Preparation method of organic pollutant photolysis catalyst
A technology for organic pollutants and photodegradation, which is used in catalyst activation/preparation, physical/chemical process catalysts, water pollutants, etc. problem, to achieve the effect of low operating cost and no secondary pollution
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Embodiment 1
[0012] (1) Pre-treat the structured ceramic carrier first: put a certain volume of structured ceramics into the laser drilling machine, adjust the diameter, array and power of the laser beam, and drill small holes with a diameter of Φ0.2 mm in a square array; (2) Put the laser-drilled structured ceramic carrier into an ultrasonic reactor, and use 0.2M KMnO 4 Soak in aqueous solution for 2.0 hours, then place it for 24 hours, and then wash with water until the pH of the washing solution is ≥ 6.5; (3) Carry out loading treatment on the above-mentioned structured ceramic carrier, the process is as follows: dissolve 30ml tetrabutyl titanate in 100ml absolute ethanol, After stirring, add 20ml of ethylene glycol and 10ml of commercially purchased graphene sol and 10ml of Bi(NO 3 ) 3 • 5H 2 O and NH 4 VO 4 (molar ratio 1:1) ethanol mixture, stirred at 30°C for 2h to obtain a mixed colloidal solution, then added 150ml of the treated structured ceramic carrier into the mixed collo...
Embodiment 2
[0014] Loading BiVO on structured ceramic supports 4 -TiO2-graphene as an industrial organic pollutant photodegradation catalyst for the degradation of methanol as an example. The activity test is carried out in a fixed-bed reactor of Φ50 x 1000mm. Methanol is used as the simulated compound of industrial organic pollutants. The composition of the simulated industrial organic pollutant waste gas is: methanol 800~2000mg / m 3 , O 2 0~10%, water vapor is 0~12%, and the rest is N 2 balance. The removal reaction temperature is 40°C~120°C, normal pressure, and the space velocity of the photocatalyst is 800-5000 h -1 , using 300W UV emission lamps and visible light lamps, the final test of its methanol degradation rate reached 99%.
Embodiment 3
[0016] Loading BiVO on structured ceramic supports 4 -TiO 2 - Graphene photodegradation catalyst for industrial organic pollutants degrades industrial wastewater as an example. The COD of its wastewater is 1200mg / L, and its COD digestion activity test is carried out in a Φ50 x 1000mm fixed-bed reactor at a reaction temperature of 20°C~60°C and normal pressure, and the space velocity of the photocatalyst is 1-10 h -1 , using 30W H-type UV emission lamps and visible light lamps, the final test wastewater COD degradation rate reached 98%.
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