Curing agent for compound heavy metal polluted soil as well as preparation and application methods of curing agent

A heavy metal-contaminated soil and application method technology, which is applied in the direction of chemical instruments and methods, restoration and application of contaminated soil, can solve the problems of high greenhouse gas emissions, change of soil structure, high energy consumption of cement, etc., and reduce infiltration volume, increased adsorption, and good durability

Active Publication Date: 2017-07-25
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Commonly used curing agents mainly include materials such as cement, lime, and phosphate, which have a good effect on the solidification and stabilization of heavy metals, but there are also a large number of disadvantages, such as high energy consumption for cement production and high greenhouse gas emissions; lime and phosphate are Non-renewable natural minerals, high cost, etc.; and a large amount of phosphate will seriously change the soil structure and further cause phosphorus pollution of groundwater and surface water

Method used

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  • Curing agent for compound heavy metal polluted soil as well as preparation and application methods of curing agent
  • Curing agent for compound heavy metal polluted soil as well as preparation and application methods of curing agent
  • Curing agent for compound heavy metal polluted soil as well as preparation and application methods of curing agent

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] The curing agent used in the composite heavy metal polluted soil is composed of the following materials in parts by mass: 45% of steel slag powder; 20% of light-burned magnesium oxide; and 35% of phosphate activated bone powder.

[0028] The steel slag powder is activated steel slag powder prepared by the following method: the converter slag is subjected to magnetic separation and then crushed and sieved; in the obtained product, the material with a particle size of less than 2 mm is taken and placed in an oven to be dried by an airflow at a temperature of 105° C. Dry to a moisture content of 1%; the obtained product is ground and passed through a 200-mesh sieve, and then calcined in an electric furnace at 700° C. for 2 hours. The basicity value of the steel slag powder is 2.07.

[0029] The main components and content of this steel slag are shown in Table 1. It should be noted that the steel slag used in the present invention is not limited to the data in Table 1, but ...

Embodiment 2

[0042] The preparation process and curing process are the same as those in Example 1, the difference is that the dosage of the curing agent is 10% (the curing agent accounts for the dry weight of the heavy metal and organic compound polluted soil).

Embodiment 3

[0044] The preparation process and curing process are the same as those in Example 1, the difference is that the dosage of the curing agent is 15% (the curing agent accounts for the dry weight of the heavy metal and organic compound polluted soil).

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Abstract

The invention discloses a curing agent for compound heavy metal polluted soil as well as preparation and application methods of the curing agent. The curing agent is prepared from the following materials in percentage by mass: 40 to 65 percent of steel slag powder, 5 to 25 percent of light calcined magnesia and 20 to 45 percent of phosphate activated bone powder. The curing agent has the advantages that firstly, the curing agent can obviously reduce the mobility and the toxicity leaching amount of heavy metals in the heavy metal polluted soil, and is particularly applied to an acidic polluted land which is high in heavy metal content and contains various pollutants; after the polluted soil is repaired, the curing agent can be used as an environment-friendly material for recycling, so that the environmental risk during secondary development use of the polluted land is obviously reduced; moreover, as the raw materials are readily available, the curing agent is low in cost, easy to prepare, convenient to use and stable in effect and can be popularized and applied to curing and stabilizing repairing of the compound polluted land in a large scale.

Description

technical field [0001] The invention relates to the field of environmental geotechnical engineering, in particular to a curing agent for composite heavy metal polluted soil and a preparation and application method. Background technique [0002] With the adjustment of urban functions and urban layout in my country, enterprises originally located in the central and suburban areas of the city, such as chemical plants, metal smelters, electroplating plants, etc., have gradually closed down or retreated to the city to enter the park. However, the production process of industries and enterprises for many years , accumulated a large amount of pollutants in the land left after its relocation, which not only brought resistance to the efficient use of the land, but also brought serious safety hazards to the surrounding environment. In recent years, the "Soil Pollution Prevention and Control Action Plan" (Ten Articles) promulgated by the government also regards contaminated soil remedia...

Claims

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Application Information

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IPC IPC(8): C09K17/04C09K17/08B09B3/00B09C1/08
CPCB09B3/00B09C1/08C09K17/04C09K17/08
Inventor 冯亚松杜延军夏威夷伍浩良
Owner SOUTHEAST UNIV
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