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Preparation method of stable-type odor-free low-density foam concrete foamer

A foamed concrete and low-density technology, applied in the field of concrete foaming agents, can solve the problems of unsuitability for low-density foamed concrete, unsatisfactory foaming ratio, poor foam stability, etc., and achieves simple process, easy operation and high foaming efficiency. Effect

Active Publication Date: 2017-04-26
福建科胜加固材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The technical problem mainly solved by the present invention is: aiming at the problems of poor foam stability, unsatisfactory expansion ratio and strong odor during use of the traditional concrete foaming agent during use, it is not suitable for preparing low-density foam concrete. A stable odorless low-density foam concrete foaming agent was prepared by compounding humic acid extraction concentrate, secondary sedimentation tank activated sludge deodorized by vermicompost extract concentrate and sodium dodecylbenzenesulfonate method
The invention utilizes octadecyltrimethylammonium chloride to balance the hydrophobicity and oleophobicity of small molecular substances in humic acid, and through compounding with protein and sodium dodecylbenzenesulfonate in activated sludge, it effectively solves the problem of traditional concrete The problem of poor stability of foaming agent and unsatisfactory foaming ratio, and the deodorization function of vermicompost solves the problem of strong odor of foaming agent

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0017] Weigh 100g of humic acid, pour it into a beaker filled with 1L of 8% sodium hydroxide solution, and then place the beaker in a digital speed measuring constant temperature magnetic stirrer at a temperature of 55°C and a speed of 350r / min. Under constant temperature, stir and mix for 45min, filter, remove the filter residue, collect the No. 1 filtrate, then add dropwise hydrochloric acid with a mass fraction of 8%, adjust the pH of the No. 1 filtrate to 2.0, let stand for 8h, filter, remove the filter residue, and collect the No. 2 filtrate Measure 200mL of the above-mentioned obtained No. 2 filtrate, add in a three-necked flask with a stirrer, then add dropwise a mass fraction of 10% sodium hydroxide solution, adjust the pH to 10.2, then add 5g of octadecyltrimethylammonium chloride , at a temperature of 60°C and a rotation speed of 300r / min, stir and react at a constant temperature for 3 hours, then transfer the material in the three-neck flask to a rotary evaporator, a...

example 2

[0020]Weigh 200g of humic acid, pour it into a beaker filled with 2L of 10% sodium hydroxide solution, and then place the beaker in a digital speed measuring constant temperature magnetic stirrer at a temperature of 65°C and a speed of 450r / min. Stir and mix at constant temperature for 60 minutes, filter, remove the filter residue, collect No. 1 filtrate, then add dropwise hydrochloric acid with a mass fraction of 10%, adjust the pH of No. 1 filtrate to 2.2, let stand for 12 hours, filter, remove the filter residue, and collect No. 2 filtrate Measure 300mL of the No. 2 filtrate of the above-mentioned gained, add in the there-necked flask with agitator, then add dropwise a mass fraction of 15% sodium hydroxide solution, adjust the pH to 10.5, then add 8g of octadecyltrimethylammonium chloride , at a temperature of 65°C and a speed of 400r / min, stir and react at a constant temperature for 5 hours, then transfer the material in the three-necked flask to a rotary evaporator, and co...

example 3

[0023] Weigh 150g of humic acid, pour it into a beaker filled with 2L of 9% sodium hydroxide solution, and then place the beaker in a digital speed measuring constant temperature magnetic stirrer at a temperature of 60°C and a speed of 400r / min. Under constant temperature, stir and mix for 53 minutes, filter, remove the filter residue, collect the No. 1 filtrate, then add dropwise the mass fraction of 9% hydrochloric acid, adjust the pH of the No. 1 filtrate to 2.1, let it stand for 10 hours, filter, remove the filter residue, and collect the No. Measure 250mL of the above-mentioned obtained No. 2 filtrate, add in the there-necked flask with agitator, then add dropwise a mass fraction of 13% sodium hydroxide solution, adjust the pH to 10.4, then add 7g of octadecyltrimethylammonium chloride , at a temperature of 63°C and a speed of 350r / min, stir and react at a constant temperature for 4 hours, then transfer the material in the three-necked flask to a rotary evaporator, and con...

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Abstract

The invention relates to a preparation method of a stable-type odor-free low-density foam concrete foamer and belongs to the technical field of concrete foamers. The method includes the steps of: dissolving active components in humic acid by a NaOH solution, filtering the solution to remove impurities and dropwise adding hydrochloric acid to remove macro-molecular substances and modify water soluble small-molecular active components; by means of microorganisms in earthworm feces, fermenting active sludge in a secondary sedimentation tank to achieve deodorization; and enzymolysing the microorganisms and animal and plant proteins by means of protease, and compounding the enzymolyzed substances with the modified humic acid extract and sodium dodecyl benzene sulfonate to obtain the stable odor-free low-density foam concrete foamer. By means of octadecyl trimethyl ammonium chloride, hydrophobicity and lipophobicity of the small-molecular substances in the humic acid can be equilibrated, and through compounding with the protein in the active sludge and the sodium dodecyl benzene sulfonate, the problems of poor stability and low foaming times in a conventional concrete foamer are solved effectively. By means of the deodorization function of the earthworm feces, a problem of intensive stink of the foamer is solved.

Description

technical field [0001] The invention relates to a preparation method of a stable odorless low-density foam concrete foaming agent, belonging to the technical field of concrete foaming agents. Background technique [0002] Foamed concrete is made of cement, lime, fly ash, aggregates, admixtures and foam, etc., which are evenly mixed and poured and hardened. It contains a large number of closed pores in the new building material. It has good fluidity, light weight, and resources. The advantages of low consumption and excellent thermal insulation performance have been recognized, valued and applied more and more widely in the construction industry. [0003] In the prior art, commonly used concrete foaming agents mainly include: rosin resins, synthetics, proteins, etc., the main components of which are one or more surfactants. Rosin resin concrete foaming agent can only be used for density greater than 600kg / m2 because of its unsatisfactory foam stability and expansion ratio. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B24/24C04B28/04C04B38/10
CPCC04B28/04C04B38/10C04B40/0039C04B2201/50C04B24/20C04B24/24C04B24/124C04B24/14C04B18/08C04B22/002C04B16/0633
Inventor 董晓许洪祥赵玲玲
Owner 福建科胜加固材料有限公司
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