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Zero-valent iron reduction-Fenton oxidation integrated reaction device and method for treating nitroaromatic compound wastewater by using zero-valent iron reduction-Fenton oxidation integrated reaction device

A reaction device, Fenton oxidation technology, applied in chemical instruments and methods, water/sewage multi-stage treatment, water/sludge/sewage treatment, etc. To solve the problems of engineering application of coupling technology and large secondary pollution, it can achieve the effect of simplifying the process of wastewater treatment, reducing treatment costs and reducing the production of iron sludge.

Active Publication Date: 2015-05-06
NANJING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the disadvantages of the Fenton section, such as high processing costs and large secondary pollution, severely limit the practical engineering application of the zero-valent iron-Fenton coupling technology.

Method used

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  • Zero-valent iron reduction-Fenton oxidation integrated reaction device and method for treating nitroaromatic compound wastewater by using zero-valent iron reduction-Fenton oxidation integrated reaction device
  • Zero-valent iron reduction-Fenton oxidation integrated reaction device and method for treating nitroaromatic compound wastewater by using zero-valent iron reduction-Fenton oxidation integrated reaction device
  • Zero-valent iron reduction-Fenton oxidation integrated reaction device and method for treating nitroaromatic compound wastewater by using zero-valent iron reduction-Fenton oxidation integrated reaction device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Example 1: Treatment of 2,4-Dinitroanisole Washing Wastewater by Zero-Valent Iron Reduction-Fenton Oxidation Coupling System

[0029] The zero-valent iron reduction-Fenton oxidation integrated device adopted in the present invention is as figure 1 As shown, the reaction device includes a reactor body in a hollow cylindrical structure. The reactor body is made of plexiglass. The inside of the reactor body is divided into iron slime collection area 1, zero-valent iron reduction area 5, and zero-valent iron reduction area from bottom to top. Valence iron Fenton oxidation zone 9 and precipitation zone 10 four reactions, and zero-valent iron reduction zone 5 and zero-valent iron Fenton oxidation zone 9 are covered with iron shavings; iron mud collection zone 1 includes sludge discharge valve 12 and exposure Gas device 2; the zero-valent iron reduction zone 5 is composed of the first partition 4 and the water distributor 3, the first partition 4 is used to carry the iron shav...

Embodiment 2

[0037] Embodiment 2: the influence of hydrogen peroxide concentration on the removal effect of nitroaromatic compounds

[0038] Set the reaction conditions of HRT=24h, zero-valent iron Fenton oxidation zone pH is 6, adjust the pumping amount of hydrogen peroxide in dosing device 7, and explore the effect of different concentration of hydrogen peroxide on UV 254 The change of the value and the influence of the change of TOC removal rate.

[0039] Depend on Image 6 It can be seen that the UV of wastewater after treatment in each reaction zone 254 The value is gradually reduced, especially when the concentration of hydrogen peroxide is 10mL / L, the UV 254 The change in the value is most obvious, and the UV of the final wastewater 254 The value is 0.14, which means that the removal effect of the target pollutants and their reduction products is the best under the condition of the concentration of hydrogen peroxide. The results showed that when the concentration of hydrogen per...

Embodiment 3

[0041] Example 3: Influence of the pH value of the zero-valent iron Fenton oxidation zone on the removal effect of nitroaromatic compounds

[0042] Under the reaction conditions of HRT=24h and hydrogen peroxide concentration of 10mL / L, the pH value of the zero-valent iron Fenton oxidation zone was controlled by adjusting the pumping amount of the sulfuric acid solution in the dosing device 7, and the zero-valent iron Fenton oxidation zone was explored. The pH value of the oxidation zone is related to the UV in the zone 254 Value changes and the impact of TOC removal rate changes.

[0043] Depend on Figure 8 Visible, UV of water 254 The value is 0.84, after the treatment of the zero-valent iron Fenton oxidation zone, the UV 254 value dropped significantly. When the pH value of the zero-valent iron Fenton oxidation zone is 3, the UV of the effluent 254 The value is the lowest, which is 0.10. As the pH value of the Fenton oxidation zone increases, the UV of the effluent 25...

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Abstract

The invention discloses a zero-valent iron reduction-Fenton oxidation integrated reaction device. The reaction device comprises a reactor body with a hollow cylindrical structure, wherein the inner part of the reactor body is divided into four reaction areas, namely an iron mud collecting area, a zero-valent iron reduction area, a zero-valent iron Fenton oxidation area and a sedimentation area from bottom to top; the four reaction areas are communicated with one another, and iron scraps fills up the zero-valent iron reduction area and the zero-valent iron Fenton oxidation area. According to the zero-valent iron reduction-Fenton oxidation integrated reaction device disclosed by the invention, a zero-valent iron reduction technology and a zero-valent iron Fenton oxidation technology are combined to ensure that the effective space of a reactor can be used to a greatest extent, the technological process of wastewater treatment can be simplified, and the running cost can be reduced; and according to the zero-valent iron reduction-Fenton oxidation integrated reaction device, the zero-valent iron reduction technology and the Fenton oxidation technology are coupled, iron ions produced by a zero-valent iron reduction working section can be fully used in a Fenton oxidation working section as catalysts, and thus the treatment efficiency of the Fenton oxidation working section can be improved.

Description

technical field [0001] The invention belongs to the technical field of sewage treatment, and in particular relates to a zero-valent iron reduction-Fenton oxidation integrated device and a method for treating nitroaromatic compound wastewater by using the device. Background technique [0002] Zero-valent iron reduction technology and Fenton oxidation technology are two typical chemical wastewater pretreatment technologies, which are often used separately or simultaneously in the design of wastewater treatment processes, which can achieve better treatment effects. When the zero-valent iron reduction technology and the Fenton oxidation technology are used at the same time, the zero-valent iron reduction reaction device and the Fenton oxidation reaction device are usually connected in series to achieve the purpose of reducing the biological toxicity of wastewater and improving the biodegradability of wastewater, thereby creating a new environment for subsequent biochemical proces...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F9/04C02F101/38
Inventor 沈锦优王连军刘建国欧昌进张帅孙秀云李健生刘晓东韩卫清
Owner NANJING UNIV OF SCI & TECH
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