Adhesives, Adhesive Sheets, and Displays
A technology of adhesive sheets and displays, applied in the direction of adhesives, adhesive types, ester copolymer adhesives, etc., can solve the problems of light reflection loss, etc., and achieve the effect of excellent step followability and high film strength
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Embodiment 1
[0152] 1. Preparation of (meth)acrylate polymer
[0153] Copolymerize 90 parts by mass of n-butyl acrylate and 10 parts by mass of acrylic acid to prepare a (meth)acrylate polymer (A), and measure the molecular weight of the (meth)acrylate polymer (A) by the method described later , The weight average molecular weight (Mw) is 400,000.
[0154] 2. Preparation of Adhesive Composition
[0155] 100 parts by mass of the (meth)acrylate polymer (A) obtained in the above step (1) (value in terms of solid content; the same applies below), and tris(propylene) as the active energy ray-curable component (B) Acyloxyethyl) isocyanurate (manufactured by TOAGOSEI CO., LTD., product name "M-315") 0.1 parts by mass, and 1,3-bis( N,N-diglycidylaminomethyl)cyclohexane (manufactured by MITSUBISH GAS CHEMICAL COMPANY, INC., product name "TETRAD-C", solid content concentration: 100% by mass) 0.05 parts by mass, and as silane coupling 0.2 parts by mass of 3-glycidyloxypropyltrimethoxysilane (manuf...
Embodiment 2~17、 comparative example 1~4
[0185] In addition to the proportion of each monomer constituting the (meth)acrylate polymer (A), the weight average molecular weight of the (meth)acrylate polymer (A), the type of active energy ray-curable component (B) and the addition The amount, the type and addition amount of the crosslinking agent (C), and the addition amount of the silane coupling agent were changed as shown in Table 1, and an adhesive sheet was produced in the same manner as in Example 1. In addition, Comparative Examples 1 and 4 were not subjected to ultraviolet irradiation treatment.
[0186] Here, the above-mentioned weight average molecular weight (Mw) is the weight average molecular weight in terms of polystyrene measured by gel permeation chromatography (GPC) under the following conditions (GPC measurement).
[0187]
[0188] ・GPC measurement device: manufactured by TOSOH CORPORATION, HLC-8020
[0189] ・GPC column (passed in the following order): manufactured by TOSOH CORPORATION
[0190] TSK...
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