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Preparation method of novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12

A magnetoelectric coupling, multiferroic technology, applied in the field of materials science, can solve the problems of limited and restricted novelty effect research and application, achieve high critical temperature, good application prospects, large dielectric constant and electric polarization strength Effect

Active Publication Date: 2015-06-03
INST OF PHYSICS - CHINESE ACAD OF SCI
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  • Abstract
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AI Technical Summary

Problems solved by technology

At present, the material system with magnetoelectric coupling multiferroic effect is still very limited, which greatly restricts the research and application of this novel effect

Method used

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  • Preparation method of novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12
  • Preparation method of novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12
  • Preparation method of novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12

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Embodiment 1

[0026] Bi with a purity higher than 99.9% 2 o 3 , Mn 2 o 3 and Cr 2 o 3 After fully grinding at a molar ratio of 1:3:4, pass through a 200-mesh sieve; put the screened raw materials into gold or platinum capsules and compact them, wherein the gold or platinum capsules have a diameter of 10 mm and a length of 10 mm. The wall thickness is 2mm; the gold or platinum capsule is placed in a six-sided top press or a 6-8 type two-stage pusher press, and the pressure is set at 8GPa and the temperature is 1050°C, so that the raw materials in the gold or platinum capsule are under high temperature and high pressure. The reaction time was 30 minutes.

[0027] figure 1 The novel magnetoelectric coupling multiferroic material BiMn prepared by embodiment 1 is shown 3 Cr 4 o 12 The XRD pattern. Via a novel magnetoelectrically coupled multiferroic material BiMn 3 Cr 4 o 12 The XRD pattern of the prepared BiMn can be obtained 3 Cr 4 o 12 It belongs to the A-site ordered cubic do...

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Abstract

The invention discloses a novel magneto-electric coupling multi-ferroic material and a preparation method thereof. A chemical formula of the novel magneto-electric coupling multi-ferroic material is BiMn3Cr4O12. The method for preparing the novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12 comprises the following steps: mixing Bi2O3, Mn2O3 and Cr2O3 of which the purities are more than 99.9% according to a molar ratio of 1:3:4, and then fully grinding and screening; filling screened raw materials into gold capsules or platinum capsules and compacting; and performing solid-phase reaction at high temperature and high pressure. The novel magneto-electric coupling multi-ferroic material BiMn3Cr4O12 disclosed by the invention has weak ferromagnetic spin orders, relatively large dielectric constants and electric dipolar polarization strength as well as relatively high critical temperature, and has good application prospects in the fields of spin electronic devices and multi-state memory devices.

Description

technical field [0001] The invention relates to the field of material science, in particular to a novel magnetoelectric coupling multiferroic material BiMn 3 Cr 4 o 12 method of preparation. Background technique [0002] Magnetoelectric coupling multiferroic materials (Magnetoelectric coupling multiferroics) refer to compounds that have both ferroelectricity and long-range magnetic ordering, and ferroelectricity and magnetic ordering have a strong coupling effect. This type of material can realize the mutual regulation of electricity and magnetism, such as regulating the electric polarization state through the magnetic field, and regulating the magnetization state through the electric field. Therefore, the magnetoelectrically coupled multiferroic material is a new type of multifunctional material. Storage, electromagnetic sensors and other fields have broad application prospects. [0003] In transition metal oxides, electric polarization does not require the participatio...

Claims

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Application Information

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IPC IPC(8): C04B35/12C04B35/622
Inventor 龙有文周龙殷云宇
Owner INST OF PHYSICS - CHINESE ACAD OF SCI
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