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Antibacterial and anti-mildew plastic-wood composite material board and preparation method thereof

A wood-plastic composite material, antibacterial and anti-mildew technology, applied in the field of plastic-wood composite materials, can solve the problems of material mechanical performance degradation, plastic-wood composite material mildew, shortened service life, etc., to reduce the cost of raw materials and low production costs , The effect of reducing the amount of plastic

Active Publication Date: 2017-01-25
安徽福美达新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, because the wood-plastic composite material is filled with a large amount of plant fibers, although the plant fibers are covered by plastic and acted on by coupling agents or compatibilizers, they are not as easy to be infected by mold and wood rot fungi as pure plant fibers, but when When it is wet in rainy days or the ground is soaked in water, the wood-plastic composite material can still provide a good living environment for fungi, causing the wood-plastic composite material to mildew, and the mechanical properties of the material will gradually decline, or even rot, greatly shortening its service life
At the same time, mildew will cause mold spots visible to the naked eye on the surface of wood-plastic composite materials, which will affect its appearance.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC: tap water is 1:500. Dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 25 minutes, dehydrated and dried, and sieved to obtain modified wood flour.

[0051](2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 1.5:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 3 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:7:1.1, heat up to 65°C, and after 8 hours of reaction, crush the product, extract the product with toluene for 72 hours, and then dry the product under va...

Embodiment 2

[0066] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC: tap water is 1:500. Dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 20 minutes, dehydrated and dried, and sieved to obtain modified wood flour.

[0067] (2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 1:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 2 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:4:0.8, raise the temperature to 60°C, and after reacting for 6 hours, crush the product, extract the product with toluene for 48 hours, and then vacuum dry...

Embodiment 3

[0082] (1) Weigh the wood powder and the wood preservative dimethyldidecylammonium chloride DDAC according to the weight ratio of 100:1. The weight ratio of DDAC: tap water is 1:500. Dilute DDAC with tap water, and then put the wood powder in into the diluent, ultrasonically treated for 30 minutes, dehydrated and dried, and sieved to obtain modified wood flour.

[0083] (2) Weigh γ-methacryloxypropyltrimethoxysilane, tap water and nano-zinc oxide at a weight ratio of 2:10:100, and mix γ-methacryloxypropyltrimethoxysilane After mixing with water, spray evenly on the surface of nano-zinc oxide, then reflux reaction in toluene solution for 4 hours, and filter under reduced pressure to obtain modified nano-zinc oxide, then add styrene, modified nano-zinc oxide and benzoyl peroxide Mix evenly according to the weight ratio of 100:10:1.4, heat up to 70°C, and after 10 hours of reaction, crush the product, extract the product with toluene for 96 hours, then dry the product under vacuu...

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Abstract

The invention discloses an antibacterial anti-mildew plastic and wood composite material plate and a preparation method thereof. The plate is prepared from modified wood flour, plastic, maleic anhydride grafted plastic, graft modified nanometer zinc oxide, activated calcium carbonate, calcium stearate, terpene resin and an antioxidant. The preparation method comprises the steps that the wood flour is modified by using dimethyl dodecyl ammonium chloride; nanometer zinc oxide is treated by using gamma-methacryloxypropyl trimethoxy silane and subsequently subjected to graft modification by using styrene; calcium carbonate is activated by using polyethylene glycol; the plastic, the maleic anhydride grafted plastic, calcium stearate, graft modified nanometer zinc oxide and the terpene resin are stirred and extruded to obtain modified plastic; the modified plastic, the modified wood flour, activated calcium carbonate and the antioxidant are stirred, melted, co-mixed and extruded to form the plate. The antibacterial anti-mildew plastic and wood composite material plate disclosed by the invention is convenient to produce and manufacture, low in production cost, friendly to environment, high in modulus, large in rigidity, resistant to creep deformation and excellent in antibacterial and anti-mildew performances.

Description

technical field [0001] The invention relates to the technical field of plastic-wood composite materials, in particular to an antibacterial and anti-mildew plastic-wood composite material board and a preparation method thereof. Background technique [0002] In recent years, a kind of green environmental protection fiber powder mainly made of wood powder, rice bran powder and other plant fiber powder as the basic material, thermoplastic polymer material (plastic) and processing aids, etc., mixed evenly and then heated and extruded by mold equipment. Materials, that is, wood-plastic composite materials are getting more and more attention. It can be made into automotive interior decoration parts, building templates, outdoor tables and chairs, garden handrails and decorative panels, open floors, waste bins, railways, etc. Sleepers, corridor panels, window and door panels, concrete cement formwork, etc. used in the construction industry. Wood-plastic composite materials have many...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L97/02C08L23/06C08L23/12C08L25/06C08L51/06C08K13/06C08K9/08C08K9/06C08K3/22C08K3/26C08K5/098B29C47/92B29C48/92
Inventor 余旺旺
Owner 安徽福美达新材料科技有限公司
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