Compound containing quinoxaline perssad and organic electroluminescence device of compound
A technology of quinoxaline groups and compounds, applied in the field of organic electroluminescent compounds and organic electroluminescent devices, can solve the problems of low electron mobility, low electron mobility, affecting the life and efficiency of devices, etc., and achieve high The effect of luminous purity, high luminous efficiency and good thermal stability
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Embodiment 1
[0050] Synthesis of compound 1
[0051]
[0052] Synthesis of Intermediate 1-1
[0053] In the flask, add 4-bromo-o-phenylenediamine (18.6g, 0.1mol), benzil (21g, 0.1mol) and acetic acid (200ml), heat to 90°C for 5 hours, cool, filter, and use Ethanol was recrystallized to obtain 28 g of the product with a yield of 78%.
[0054] Synthesis of intermediate 1-2
[0055] In a flask, add intermediate 1-1 (20g, 56mmol), 9-anthraceneboronic acid (12.3g, 56mmol), potassium carbonate (15g, 112mmol), tetrakistriphenylphosphine palladium (1g), tetrahydrofuran (300ml) and Water (100ml) was heated under nitrogen protection for 5 hours, cooled, extracted with dichloromethane, concentrated, and the crude product was recrystallized with tetrahydrofuran and ethanol to obtain 21g of the product with a yield of 82%.
[0056] Synthesis of Intermediates 1-3
[0057] In the flask, add intermediate 1-2 (20g, 44mmol), N,N-dimethylformamide (250ml) and N-bromosuccinimide (8.2g, 46mmol), react a...
Embodiment 2
[0063] Synthesis of compound 7
[0064]
[0065] In a three-necked flask, add intermediate 1-3 (3g, 5.6mmol), 2,4-diphenyl-6-(4-pinacolyl phenyl)-pyrimidine (2.4g, 5.6mmol), carbonic acid Potassium (1.5g, 11.2mmol), tetrakistriphenylphosphine palladium (0.1g), tetrahydrofuran (50ml) and water (20ml), heated for 5 hours under nitrogen protection, cooled, filtered, and the crude product was recrystallized from tetrahydrofuran and ethanol , to obtain product 3.9g, yield 91%.
Embodiment 3
[0067] Synthesis of Compound 10
[0068]
[0069] In a three-necked flask, add intermediate 1-3 (3g, 5.6mmol), 2,4-diphenyl-6-(4-pinacol ester phenyl)-1,3,5-triazine (2.4 g, 5.6mmol), potassium carbonate (1.5g, 11.2mmol), tetrakistriphenylphosphine palladium (0.1g), tetrahydrofuran (50ml) and water (20ml), heated under nitrogen for 5 hours, cooled, filtered, the crude product Then recrystallized with tetrahydrofuran and ethanol to obtain 2.6 g of the product with a yield of 83%.
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