Preparation method and application of biochar-based conditioner for cadmium contaminated soil
A technology for cadmium-contaminated soil and biochar, applied in the restoration of polluted soil, soil conditioning materials, applications, etc., can solve problems such as complicated processes and secondary pollution, achieve simple process, enhance passivation, and reduce phosphorus. effect of dissolution
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Embodiment 1
[0055] This embodiment is a preparation method of a biochar-based cadmium-contaminated soil conditioner, comprising the following steps:
[0056] 1) Mix wood chips and sludge at a mass ratio of 4:1 to prepare a mixture, adjust the moisture content to about 70%, and mix the limestone and the mixture again at a ratio of 5:1, and then carry out in an oxygen-free environment Carbonization, the temperature of carbonization is 600°C, and the carbonization time is 2h to prepare calcium-loaded biochar; wherein the content of organic matter in the sludge is 30%;
[0057] 2) Mix zeolite powder and potassium dihydrogen phosphate in a mass ratio of 8:1, add 1.2 times of water and stir evenly, and leave for 1 hour to obtain phosphorus-modified zeolite;
[0058] 3) Mix calcium-containing biochar and phosphorus-containing zeolite powder at a mass ratio of 5:1, and add modified starch with a mass percentage of 1%, keep the moisture content at 20%, age for 4 days, and dry through a 10-mesh sie...
Embodiment 2
[0060] This embodiment is a preparation method of a biochar-based cadmium-contaminated soil conditioner, comprising the following steps:
[0061] 1) Mix sawdust and sludge at a mass ratio of 3:1 to prepare a mixture, adjust the moisture content to about 80%, mix raw gypsum and the mixture again at a ratio of 5:1, and carry out the process in an oxygen-free environment. Carbonization, the temperature of carbonization is 400°C, and the carbonization time is 2h to prepare calcium-loaded biochar; wherein the content of organic matter in the sludge is 30%;
[0062] 2) Mix zeolite powder and potassium dihydrogen phosphate in a mass ratio of 6:1, add 1.2 times of water and stir evenly, and leave for 1 hour to obtain phosphorus-modified zeolite;
[0063] 3) Mix calcium-containing biochar and phosphorus-containing zeolite powder at a mass ratio of 5:1, and add modified starch with a mass percentage of 1%, keep the moisture content at 25%, age for 4 days, and dry through a 10-mesh sieve...
Embodiment 3
[0065] This embodiment is a preparation method of a biochar-based cadmium-contaminated soil conditioner, comprising the following steps:
[0066] 1) Mix wood chips and sludge at a mass ratio of 4:1 to prepare a mixture, adjust the moisture content to about 80%, mix raw gypsum and the mixture again at a ratio of 3:1, and carry out the process in an oxygen-free environment. Carbonization, the temperature of carbonization is 480°C, and the carbonization time is 2h to prepare calcium-loaded biochar; wherein the content of organic matter in the sludge is 30%;
[0067] 2) Mix zeolite powder and potassium dihydrogen phosphate at a mass ratio of 6:1, add 1.5 times of water, stir evenly, and leave for 1 hour to obtain phosphorus-modified zeolite.
[0068] 3) Mix calcium-containing biochar and phosphorus-containing zeolite powder at a mass ratio of 4:1, add 1% modified starch by mass, keep the moisture content at 25%, age for 6 days, and dry through a 10-mesh sieve , to produce biochar...
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