Current collector, pole piece using same and battery
A current collector and pole piece technology, applied in the direction of batteries, battery electrodes, secondary batteries, etc., can solve problems such as thermal runaway, inability to effectively suppress short-circuit probability, temperature rise, and fire, so as to suppress Joule heat and improve overcharging Safety performance, the effect of improving safety performance
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preparation example Construction
[0089] One, the preparation method of current collector at least comprises the following steps:
[0090] 1. Preparation of PPTC material layer: According to the mass fraction, after melting 60-90% of the polymer, add 10%-40% of conductive agent, mix well and pour into the mold to form the PPTC material layer of required thickness; preferably Yes, the reaction temperature is between 70°C and 160°C depending on the type of polymer used.
[0091] 2. Preparation of current collector: prepare a metal layer on at least one surface of the PPTC material layer by mechanical rolling, bonding, vapor deposition, and electroless plating.
[0092] Second, the preparation of pole pieces:
[0093] 1. Preparation of electrode active material slurry: Add appropriate proportions of electrode active material, binder, and conductive agent to the organic solvent and stir and mix to obtain a uniformly dispersed slurry, with the solid content controlled within the range of 30% to 70%. , the viscosi...
Embodiment
[0100] (1) Preparation of electrolyte
[0101] Using 1M lithium hexafluorophosphate (LiPF 6 ) as a lithium salt, using a mass ratio of 50:50 EC:PC mixed non-aqueous solvent mixed as the electrolyte.
[0102] (2) Preparation of positive electrode current collector
[0103] According to the mass fraction, mix the conductive agent and the polymer according to the ratio shown in Table 1, and press the mold to form a PPTC material layer with a certain thickness after mixing evenly; Al is evaporated onto the thin layer PPTC material by evaporation, A uniformly distributed metal layer with a certain thickness is obtained, thereby obtaining the current collector of the embodiment of the present application.
[0104] The specific process of evaporation is: put the PPTC material layer after surface cleaning treatment in the vacuum coating room, melt and evaporate the high-purity metal wire in the metal evaporation room at a high temperature of 1600 ° C to 2000 ° C, and the evaporated ...
Embodiment 3
[0129] In Example 3, adjusting the thickness of the PPTC to 16 μm has no effect on the test results of the safety performance, but the increase of the thickness will lead to a decrease of the energy density.
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