Device of increasing adsorption bed thermal-circular gas desorption regeneration efficiency and method thereof

A technology of hot gas circulation and regeneration efficiency, which is applied in the fields of chemical industry and environmental protection. It can solve the problems of increasing the regeneration time of the system, the inability to apply it on a large scale, and the low condensation temperature, so as to improve the desorption efficiency, solve the problem of secondary water pollution, and effectively desorb attached effect

Active Publication Date: 2015-12-09
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

but if figure 1 The traditional hot gas cycle desorption process shown requires a lot of energy for heating and condensing the gas, which cannot be applied on a large scale
figure 2 The split-flow condensing system shown better solves the problem of capacity matching between heating and condensation, and greatly reduces the demand for equipment and energy consumption compared with the first method, but the condensation temperature in the split-flow process determines the recovery of each cycle. The amount of adsorbed substances, for some adsorbed substances with low boiling point, often requires a very low condensation temperature, which puts forward high requirements for refrigeration equipment, otherwise it will affect the desorption efficiency due to the high concentration of reflux gas, and increase the regeneration of the system time

Method used

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  • Device of increasing adsorption bed thermal-circular gas desorption regeneration efficiency and method thereof
  • Device of increasing adsorption bed thermal-circular gas desorption regeneration efficiency and method thereof
  • Device of increasing adsorption bed thermal-circular gas desorption regeneration efficiency and method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0021] Embodiment 1: by the first valve 1, the second valve 2, the third valve 3, the fourth valve 4, the fifth valve 5, the sixth valve 6, the seventh valve 14, the pressure reducing valve 7, the air compressor 8, Condenser 9, membrane separation device 10, circulating gas heater 11, activated carbon bed 12, circulating fan 13, flow meter, temperature detector, corresponding pipelines and automatic control system are connected, the first valve 1, the fourth valve 4 and the activated carbon bed 12 constitute the adsorption gas path; the activated carbon bed 12, the circulating fan 13 and the circulating gas heater 11 constitute the desorption main gas path; the sixth valve 6, the seventh valve 14 and the air compressor 8, the condenser 9, and the membrane separation The device 10 and the pressure reducing valve 7 are connected to form a part of the condensation recovery gas path.

[0022] When the activated carbon bed is adsorbing, only the first valve 1 and the fourth valve 4...

Embodiment 2

[0024] Adopt the device described in embodiment 1 to be used for thermal cycle gas desorption recovery polyurethane solvent example

[0025] The drying room workshop of a certain coating production line has a system design scale of 5000m3 / h. Considering the heat preservation requirements of the drying room, the gas is recycled in a closed circuit without environmental discharge; the solvent is polyurethane paint solvent (including xylene, aromatic solvent ( Except xylene), butyl acetate and methyl isobutyl ketone, etc.); the temperature of the incoming gas is 50~80℃, and the content of organic matter in the gas is 400~3000mg / m 3 . The system adopts comprehensive energy utilization measures such as heat exchange, and the temperature of the return air is lower than the temperature of the incoming air by less than 10°C. The system is running normally, the purity of the solvent recovered from the polyurethane paint spraying process is greater than 99%, the water content of the so...

Embodiment 3

[0027] Using the device described in Example 1, a compound packaging factory, the system design scale air volume is 100,000 m 3 / h, the recovery solvent is ethyl acetate. The recovery of ethyl acetate by this method is 800 tons per year, the purity of the refined solvent is greater than 99.6%, and the water content is less than 300ppm.

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Abstract

The invention relates to a device of increasing thermal-circular gas desorption efficiency and a method thereof. In the method, a by-pass system is added at each of the front and the back of an activated charcoal bed. On the basis of thermal-circular gas desorption, compressive condensation and a membrane separation system are employed for increasing desorption efficiency. During adsorption, a valve of the by-pass is closed so that the by-pass system is out of work; during desorption, an inlet-outlet valve of to-be-processed gas on the activated charcoal bed is closed and the valve of the by-pass is opened and then thermal gas desorption is carried out through circular heating by a circulating fan and a gas flow heater. When the gas is heated to a preset temperature, the valve and a pressure-reducing valve are opened, so that a part of the gas passes through an air compressor and then is condensed in a condenser to recycle organic solvents being high in purity, wherein the gas being not recycled is completely separated through the membrane separation system. High concentration gas is subjected to compressive condensation recycling before flowing-back to the air compressor through the valve, while clean gas is heated in the gas flow heater through the pressure-reducing valve and the valve and then is desorbed. The device is used of purification of polluted gas and recycling of organic solvents, is greatly increased in desorption efficiency and is increased in recycling purity and recycling efficiency of the organic solvents.

Description

technical field [0001] The invention relates to the technical fields of chemical industry and environmental protection, in particular to a device and a method for improving the desorption regeneration efficiency of hot gas circulation in an adsorption bed. Background technique [0002] In the fields of chemical industry and environmental protection, activated carbon adsorption beds are widely used in exhaust gas purification and recovery processes. Activated carbon adsorption recovery, on the one hand, helps to reduce production costs and generate economic benefits, on the other hand, it can reduce environmental pollution, and is an important link in the clean production of enterprises. The commonly used activated carbon adsorption recovery uses steam desorption, which has the defects of secondary water pollution and high overall energy consumption, and has the problem of low desorption efficiency for organic substances with higher boiling points. The boiling point range of...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/02B01J20/34B01D53/00B01D53/22
Inventor 羌宁李照海刘涛荀志萌吴娅
Owner TONGJI UNIV
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