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Antiwear agent and preparation method thereof

An anti-wear agent, lignin acid technology, applied in the field of anti-wear agent, can solve the problems of different susceptibility, unstable use effect, reduce the anti-wear performance of diesel oil, etc., and achieve good anti-wear performance, strong adaptability and superior performance. Effect

Active Publication Date: 2018-04-20
徐文忠 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] At present, due to the requirements of environmental protection and reduction of exhaust emissions, cleaner and more environmentally friendly diesel oil is required. The standard of diesel oil is constantly improving, and the deep processing of diesel oil removes nitrogen, sulfur and other elements in diesel oil. The removal of these elements is at the same time. It also reduces the anti-wear performance of diesel, making diesel engines more susceptible to wear, so the usage and market demand of diesel anti-wear agents continue to expand
[0003] Most of the existing diesel antiwear agents are fatty acid type and fatty acid ester type. This type of antiwear agent is all C18 acid, and has different susceptibility to different hydrogenated diesel oils, and the use effect is not stable.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] An antiwear agent is made from the following raw materials: lignin acid 18.5kg; stearic acid 19.5kg; glass glue oil 38.5kg (glass glue 25.025kg and 13.475kg industrial white oil) and pentaerythritol 21.5kg.

[0029] The preparation method comprises the following steps:

[0030] (1) glass glue and industrial white oil are compounded and mixed to form glass glue oil, and lignin acid, stearic acid, glass glue oil and pentaerythritol are mixed evenly by weight to obtain a mixed solution;

[0031] (2) Heating the mixed solution until the reaction is completed, the reaction time is 5-6 hours, and then dehydrating. After dehydration, the water content is detected as traces, and finally cooled to 90°C to obtain an intermediate product;

[0032] (3) Add 15% heavy aromatic hydrocarbons of the weight of the intermediate product to the intermediate product, keep stirring, and cool to room temperature to obtain the finished antiwear agent.

Embodiment 2

[0034] An antiwear agent made from the following raw materials:

[0035] 21.5kg of lignin acid; 20.5kg of stearic acid; 41.5kg of glass glue oil (26.975kg of glass glue and 14.525kg of industrial white oil) and 18.5kg of pentaerythritol.

[0036] The preparation method comprises the following steps:

[0037] (1) Glass glue and industrial white oil are compounded and mixed to form glass glue oil, lignin acid, stearic acid and glass glue oil are mixed for the first time according to the weight ratio, and then mixed with pentaerythritol for the second time Mix for the first time, and obtain a mixed solution after mixing evenly;

[0038] (2) Heating the mixed solution at a temperature of 120°C until the reaction is complete. The reaction time is 6 hours, and then dehydrated to a moisture content of 0.03%. After dehydration, the water content is detected as a trace, and finally cooled to 80 °C, the intermediate product was obtained;

[0039] (3) Add 15% heavy aromatic hydrocarbo...

Embodiment 3

[0041] An antiwear agent made from the following raw materials:

[0042] 20kg of lignin acid; 20kg of stearic acid; 40kg of glass glue oil (26kg of glass glue and 14kg of industrial white oil) and 20kg of pentaerythritol.

[0043] The preparation method comprises the following steps:

[0044] (1) Glass glue and industrial white oil are compounded and mixed to form glass glue oil, lignin acid, stearic acid and glass glue oil are mixed for the first time according to the weight ratio, and then mixed with pentaerythritol for the second time Mix for the first time, and obtain a mixed solution after mixing evenly;

[0045] (2) Heating the mixed solution at a temperature of 130°C until the reaction is complete. The reaction time is 5 hours, and then dehydrated to a moisture content of 0.02%. After dehydration, the water content is detected as traces, and finally cooled to 85 °C, the intermediate product was obtained;

[0046] (3) Add 15% heavy aromatic hydrocarbons of the weight ...

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PUM

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Abstract

The invention relates to an anti-wear agent and a preparation method thereof. The anti-wear agent is prepared from the following raw materials: 18.5 to 21.5 parts of lignoceric acid, 19.5 to 20.5 parts of stearic acid, 38.5 to 41.5 parts of glass cement oil and 18.5 to 21.5 parts of pentaerythritol. The preparation method comprises the following steps: after mixing the raw materials, reacting, and then carrying out dehydration refining to synthesize a novel diesel anti-wear agent. The anti-wear agent has the beneficial effects that the anti-wear agent prepared in the invention is high in adaptive capacity, can be used for improving the anti-wear performance of various atmospheric and vacuum, catalytic and hydrogenation diesels, and has good anti-wear performance for diesels with different raw materials and technologies through tests; the anti-wear agent is superior in performance, the performance completely meets and is superior to the relevant standard of the industry, and the addition amount can be reduced by 10% to 16% compared with an existing anti-wear agent; and the anti-wear agent meets the increasing environmental requirements of the diesels.

Description

technical field [0001] The invention relates to an antiwear agent, in particular to an antiwear agent for improving the antiwear performance of diesel oil and a preparation method thereof. Background technique [0002] At present, due to the requirements of environmental protection and reduction of exhaust emissions, cleaner and more environmentally friendly diesel oil is required. The standard of diesel oil is constantly improving, and the deep processing of diesel oil removes nitrogen, sulfur and other elements in diesel oil. The removal of these elements is at the same time. It also reduces the anti-wear performance of diesel, making diesel engines more susceptible to wear, so the usage and market demand of diesel anti-wear agents continue to expand. [0003] Most of the existing diesel antiwear agents are fatty acid type and fatty acid ester type. This type of antiwear agent is all C18 acid, which has different susceptibility to different hydrogenated diesel oils, and th...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10L1/18C10L1/188C10L1/182C10L1/12C10L1/16C10L1/04C10L10/08
CPCC10L1/04C10L1/106C10L1/1216C10L1/1616C10L1/1802C10L1/1826C10L1/1881C10L10/08C10L2270/026
Inventor 徐文忠
Owner 徐文忠
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