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Polyamide compound for environment-friendly electroplating and preparation method thereof

A technology of aromatic ring polyamide and polyamide, which is applied in the field of polyamide composites for environmental protection electroplating and its preparation, and can solve problems such as allergies, inability to meet the adhesion requirements of metal electroplating products, and low bonding strength of substrate electroplating

Active Publication Date: 2018-02-06
JIANGMEN DENGZHONGTAI ENG PLASTICS CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Hexavalent chromium is an ingestion poison / inhalation poison, and skin contact may cause allergies; it is more likely to cause genetic defects, inhalation may cause cancer, and has a persistent danger to the environment
The major defects of existing electroplating grade nylon materials are: 1. Need to use special nylon electroplating potion; 2. The bonding force of substrate electroplating is not high, which cannot meet the adhesion requirements of metal electroplating products; 3. The production is not flexible, High cost, the cost of traditional nylon electroplating process is about 2.4 yuan / DM, while the cost of ABS electroplating process is about 1.2 yuan / dm
Therefore, its market application is not as broad as that of ABS

Method used

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  • Polyamide compound for environment-friendly electroplating and preparation method thereof
  • Polyamide compound for environment-friendly electroplating and preparation method thereof
  • Polyamide compound for environment-friendly electroplating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0088] A kind of polyamide compound that is used for environment-friendly electroplating, comprises following raw material (raw material total weight 10KG) by weight percentage:

[0089] PA6T / 66 90%,

[0090] TPE 10%.

[0091]The above-mentioned preparation method for the polyamide compound of environmental protection electroplating, comprises the following steps:

[0092] Adding PA6T / 66 and TPE into a twin-screw extruder through a main feeder for melt polymerization, and strand cutting to obtain the polyamide compound of the present invention.

Embodiment 2

[0094] A kind of polyamide compound that is used for environment-friendly electroplating, comprises following raw material (raw material total weight 10KG) by weight percentage:

[0095]

[0096] The above-mentioned preparation method for the polyamide compound of environmental protection electroplating, comprises the following steps:

[0097] (1) Add PA6T / 66 and TPE to the twin-screw extruder through the main feeder to carry out melt polymerization, and pelletize the strands to obtain the blend, which is set aside;

[0098] (2) Add inorganic mineral powdered alumina into the high mixer, raise the temperature of inorganic mineral powdered alumina to 120°C, then add silane coupling agent KH550 for reaction, the reaction time is 30 minutes, take it out for use;

[0099] (3) The blend that step (1) obtains and SEED are joined in the twin-screw extruder by main feeder, and the inorganic ore powder aluminum oxide that is processed through step (2) is added in side feeder simulta...

Embodiment 3

[0101] A kind of polyamide compound that is used for environment-friendly electroplating, comprises following raw material (raw material total weight 10KG) by weight percentage:

[0102]

[0103] The above-mentioned preparation method for the polyamide compound of environmental protection electroplating, comprises the following steps:

[0104] (1) PA12T and TPO are added to the twin-screw extruder through the main feeder to carry out melt polymerization, and the strands are pelletized to obtain the blend, which is set aside;

[0105] (2) Add inorganic mineral powdered alumina into the high mixer, raise the temperature of inorganic mineral powdered alumina to 120°C, then add silane coupling agent KH550 for reaction, the reaction time is 30 minutes, take it out for use;

[0106] (3) The blend that step (1) obtains and SEED are joined in the twin-screw extruder by main feeder, add the inorganic mineral powder alumina and the processing through step (2) in side feeder simultane...

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PUM

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Abstract

The invention provides a polyamide compound for environment-friendly electroplating. The polyamide compound is prepared from the following raw materials in percentage by weight: 40 percent to 90 percent of aromatic-ring-containing polyamide resin, 3 percent to 20 percent of a thermoplastic elastomer, 0 percent to 20 percent of aliphatic polyamide, 0 percent to 2 percent of a coupling agent and 0 percent to 40 percent of inorganic ore powder, wherein the melt index of the thermoplastic elastomer is higher than that of the aromatic-ring-containing polyamide resin and the aliphatic polyamide. Theinvention further provides a preparation method of the polyamide compound for the environment-friendly electroplating; the polyamide compound provided by the invention has better electroplating performance and mechanical property and can be treated by utilizing an environment-friendly potassium permanganate roughening solution, so that the polyamide compound is suitable for the development of theenvironment-friendly electroplating; after the electroplating is carried out, the electroplating binding force between the polyamide compound and the surface of an electroplating cladded layer can reach 10N or more; the utilization safety is ensured.

Description

technical field [0001] The invention belongs to the technical field of polymer materials, and in particular relates to a polyamide compound used for environmental protection electroplating and a preparation method thereof. Background technique [0002] Plastic electroplating can make the surface of plastic products have a metallic luster, which is beautiful, plays a decorative role, improves the mechanical strength of the product surface, and prolongs the service life; makes plastic products have high stability against external factors such as light and atmosphere, and is not easy to age; Plastics are electrically conductive, magnetically conductive and weldable. Plastic electroplating products can be used in industries such as aerospace, shipbuilding, automobiles, electronic appliances, architectural decoration, toys and daily necessities, and have a wide range of uses. [0003] There are two common electroplating processes for plastic products: water electroplating and va...

Claims

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Application Information

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IPC IPC(8): C08L77/06C08L77/02C08L23/00C08L67/00C08L53/02C08K9/06C08K9/04C08K3/34C08K3/36C08K3/22C08K7/14C08K7/06
CPCC08K2003/2227C08K2201/003C08L77/06C08L2201/08C08L2205/02C08L2205/03C08L2207/04C08L77/02C08L23/00C08L67/00C08L53/02C08L53/025C08K9/06C08K9/04C08K3/34C08K3/22C08K3/36C08K7/14C08K7/06
Inventor 金良文梁永华郑红专
Owner JIANGMEN DENGZHONGTAI ENG PLASTICS CO LTD
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