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Modified calcium carbonate padding for architectural decoration and preparation method thereof

A calcium carbonate filler, calcium carbonate technology, applied in fibrous fillers, chemical instruments and methods, inorganic pigment treatment and other directions, can solve problems such as poor direct application effect, uneven dispersion of high polymers, and easy formation of aggregates, etc. Achieve the effect of improving rigidity, simple preparation method and good suspension stability

Inactive Publication Date: 2015-09-23
安徽雪城超细碳酸钙有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the products, and reduce the cost, but its surface has a strong hydrophilic hydroxyl group, showing a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in Partially dispersed in the polymer is not uniform, resulting in interface defects between the two materials, the direct application effect is not good, and calcium carbonate as a filler, its acid resistance, smoothness, whiteness and other properties need to be further improved, therefore, in order to To improve the reinforcing effect of calcium carbonate and the dispersion performance in composite materials and the physical properties of modified calcium carbonate filled composite materials, it is necessary to use different surface modifiers and treatment methods to modify the surface of calcium carbonate powder, and then broaden the Application fields of calcium carbonate

Method used

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Embodiment Construction

[0012] specific implementation

[0013] The present invention will be described in detail below through specific examples.

[0014] A modified calcium carbonate filler for building decoration and a preparation method thereof are prepared from the following raw materials in parts by weight (kg): calcium carbonate 150, sodium oleate 46, sodium dodecylbenzenesulfonate 0.6, carbonic acid Sodium hydrogen 2, styrene 6, potassium persulfate 0.04, fumed silica 5, organic bentonite 3, leaf rock ash 4, phosphogypsum powder 3, aluminum dihydrogen tripolyphosphate 2, appropriate amount of deionized water;

[0015] A modified calcium carbonate filler for building decoration and a preparation method thereof according to the present invention are prepared by the following specific steps:

[0016] (1) Dissolve sodium oleate in deionized water to make a 1% sodium oleate aqueous solution, stir it electrically for 10min and raise the temperature to 60°C, add calcium carbonate and stir for 1.5h,...

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Abstract

The invention discloses a modified calcium carbonate padding for architectural decoration and a preparation method thereof. The padding is characterized by being prepared from the following raw materials in parts by weight: 100-150 parts of calcium carbonate, 30-50 parts of sodium oleate, 0.3-0.7 part of sodium dodecyl benzene sulfonate, 1-3 parts of sodium bicarbonate, 4-8 parts of styrene, 0.02-0.05 part of potassium peroxodisulfate, 3-5 parts of fumed silica, 2-3 parts of organic bentonite, 3-5 parts of shale ash, 2-4 parts of ardealite powder, 1-2 parts of aluminum dihydrogen tripolyphosphate and a moderate amount of deionized water. According to the preparation method, the added shale ash, ardealite powder and aluminum dihydrogen tripolyphosphate can significantly improve the rigidity, whiteness and stability of calcium carbonate, and have the characteristics of being anticorrosive and weather-proof, and capable of keeping relatively high strength; moreover, the cost is reduced; the preparation method provided by the invention is simple and convenient to operate; industrialization is easy to achieve; the produced padding has a good decorative function if used in architectural decoration industry.

Description

technical field [0001] The invention relates to the field of industrial fillers, in particular to a modified calcium carbonate filler for building decoration and a preparation method thereof. Background technique [0002] As a filler for rubber and plastic products, calcium carbonate can improve the heat resistance, wear resistance, dimensional stability, rigidity and processability of the product, and reduce the cost of the product, but its surface has hydroxyl groups with strong hydrophilicity. It presents a strong alkalinity. This hydrophilic and oleophobic property makes the affinity between calcium carbonate and organic polymers poor, and it is easy to form aggregates, resulting in uneven dispersion in the polymer, resulting in two materials. The effect of direct application is not good, and calcium carbonate is used as a filler, and its acid resistance, smoothness, whiteness and other properties need to be further improved. Therefore, in order to improve the reinforci...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09C1/02C09C3/06C09C3/08C09C3/10C09C3/04C04B14/28
Inventor 窦念根
Owner 安徽雪城超细碳酸钙有限公司
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