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Composition for foaming material with high rebound resilience and preparation method thereof

A technique for foaming materials and compositions, which is applied in the field of compositions for high-resilience foaming materials and its preparation, and can solve problems such as reduced service performance, poor wear resistance, and poor resilience of foaming materials, and reduce interfacial tension , The process is simple, the effect of improving the resilience

Inactive Publication Date: 2017-09-12
MIRACLL CHEM
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, high expansion ratio olefin polymer foaming materials have poor resilience, large permanent deformation, serious decline in mechanical properties, and poor wear resistance, which greatly reduces their performance and seriously affects their application range.

Method used

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  • Composition for foaming material with high rebound resilience and preparation method thereof
  • Composition for foaming material with high rebound resilience and preparation method thereof
  • Composition for foaming material with high rebound resilience and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] A composition for foaming materials with high resilience, comprising the following components in parts by weight:

[0034]

[0035] Prepare the foamed product as follows:

[0036] 1) Base material preparation: in the process of adopting the one-step method known in the art to produce TPU, EVA-1, EVA-2, EVA grafted maleic anhydride are added in the extruder by side feeding screw, control extruding screw The temperature is 100-190°C, the temperature of the die head is controlled at 150°C, and the base material is obtained through extrusion and granulation;

[0037] 2) Preparation of high-resilience foaming material: mix the base material prepared in step 1), 0.1 part of azodicarbonamide, and 0.01 part of DCP through a high-mixer and put them into the product mold. The temperature of the flat vulcanizer is 100 ° C , molded and foamed for 1 minute, and then cooled the mold to 5° C. to obtain the final high-resilience foamed product material.

[0038] The physical prope...

Embodiment 2

[0040] A composition for foaming materials with high resilience, comprising the following components in parts by weight:

[0041]

[0042] Prepare the foamed product as follows:

[0043]1) Base material preparation: in the process of adopting the one-step method known in the art to produce TPU, EVA-1, EVA-2, EVA grafted maleic anhydride are added in the extruder by side feeding screw, control extruding screw The temperature is 100-190°C, the temperature of the die head is controlled at 150°C, and the base material is obtained through extrusion and granulation;

[0044] 2) Preparation of high-resilience foaming material: mix the base material prepared in step 1), 1 part of azodicarbonamide, and 0.05 part of DCP through a high-speed mixer and put them into the product mold. The temperature of the flat vulcanizer is 100 °C , molded and foamed for 1 minute, and then cooled the mold to 5° C. to obtain the final high-resilience foamed product material.

[0045] The physical pro...

Embodiment 3

[0047] A composition for foaming materials with high resilience, comprising the following components in parts by weight:

[0048]

[0049]

[0050] Prepare the foamed product as follows:

[0051] 1) Preparation of base material: adopt the one-step method known in the art to produce TPU particles, then add TPU particles and EVA-1, EVA grafted maleic anhydride to a twin-screw extruder after mixing with a high mixer, and control extrusion The temperature of the screw is 100-190°C, the temperature of the die head is controlled at 150°C, and the base material 1 is obtained by extrusion and granulation; then the base material 1 and EVA-2 are mixed by a high-speed mixer and added to the twin-screw or internal mixer , mixed uniformly and then extruded and granulated to obtain the final base material 2;

[0052] 2) Preparation of high-resilience foaming material: base material 2 prepared in step 1), 1.5 parts of azodicarbonamide, 0.1 part of DCP are mixed uniformly by a high-mix...

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Abstract

The invention relates to a composition for foaming material with high rebound resilience and a preparation method thereof. The composition is prepared from the following components in parts by weight: 5 to 95 parts of alkene polymer, 5 to 95 parts of TPU (thermoplastic polyurethane) elastomer, 0.1 to 45 parts of compatilizer, 0.1 to 10 parts of foaming agent, 0.01 to 5 parts of crosslinking agent, 0 to 5 parts of crosslinking additive, and 0 to 10 parts of other additive. The composition has the advantages that by utilizing the comptilzier with polarity groups or double active groups, the interface tension between the alkene polymer and TPU is reduced, an alkene polymer / TPU IPN (inter-penetrating polymer network) structure is formed, and the problem of compatibility between two types of materials is solved; by successfully introducing the TPU component into the alkene polymer, the excellent resilience of TPU is utilized, and the rebound resilience, compression permanent deformation and the like of the alkene polymer are greatly improved.

Description

technical field [0001] The invention relates to a composition for high-resilience foaming materials and a preparation method thereof, belonging to the field of lightweight materials. Background technique [0002] Olefin polymer foaming materials (such as EVA, SEBS, POE, etc.) have good softness, rubber-like elasticity, good flexibility below 0°C, good chemical stability, anti-aging and With good ozone strength, it is widely used in foamed shoe materials, luggage linings, toy materials, sporting goods materials, building materials, and various emerging applications including electronic accessories and automotive interiors. [0003] However, high expansion ratio olefin polymer foaming materials have poor resilience, large permanent deformation, serious decline in mechanical properties, and poor wear resistance, which greatly reduces their performance and seriously affects their application range. Thereby, develop a kind of high resilience, and can keep the olefinic polymer / TP...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L75/06C08L51/06C08L75/08C08L53/02C08L51/00C08K5/14C08L23/16C08L63/08C08J9/10C08J9/08C08J9/32
CPCC08J9/08C08J9/102C08J9/103C08J9/105C08J9/32C08J2203/02C08J2203/04C08J2203/22C08J2323/08C08J2323/16C08J2353/02C08J2375/08C08J2423/08C08J2453/02C08J2475/06C08J2475/08C08L23/0815C08L23/0853C08L23/16C08L53/025C08L75/06C08L75/08C08L2203/14C08L2205/025C08L2205/03C08L2205/035C08L51/06C08K5/14C08L51/006C08L63/08C08G18/4277C08G18/44C08G18/833C08G18/85C08G18/86C08G2270/00C08J9/0061C08L75/04C08G2110/0008C08G2110/0066C08L53/02C08L59/02C08L23/14C08L23/26
Inventor 王光阜战振生张生王仁鸿
Owner MIRACLL CHEM
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