A high-temperature-resistant high-efficiency environment-friendly full ester-based drilling lubricant and preparation method thereof
A technology of high temperature resistance and lubricant, applied in chemical instruments and methods, drilling compositions, etc., can solve the problems of reduced torque of soil moving slurry, non-degradation, pollution of the ocean, etc., to shorten the tripping time and improve the work. Efficiency, the effect of reducing hydraulic friction
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[0038] The high-temperature-resistant high-efficiency and environment-friendly all-ester-based drilling lubricant prepared by the above-mentioned preparation method.
[0039] The drilling lubricant of the present invention has good lubricating performance, and the torque reduction rate of mud-moving slurry in fresh water reaches more than 90%, and the torque reduction rate of mud-moving slurry in seawater reaches more than 80%; the viscosity index is greater than 180, and the biodegradation rate is as high as more than 90%. The temperature resistance can reach above 200°C.
[0040] Below in conjunction with specific embodiment the present invention is described in further detail:
Embodiment 1
[0042] 1. Synthesis of Trimethylolpropane Sebacic Acid Modified Polyurethane
[0043] Put 100 grams of polypropylene oxide, 60 grams of trimethylol propane diacid and 20 grams of isophorone diisocyanate in a container, react for 3 hours under the conditions of temperature 90°C and negative pressure 180 mmHg, and add trihydroxy 50 grams of methylpropionic acid, 30 grams of chain extender diethylene glycol and 10 grams of catalyst stannous octoate, under the condition of adjusting the negative pressure of 50 mmHg, the temperature was continued for 6 hours at 110 ° C to obtain trimethylol propane decanedic acid modified polyurethane ;
[0044] 2. Synthesis of trimethylolpropane mixed esters
[0045] 100 grams of the prepared trimethylolpropane sebacic acid modified polyurethane was mixed with 20 grams of ricinoleic acid, 12 grams of diethanolamine and 6 grams of boric acid, and the negative pressure was 230 mmHg, and nitrogen was circulated continuously, and at a temperature of ...
Embodiment 2
[0056] 1. Synthesis of Trimethylolpropane Sebacic Acid Modified Polyurethane
[0057] Put 120 grams of polypropylene oxide, 70 grams of trimethylolpropane diacid and 24 grams of isophorone diisocyanate in a container, react for 4 hours under the conditions of temperature 80 ° C and negative pressure 160 mmHg, and add trihydroxy 60 grams of methylpropionic acid, 35 grams of chain extender diethylene glycol and 12 grams of catalyst stannous octoate, under the condition of adjusting the negative pressure of 40mmHg, the temperature continued to react for 5 hours at 110°C to obtain trimethylolpropane sebacic acid modified polyurethane ;
[0058] 2. Synthesis of trimethylolpropane mixed esters
[0059] Mix 200 grams of the prepared trimethylolpropane sebacic acid-modified polyurethane with 45 grams of ricinoleic acid, 25 grams of diethanolamine and 12 grams of boric acid, and nitrogen gas is fed into the negative pressure 240mHg high uninterrupted circulation, at a temperature of 1...
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