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Ore dressing method of copper-cobalt ores

A beneficiation method, copper-cobalt technology, applied in the direction of chemical instruments and methods, wet separation, solid separation, etc., can solve the problems of reducing the recovery rate of other valuable metals, waste of resources, low metal recovery rate, etc., and achieve the improvement of copper-cobalt Sorting efficiency, strong ore adaptability and strong controllability

Inactive Publication Date: 2017-05-10
BEIJING GENERAL RES INST OF MINING & METALLURGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The beneficiation and enrichment methods of copper-cobalt ore in the prior art mainly include: 1) ore washing—the main methods are mechanized ore washing and manual elutriation, and part of the silt in the ore is removed by washing to achieve the purpose of improving the ore grade. The operation is simple, but the metal recovery rate is low, and it is basically close to elimination; 2) Dense medium (HMS) beneficiation - a method of beneficiation using a heavy medium with a density greater than water as the separation medium, but the metal recovery rate of this process is low, usually at 60 % or less, resulting in a great waste of resources; 3) flotation - is the most commonly used method to deal with copper-cobalt sulfide ore, the main process includes copper-cobalt priority flotation and copper-cobalt mixed flotation, and then use other methods to separate , but limited by the existing technology, it is difficult to effectively separate copper-cobalt ore by using flotation methods. While pursuing a single element concentrate, it will reduce the recovery rate of other valuable metals and increase production costs

Method used

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  • Ore dressing method of copper-cobalt ores

Examples

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Effect test

Embodiment 1

[0042] Example 1. The raw ore copper grade of a copper-cobalt ore is 1.56%, and the cobalt grade is 0.12%. The process mineralogy research shows that the copper-containing minerals in this ore are mainly chalcopyrite and bornite, and the cobalt-containing minerals are mainly sulfur-copper-cobalt ore. And pyrite containing cobalt.

[0043] The ore is ground with a wet ball mill, and the particle size of the ground product is -0.074mm, accounting for 65%. Lime is added during the grinding process, and the pH value of the slurry is adjusted to 9.6. The combination of butyl xanthate and butylammonium black medicine is used as the collection The mixed flotation of copper and cobalt is carried out with terpineol oil as a foaming agent. The mixed flotation includes one roughing, two sweeping and three refining. The amount of roughing collector is 80g / t, and the amount of foaming agent is 20g / t. t, the amount of agent used for sweeping is gradually reduced to one-third of that of roug...

Embodiment 2

[0047]Example 2, the raw ore copper grade of a copper-cobalt ore is 1.62%, and the cobalt grade is 0.13%. The process mineralogy research shows that the copper-containing minerals in the ore are mainly chalcopyrite, accompanied by a small amount of bornite and chalcocite, etc., containing Cobalt minerals are mainly sulfur-copper-cobalt ore.

[0048] The ore is ground by a wet ball mill, and the particle size of the ground product is -0.074mm, accounting for 65%. Lime is added during the grinding process, and the pH value of the slurry is adjusted to 9.5. The combination of butyl xanthate and butylammonium black medicine is used as a collection The mixed flotation of copper and cobalt is carried out with terpineol oil as a foaming agent. The mixed flotation includes one roughing, two sweeping and three refining. The amount of roughing collector is 80g / t, and the amount of foaming agent is 20g / t. t, the amount of agent used for sweeping is gradually reduced to one-third of that ...

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Abstract

The invention discloses an ore dressing method of copper-cobalt ores. The ore dressing method comprises the following steps: first, carrying out ore grinding treatment on copper-cobalt raw ores, adding a certain quantity of regulator in an ore grinding process, and regulating the pH value of ore slurry within a 9-10 range; sequentially adding a collector and a foaming agent into the ore slurry which is treated by ore grinding, carrying out copper-cobalt bulk flotation rough concentration, and after scavenging twice, obtaining tailings; adding an inhibitor into bulk flotation foams, and after carrying out fine concentration for three times, obtaining copper-cobalt bulk concentrates; using the copper-cobalt bulk concentrates as fed ores, carrying out regrinding treatment, adding a certain quantity of regulator in a regrinding treatment process, and regulating the pH value of the ore slurry within a 12-13 range; sequentially adding an inhibitor and a collector into the ore slurry which is treated by regrinding, carrying out copper-cobalt separating flotation, and obtaining cobalt concentrates after one rough concentration and one scavenging; and after carrying out fine concentration twice on the foams which are subjected to copper-cobalt separating flotation, obtaining copper concentrates. The method can effectively separate the copper-cobalt ores and obtain high-quality copper and cobalt concentrates.

Description

technical field [0001] The invention relates to the technical field of beneficiation, in particular to a beneficiation method of copper-cobalt ore. Background technique [0002] my country is a country seriously deficient in cobalt resources. With the rapid economic development in recent years, especially the rapid development of the lithium battery industry, the demand for cobalt is increasing day by day. Cobalt is associated with other elements in most cases. Copper-cobalt ore is the main source of cobalt. Copper minerals in sulfide ores mainly include chalcopyrite, bornite, chalcocite, etc. Cobalt minerals are copper-cobalt sulfide ore. [0003] The beneficiation and enrichment methods of copper-cobalt ore in the prior art mainly include: 1) ore washing-the main methods are mechanized ore washing and manual elutriation, and part of the silt in the ore is removed by washing to achieve the purpose of improving the ore grade. The operation is simple, but the metal recovery ...

Claims

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Application Information

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IPC IPC(8): B03B7/00
CPCB03B7/00
Inventor 叶岳华李成必王立刚田祎兰曾克文刘万峰周高云刘水红陈旭波胡志强
Owner BEIJING GENERAL RES INST OF MINING & METALLURGY
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