Method for removing pesticide residues from tea leaves through high-energy X-ray irradiation
A technology of pesticide residues and ray irradiation, applied in food science, tea treatment before extraction, etc., can solve problems such as difficult implementation in tea plantations, no commercial value, and tea is not durable to storage
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Embodiment 1
[0027] Example 1: The 7-day-old tea leaves applied with beta-cyfluthrin pesticide were picked normally, and the fresh tea leaves were roasted green, and the water content was controlled at more than 15%. Put the fried green tea into a food-grade polyethylene plastic bag, put a GEX B3 radiochromic film dosimeter (or phenylalanine dosage film) in the bag, seal it and put it into a carton of 500×500×200mm (length, width and height) Inside, it was irradiated with an X-ray beam with an energy of 7 MeV and a beam current of 5 mA. Since a single carton is irradiated, the carton full of tea leaves is fixed under the X-ray beam for irradiation. After the cumulative irradiation dose is 250kGy, it is removed from the X-ray.
[0028]After standing for 1 day, carry out the detection of pesticide residues according to the test method of GB 2763-2016, first carry out quantitative detection with a rapid pesticide detection instrument, and then carry out precise detection with liquid chromatog...
Embodiment 2
[0029] Embodiment 2: the tea tree that has applied imidacloprid according to the normal dosage is picked fresh tealeaves after 7 days, and water content is not less than 15%, carries out irradiation according to the method of the present invention (with the conveying speed of 1-3m / min through irradiation According to the room, with the energy of 5-10MeV, beam current is 4-7mA high-energy X-rays irradiate), different doses of radiation, respectively 150kGy, 200kGy, 300kGy, 350kGy, 400kGy and other doses, the same as example 1 In the post-processing method, sampling, sample preparation, and testing, it was found that with an irradiation dose of 350kGy, the detection value of imidacloprid was 0.28±0.019mg / kg, which met the limit requirement of 0.5mg / kg in GB2763-2016.
Embodiment 3
[0030] Embodiment 3: With the fully processed tea leaves such as Dahongpao of oolong tea, Chuanhong of black tea, Anhua black tea of black tea, etc., the water content is in the range of 2-4%, spraying imidacloprid and beta-cyfluthrin respectively Pesticides such as , buprofezin, place more than 7 days, preferably 10 days, irradiate according to the inventive method (passing through the irradiation chamber with the transmission speed of 2m / min, with energy being 7MeV, beam current being 5mA high-energy X- ray irradiation), doses such as 150kGy, 200kGy, 300kGy, 350kGy, 400kGy respectively, and then sampling, sample preparation, and detection by the method of example 1. The results show that the X-ray beam with an energy of 7 MeV and a beam current of 5mA is less effective in removing residues in dry finished tea than in semi-finished tea with high water content, especially for the removal of imidacloprid and buprofezin. The effect is even worse. Therefore, the method for rem...
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