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A kind of hollow pva fiber and its preparation method and application

A fiber and hollow technology, which is applied in the field of hollow PVA fiber and its preparation, can solve the problems of poor use effect, degradable performance, and high temperature resistance, acid and alkali resistance in the field of oil and gas fields, and achieves the promotion of secondary exploitation, increased income, and good adhesion. , the effect of improving stability

Active Publication Date: 2019-09-03
CHINA PETROCHEMICAL CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although domestic and foreign colleagues have made a lot of efforts, so far, the existing fracturing technology still cannot achieve the purpose of reducing the damage of fracturing fluid to the reservoir and improving the sand-carrying performance. The existing fiber Due to its degradable properties and limitations in high temperature, acid and alkali resistance, it is not well used in oil and gas fields.

Method used

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  • A kind of hollow pva fiber and its preparation method and application
  • A kind of hollow pva fiber and its preparation method and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0044] Preparation of hollow PVA fibers:

[0045] (1) Preparation of spinning stock solution: the degree of polymerization is 1800, the degree of alcoholysis is 99.5 (mol)% PVA and copper sulfate, titanium tetrachloride, boric acid are dissolved in water and made into spinning stock solution, wherein PVA is in the stock solution The mass concentration of copper sulfate is 15%, the mass concentration of copper sulfate relative to PVA is 3.5%, the mass concentration of titanium tetrachloride relative to PVA is 1.0%, and the mass concentration of boric acid relative to PVA is 1.2%, the stock solution is heated up to 105~ 110°C, keep the pressure 0.01-0.15MPa, dissolve for 14-15 hours and enter the spinning process. At this time, take a part of the stock solution and lower the temperature to 50°C to measure its viscosity to be 8000mPa·s.

[0046] (2) Spinning: The PVA stock solution is sent to the spinning assembly by a metering pump, and the PVA stock solution is sprayed into th...

Embodiment 2

[0049] Prepare hollow PVA fibers with reference to Example 1, wherein PVA fibers are prepared by spinning polyvinyl alcohol with a degree of polymerization of 2000 and a degree of alcoholysis of 99.5 (mol), the section of the PVA fibers is a hollow structure, and the diameter of the hollow part is 50 μm, the PVA fiber contains copper element, the mass content of copper element in the PVA fiber is 0.08%, and the PVA fiber also contains polyethylene glycol with a molecular weight of 1000.

Embodiment 3

[0051] Prepare hollow PVA fibers with reference to Example 1, wherein PVA fibers are prepared by spinning polyvinyl alcohol with a degree of polymerization of 1700 and a degree of alcoholysis of 99.0 (mol). The section of the PVA fibers is a hollow structure, and the diameter of the hollow part is 70 μm, the PVA fiber contains copper and titanium elements, the mass content of copper and titanium in the PVA fiber is 1.5%, and the PVA fiber also contains polyethylene glycol with a molecular weight of 1500.

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Abstract

Hollow PVA fiber is prepared from PVA with the polymerization degree being 1,000-3,500 and the alcoholysis degree being 99.0-99.9(mol)% through spinning, wherein the section of the PVA fiber adopts a hollow structure, and the diameter of the hollow part is 0.1-100 mu m. The hollow PVA fiber is added to an oil and gas field fracturing fluid, so that the fracturing fluid has very good sand-carrying capacity, flowback of the fracturing fluid is facilitated, the usage amount of guar gum and other components which are difficult to dissolve completely and difficult to discharge from the bottom of a well can be reduced, and damage to environment is reduced; the hollow PVA fiber can improve the strength and the toughness of a cementing material and can also perform a leakage prevention function after being added to an oil and gas field cementing agent; the hollow PVA fiber has good filtration reduction function after being added to a temporary plugging agent used during fracturing of an oil and gas field and can form a shielding layer at to-be-temporarily plugged part, so that smooth diversion of the fracturing fluid can be realized. Components remaining in the environment can be decomposed into non-toxic hydrocarbon finally and cannot damage to the environment.

Description

technical field [0001] The invention relates to PVA fibers, in particular to a hollow PVA fiber and its preparation method and application. Background technique [0002] my country's low-permeability oil and gas resources are huge, accounting for more than 70% of the total proven reserves, and are the main potential areas for increasing reserves and production in the future. This type of oil and gas resources has the characteristics of three lows, that is, low proven rate, low natural production rate, and low recovery rate. The practical application shows that in the exploitation of such oil and gas fields, there is an urgent need for well-functioning cementing agents, fracturing temporary plugging agents, and oil and gas field fracturing fluids that can play a good role in carrying sand. At the same time, it is necessary to minimize the damage to the environment . [0003] In recent years, researchers at home and abroad have carried out a lot of research on fracturing, ce...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D01F6/50D01F1/10D01D5/06C09K8/62
Inventor 王建李海英王华全蔡霞张振宇
Owner CHINA PETROCHEMICAL CORP
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