Phenolic modification of starch: put starch, phenol, sodium hydroxide and water into the reaction kettle in turn, heat to 80°C, stir at constant temperature at 1500r / min for 2 hours, then adjust the temperature to 55°C, Stir at a speed of 500r / min for 30min, cool naturally to room temperature, and obtain a phenolized starch solution for use; the mixing mass ratio of the starch, phenol, sodium hydroxide and water is 12:1.3:2.5:40;
[0020] (2) Modified rosin resin: Add rosin resin to the reaction kettle, and then add catalyst, the amount of catalyst is 0.15% of the mass of rosin resin, control the catalyst to be added dropwise within 50 minutes; stir to raise the temperature to 105°C, add pentaerythritol, pentaerythritol Be 1:20 with the mass ratio of rosin resin, keep temperature and condense and reflux 1.5 hours, obtain mixture A; Described catalyzer is tetraethylammonium bromide; ...
Embodiment 2
[0028] A kind of environmental protection adhesive, comprises the following steps:
[0029] (1) Phenolic modification of starch: put starch, phenol, sodium hydroxide and water into the reaction kettle in turn, heat to 90°C, stir at constant temperature at 1500r / min for 2 hours, then adjust the temperature to 60°C, Stir at a speed of 500r / min for 40min, and cool naturally to room temperature to obtain a phenolized starch solution for use; the mixing mass ratio of the starch, phenol, sodium hydroxide and water is 15:1.3:2.5:40;
[0030] (2) Modified rosin resin: Add rosin resin to the reaction kettle, and then add catalyst, the amount of catalyst is 0.18% of the mass of rosin resin, control the catalyst to be added dropwise within 50 minutes; stir and heat up to 108°C, add pentaerythritol, pentaerythritol Be 1:20 with the mass ratio of rosin resin, keep temperature and condense and reflux 1.5 hours, obtain mixture A; Described catalyzer is tetraethylammonium bromide; In mixture ...
Embodiment 3
[0038] A kind of environmental protection adhesive, comprises the following steps:
[0039] (1) Phenolic modification of starch: Put starch, phenol, sodium hydroxide and water into the reaction kettle in turn, heat to 85°C, stir at constant temperature at 1500r / min for 2 hours, then adjust the temperature to 58°C, Stir at a speed of 500r / min for 36min, cool naturally to room temperature, and obtain a phenolized starch solution for use; the mixing mass ratio of the starch, phenol, sodium hydroxide and water is 14:1.3:2.5:40;
[0040](2) Modified rosin resin: Add rosin resin to the reaction kettle, and then add catalyst, the amount of catalyst is 0.16% of the mass of rosin resin, control the catalyst to be added dropwise within 50 minutes; stir and heat up to 106°C, add pentaerythritol, pentaerythritol Be 1:20 with the mass ratio of rosin resin, keep temperature and condense and reflux 1.5 hours, obtain mixture A; Described catalyzer is tetraethylammonium bromide; In mixture A, ...
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