Machinable silica aerogel composite rigid thermal insulating tile and preparation method thereof
A technology of silica aerogel and silica sol, which is applied in chemical instruments and methods, hydraulic material layered products, layered products, etc. The weight of the thermal tile and the hidden safety hazards are not easy to solve, and the effects of scientific and reasonable preparation method, low cost and improved storage capacity are achieved.
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Embodiment 1
[0035] First measure 20 moles of ethanol, add 5 moles of tetraethyl orthosilicate and 30 moles of deionized water while stirring, after mixing evenly, add 0.002 moles of hydrochloric acid and continue stirring to obtain silica sol; The tiles were dried and weighed for degassing treatment, and then all the prepared sol was filled into the rigid insulation tiles by negative pressure, and the pressure was maintained for 10 minutes, and 0.004 moles of ammonia water was added, and the gel was formed after standing at 50°C for 6 hours. Then add 3 liters of ethanol solvent, so that the gelled material is completely immersed in the ethanol solvent for aging treatment, the aging time is 24 hours; add 3 liters of 10% n-hexane solution of trimethylchlorosilane for hydrophobic treatment , treated for 2 days, and then the gel was cleaned with 3 liters of n-hexane solution each time until the pH of the cleaning solution was 6.5; the rigid insulation tile was taken out from the gel and dried ...
Embodiment 2
[0038] First measure 50 moles of ethanol, add 5 moles of tetraethyl orthosilicate and 15 moles of deionized water while stirring, after mixing evenly, add 0.001 moles of hydrochloric acid and continue stirring to obtain silica sol; The tiles were dried and weighed for degassing, and then all the prepared sol was filled into the inside of the rigid insulation tiles by negative pressure, and the pressure was maintained for 10 minutes, and 0.005 moles of ammonia water was added, and the gel was formed after standing at 50°C for 6 hours. Then add 4.5 liters of ethanol solvent, so that the gelled material is completely immersed in the ethanol solvent for aging treatment, the aging time is 24 hours; add 4.5 liters of 10% trimethylchlorosilane n-hexane solution for hydrophobic treatment, Treat for 2 days, and then wash the gel with 4.5 liters of n-hexane solution each time until the pH of the cleaning solution is 6.5; take out the rigid insulation tile from the gel and dry it at room ...
Embodiment 3
[0041]First measure 400 moles of ethanol, add 50 moles of tetraethyl orthosilicate and 200 moles of deionized water while stirring, after mixing evenly, add 0.01 moles of hydrochloric acid and continue stirring to obtain silica sol; After the tile is dried and weighed, it is degassed, and then the prepared sol is filled into the inside of the rigid insulation tile by negative pressure, and the pressure is kept for 10 minutes, and 0.05 mole of ammonia water is added, and the gel is formed after standing at 50°C for 6 hours. Then add 40 liters of ethanol solvent to make the gelled material completely immersed in ethanol solvent for aging treatment, the aging time is 24 hours; add 40 liters of 10% trimethylchlorosilane n-hexane solution for hydrophobic treatment, Treat for 2 days, and then wash the gel with 40 liters of n-hexane solution each time until the pH of the cleaning solution is 6.5; take out the rigid insulation tile from the gel and dry it at room temperature for 24 hou...
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