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Ash residue treatment method and autoclaved brick manufacturing method

A technology for ash and slag treatment and autoclaved bricks, which is applied in the manufacture of combustible gas, bulk chemical production, gasification process, etc. The effect of shrinking and promoting digestion speed

Inactive Publication Date: 2017-05-24
ENN SCI & TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0003] In order to make full use of the useful components contained in the ash, in the prior art, the utilization of the ash generally adopts the methods of calcination and acid and alkali dissolution to extract alumina and rare metal Ga from the ash, such as patent CN 103349994A, The ash treatment methods mentioned in CN103351014A and CN 103991898A, looking at these methods, because they only realize the recycling of alumina and rare metals in the ash, they cannot recycle the residual alkali metal catalysts and slag in the ash. About 80% of the total mass of ash contains silicon, iron, calcium and other elements, which makes the comprehensive utilization rate of useful components in ash very low

Method used

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  • Ash residue treatment method and autoclaved brick manufacturing method
  • Ash residue treatment method and autoclaved brick manufacturing method
  • Ash residue treatment method and autoclaved brick manufacturing method

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Effect test

Embodiment 1

[0049] The ash processing method of the present embodiment adopts a one-step method to process ash, and the specific steps include the following processes:

[0050] According to the mass ratio of 60:40:120:1:75, gasification ash, calcium oxide, deionized water, natural gypsum, and stone chips are added to the reactor for reaction to obtain a one-step reaction mixed system. Calcium oxide will The water-insoluble catalyst in the gasification ash is digested into a water-soluble catalyst, and the water-soluble catalyst in the gasification ash is extracted with deionized water; the reaction temperature is 120°C, the reaction pressure is 0.2MPa, and the reaction time is 2h. in,

[0051] In the calcium oxide used, the mass percentage of calcium oxide with a particle diameter greater than 0.080mm is 20%, the mass percentage of calcium oxide with a particle diameter less than 0.080mm is 80%, and the mass percentage of calcium oxide with a particle diameter greater than 0.20mm is 10%; ...

Embodiment 2

[0057] The ash processing method of the present embodiment adopts a one-step method to process ash, and the specific steps include the following processes:

[0058] According to the mass ratio of 80:20:400:3:40, gasification ash, calcium hydroxide, tap water, desulfurized gypsum, and sand are added to the reactor for reaction to obtain a one-step reaction mixed system. The water-insoluble catalyst in the gasification ash is digested into a water-soluble catalyst, and tap water is used to extract the water-soluble catalyst in the gasification ash; the reaction temperature is 200°C, the reaction pressure is 1.6MPa, and the reaction time is 2h. in,

[0059] In the calcium hydroxide used, the mass percentage of calcium hydroxide with a particle diameter greater than 0.080mm is 18%, the mass percentage of calcium hydroxide with a particle diameter less than 0.080mm is 88%, and the mass percentage of calcium hydroxide with a particle diameter greater than 0.20mm Among the gasificat...

Embodiment 3

[0065] The ash processing method of the present embodiment adopts a one-step method to process ash, and the specific steps include the following processes:

[0066] According to the mass ratio of 120:10:10:960:7:40, gasification ash, calcium hydroxide, calcium oxide, water washing tower wastewater, phosphogypsum, and stone chips are added to the reactor for reaction to obtain a one-step reaction Mixed system, calcium hydroxide digests the non-water-soluble catalyst in the gasification ash into a water-soluble catalyst, and the water-soluble catalyst in the gasification ash is extracted from the wastewater of the water washing tower; the reaction temperature is 280°C, and the reaction pressure is 6.5MPa , The reaction time is 2h. in,

[0067] In the calcium hydroxide used, the mass percentage of calcium hydroxide with a particle diameter greater than 0.080mm is 20%, the mass percentage of calcium hydroxide with a particle diameter less than 0.080mm is 80%, and the mass percentag...

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Abstract

The invention discloses an ash residue treatment method and an autoclaved brick manufacturing method, relating to the technical field of catalytic coal gasification and aiming at solving the problem of very low comprehensive utilization ratio of useful components in ash residue. The ash residue treatment method comprises the step of treating the ash residue to be treated by using a digesting agent and washing liquor. The autoclaved brick manufacturing method comprises the steps of pressing the ash residue treated by the ash residue treatment method into an autoclaved brick green body, and carrying out steam press maintenance on the autoclaved brick green body to obtain an autoclaved brick. The ash residue treatment method and the autoclaved brick manufacturing method have the beneficial effects that the ash residue is treated to obtain a catalyst and an autoclaved brick raw material in the ash residue, the autoclaved brick raw material is manufactured into an autoclaved brick, and the comprehensive utilization ratio of the useful components in the ash residue is improved.

Description

technical field [0001] The invention relates to the technical field of coal catalytic gasification, in particular to an ash treatment method and an autoclaved brick manufacturing method. Background technique [0002] Catalytic coal gasification refers to the catalytic gasification reaction of pulverized coal and water vapor under the conditions of medium-low temperature and high pressure, through the catalytic action of alkali metal catalyst, to generate CH-rich gas. 4 Gas and a lot of ash. Since coal powder is catalyzed by alkali metal catalysts for catalytic gasification, the ash generated after coal catalytic gasification is rich in alkali metal catalysts and elements such as iron, calcium, silicon, and aluminum. [0003] In order to make full use of the useful components contained in the ash, in the prior art, the utilization of the ash generally adopts the methods of calcination and acid and alkali dissolution to extract alumina and rare metal Ga from the ash, such as ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C10J3/72C04B28/02
CPCY02P20/52Y02P20/584C10J3/72C04B28/021C10J2300/093C10J2300/0976C10J2300/0986C10J2300/1628C04B22/143C04B14/06C04B14/02C04B22/064C04B40/024
Inventor 芦涛毛燕东刘雷李克忠
Owner ENN SCI & TECH DEV
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