Aqueous dry lamination adhesive and preparation method thereof

A film-coating adhesive and dry-type technology, which is applied in adhesive types, rosin adhesives, ester copolymer adhesives, etc., can solve the problems that acrylic emulsions cannot balance adhesion, initial adhesion, and peel strength. Achieve the effects of improving adhesion and peel strength, excellent initial tack, and wide application

Active Publication Date: 2016-04-13
常德市雄鹰科技有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, conventional polymerized acrylic emulsions for laminating adhesives cannot meet the requirements of adhesion, initial adhesion and peel strength, and often need to be formulated to complement each other.

Method used

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  • Aqueous dry lamination adhesive and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] The preparation method of the water-based dry-type film-coating adhesive in this example is prepared as follows:

[0018] (1) Mix 25 parts of styrene, 40 parts of butyl acrylate and 2 parts of hydroxyethyl acrylate to obtain mixed monomer A solution; 4 parts of N-methylolacryloyl, 3.5 parts of acrylic acid and 20 parts of deionized water Mix uniformly to obtain a mixed monomer B solution; 20 parts of styrene, 55 parts of butyl acrylate, 35 parts of isooctyl acrylate, 5 parts of acrylonitrile and 12 parts of rosin are mixed uniformly to obtain a mixed monomer C solution;

[0019] (2) Mix 180 parts of deionized water, 3 parts of isooctylphenol polyoxyethylene ether, 0.8 parts of sodium dodecylbenzenecyclonate and 10%-15% of monomers A and B in step (1) Add the solution into the reaction kettle, stir and heat up to 70±2°C to obtain a mixed solution, add 0.3 parts of buffer and 0.2 parts of potassium persulfate into the reaction kettle, control the temperature at 75±1°C, an...

Embodiment 2

[0024] The preparation method of the water-based dry-type film-coating adhesive in this example is prepared as follows:

[0025] (1) Mix 28 parts of styrene, 48 parts of butyl acrylate, 3 parts of hydroxyethyl acrylate and 3 parts of acrylonitrile to obtain a mixed monomer A solution; 5 parts of N-methylolacryloyl, 6 parts of acrylic acid and 40 parts of deionized water were mixed uniformly to obtain mixed monomer B solution; 25 parts of styrene, 65 parts of butyl acrylate, 25 parts of isooctyl acrylate, 6 parts of acrylonitrile and 15 parts of rosin were mixed uniformly to obtain mixed monomer C solution ;

[0026] (2) Mix monomers A and B with 200 parts of deionized water, 4.0 parts of isooctylphenol polyoxyethylene ether, 1.4 parts of sodium dodecylbenzenecyclonate and 10%-15% in step (1) Add the solution into the reaction kettle, stir and heat up to 70±2°C to obtain a mixed solution, add 0.4 parts of buffer and 0.3 parts of potassium persulfate into the reaction kettle, c...

Embodiment 3

[0031] The preparation method of the water-based dry-type film-coating adhesive in this example is prepared as follows:

[0032] (1) Mix 30 parts of styrene, 55 parts of butyl acrylate, 5 parts of hydroxyethyl acrylate and 5 parts of acrylonitrile to obtain a mixed monomer A solution; 6 parts of N-methylol acryloyl, 8 parts of acrylic acid and 50 parts of deionized water were mixed uniformly to obtain mixed monomer B solution; 35 parts of styrene, 75 parts of butyl acrylate, 40 parts of isooctyl acrylate, 8 parts of acrylonitrile and 25 parts of rosin were mixed uniformly to obtain mixed monomer C solution ;

[0033] (2) Mix monomers A and B with 220 parts of deionized water, 4.8 parts of isooctylphenol polyoxyethylene ether, 1.8 parts of sodium dodecylbenzenecyclonate and 10%-15% in step (1) Add the solution into the reaction kettle, stir and heat up to 70±2°C to obtain a mixed solution, add 0.5 parts of buffer and 0.4 parts of potassium persulfate into the reaction kettle, ...

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Abstract

The invention discloses an aqueous dry lamination adhesive and a preparation method thereof. Raw materials of the aqueous dry lamination adhesive comprise styrene, butyl acrylate, isooctyl acrylate, acrylonitrile, N-methylolacrylamide, hydroxyethyl acrylate, acrylic acid, rosin, potassium persulfate, sodium dodecylbenzene sulfonate, isooctyl phenol polyoxyethylene ether, sodium bicarbonate, deionized water, ammonia water, a wetting agent and antifoaming agent. Aqueous latex with a core-shell structure is prepared through a segmented polymerization technology, so functional groups make a substrate and a plastic film be fully bonded, and polymer molecular chains are self-crosslinked, thereby the adhesion and the peeling strength of the substrate are improved, the adhesive has excellent initial adhesion, pressure sensitivity and covering ability, the excellent leveling property and the dynamic wetability of the adhesive make a laminated product have brilliant gloss, and the adhesive can be widely used in paper plastic lamination.

Description

technical field [0001] The invention relates to a packaging printing material, in particular to a water-based dry film-coating glue and a preparation method thereof. Background technique [0002] Dry laminating adhesive is a layer of adhesive that is coated on the plastic film during the paper-plastic laminating process, and then passes through the drying tunnel of the laminating machine to remove the solvent or water in the adhesive, and then Bonded with paper-plastic printed matter under hot pressing to achieve beautiful, bright, waterproof, anti-fouling, increase the mechanical strength of the paper product, abrasion resistance, folding resistance, chemical corrosion resistance and other protective effects. Existing composite film materials are divided into two types: glossy film and matte film. Glossy film requires smoothness and brightness, excellent adhesion, no blistering and no delamination, and matte film requires strong powder covering ability. At present, convent...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09J133/08C09J193/04C08F220/18C08F212/10C08F220/44C08F220/58C08F220/28C08F220/06
CPCC08F220/18C08F220/1804C08L2207/53C09J133/08C08L93/04C08F212/10C08F220/1808C08F220/44C08F220/58C08F220/281C08F220/06
Inventor 熊成章王锟
Owner 常德市雄鹰科技有限责任公司
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