A kind of carbon steel anticorrosion compound corrosion inhibitor used in neutral medium

A technology of composite corrosion inhibitor and neutral medium, applied in the field of composite corrosion inhibitor, can solve the problems such as the effect of aggressive ions is not as good as that of chromate, unstable corrosion inhibition performance, unfavorable production and application, etc., which is convenient for industrial promotion and application, Excellent corrosion inhibition performance, beneficial to environmental protection

Inactive Publication Date: 2017-02-01
SOUTHWEST PETROLEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The existing literature reports and the research of our research group have shown that sodium tungstate, cerium nitrate and neutral red are environmentally friendly corrosion inhibitors, but they are used alone as corrosion inhibitors in neutral media to prevent corrosion of carbon steel. The main disadvantages: first, the dosage is large, the corresponding cost is high, which is not conducive to industrial production and application; second, the corrosion inhibition performance is unstable
Simply using a corrosion inhibitor, the corrosion inhibition film formed on the steel sheet is not very dense, and the effect of preventing aggressive ions is not as good as that of chromate

Method used

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  • A kind of carbon steel anticorrosion compound corrosion inhibitor used in neutral medium
  • A kind of carbon steel anticorrosion compound corrosion inhibitor used in neutral medium
  • A kind of carbon steel anticorrosion compound corrosion inhibitor used in neutral medium

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Embodiment 1

[0026] Dissolve a certain amount of sodium chloride with deionized water to obtain a sodium chloride solution with a mass fraction of 3.5%, which is used as a corrosion medium for carbon steel; 2 WO 4 , Ce(NO 3 ) 3 and C 15 h 17 ClN 4 Soluble in sodium chloride solution, under different proportions (600mg / L Na 2 WO 4 , 500mg / L Ce(NO 3 ) 3 and 100~1000mg / L C 15 h 17 ClN 4 ) of W-Ce-C 15 h 17 ClN 4 Composite corrosion inhibitor. Stir at constant temperature (30°C) for 10 minutes under a magnetic stirrer, and after several compounds are fully dissolved and reacted in NaCl aqueous solution, different ratios of W-Ce-C can be obtained. 15 h 17 ClN 4 Composite corrosion inhibitor.

[0027] 2. W-Ce-C 15 h 17 ClN 4 Performance Test of Composite Corrosion Inhibitor

[0028]Carbon steel sample treatment: Grind the 30mm×20mm×2mm carbon steel sample with 400#, 600#, 800# sandpaper in turn, then wash with acetone and ethanol to remove the grease on the surface of the s...

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Abstract

The invention relates to a composite corrosion inhibitor for corrosion protection of carbon steel in a neutral medium. A preparation method of the composite corrosion inhibitor comprises the following steps: (1) dissolving sodium chloride at a mass percentage of 1-5% with deionized water, and (2) adding sodium tungstate, cerous nitrate and neutral red at a mass ratio of (5-6):(4-5):(5-6) into a sodium chloride aqueous solution, and stirring for 10min at a constant temperature of 30 DEG C, wherein the total mass percentage of sodium tungstate, cerous nitrate and neutral red in the sodium chloride aqueous solution is 0.14-0.17%. The inhibitor is used for anticorrosion treatment of the carbon steel in the neutral medium, can effectively prevent or slow down a corrosion effect of Cl- in a high Cl- ion solution on the carbon steel, has significant corrosion inhibition ability, is low in production cost, green and environment-friendly, can effectively solve the corrosion problem of the carbon steel in the neutral medium, and a use method is simple.

Description

technical field [0001] The invention relates to a composite corrosion inhibitor used for carbon steel anticorrosion in the field of industrial circulating cooling water systems. Background technique [0002] Every year, a large amount of metal materials are lost due to corrosion, causing huge economic losses. Carbon steel is currently one of the most widely used metal materials, and about 80% of petroleum and chemical equipment are made of iron-carbon alloys. Carbon steel is a kind of steel with poor corrosion resistance, especially in highly corrosive working environments (such as seawater medium), corrosion becomes a more serious problem. [0003] Corrosion inhibitor is a substance that can reduce the corrosion rate of metals by adding a small amount to the corrosion system. It can prevent or slow down the corrosion of engineering materials. Its dosage is very small, generally 0.1% to 1%. But the effect is remarkable. Corrosion inhibitor anticorrosion technology is wide...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23F11/08
Inventor 郑超超庄稼张洪旭梁秋梅曾宪光
Owner SOUTHWEST PETROLEUM UNIV
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