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Antistatic polyamide composite material and preparation method thereof

A composite material and polyamide technology, which is applied in the field of antistatic polyamide composite materials and its preparation, can solve the problems that antistatic and plasticizing and toughening cannot be realized at the same time, and achieve good antistatic effect and strong mechanical properties

Active Publication Date: 2015-01-28
SUZHOU POLYMER NEW MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The antistatic effect of the composition is improved by directly adding an antistatic agent, and increasing the relative content of the antistatic agent reduces the content of other raw materials, so that antistatic and plasticizing and toughening cannot be achieved at the same time.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Antistatic polyamide composite material, including the following raw materials in parts by weight: 40 parts of polyamide, 20 parts of polyphenylene sulfide, 20 parts of polyvinylpyridine, 30 parts of polyimide, 40 parts of calcium acetate, 20 parts of carbon black , 20 parts of sulfur, 30 parts of barium sulfate, 4 parts of toluene diisocyanate, 10 parts of stabilizer, 10 parts of titanium dioxide, and 40 parts of resin.

[0024] The stabilizer is sodium stearate.

[0025] The particle size of titanium dioxide is 5 microns.

[0026] The resin is phenolic resin.

[0027] The preparation method of antistatic polyamide composite material comprises the following steps:

[0028] (1) Add polyamide, polyphenylene sulfide and polyvinylpyridine into the reaction kettle, stir evenly and heat up to 115°C;

[0029] (2) Add polyimide, calcium acetate, carbon black, and sulfur within 15 minutes, and heat up to 200°C for 1 hour;

[0030] (3) Add barium sulfate, toluene diisocy...

Embodiment 2

[0033] Antistatic polyamide composite material, including the following raw materials in parts by weight: 50 parts of polyamide, 30 parts of polyphenylene sulfide, 30 parts of polyvinylpyridine, 80 parts of polyimide, 60 parts of calcium acetate, 30 parts of carbon black , 70 parts of sulfur, 60 parts of barium sulfate, 15 parts of toluene diisocyanate, 30 parts of stabilizer, 30 parts of titanium dioxide, and 90 parts of resin.

[0034] The stabilizer is sodium benzoate.

[0035] The particle size of titanium dioxide is 8 microns.

[0036] The resin is diallyl phthalic aldehyde resin.

[0037] The preparation method of antistatic polyamide composite material comprises the following steps:

[0038] (1) Add polyamide, polyphenylene sulfide and polyvinylpyridine into the reaction kettle, stir evenly and heat up to 120°C;

[0039] (2) Add polyimide, calcium acetate, carbon black, and sulfur within 45 minutes, and heat up to 250°C for 2 hours;

[0040] (3) Add barium sulfa...

Embodiment 3

[0043] Antistatic polyamide composite material, including the following raw materials in parts by weight: 45 parts of polyamide, 25 parts of polyphenylene sulfide, 25 parts of polyvinylpyridine, 50 parts of polyimide, 50 parts of calcium acetate, 25 parts of carbon black , 50 parts of sulfur, 40 parts of barium sulfate, 10 parts of toluene diisocyanate, 20 parts of stabilizer, 20 parts of titanium dioxide, and 70 parts of resin.

[0044] The stabilizer is sodium stearate.

[0045] The particle size of titanium dioxide is 7 microns.

[0046] The resin is a silicone resin.

[0047] The preparation method of antistatic polyamide composite material comprises the following steps:

[0048] (1) Add polyamide, polyphenylene sulfide and polyvinylpyridine into the reaction kettle, stir evenly and heat up to 118°C;

[0049] (2) Add polyimide, calcium acetate, carbon black, and sulfur within 25 minutes, and heat up to 230°C for 1.5 hours;

[0050](3) Add barium sulfate, toluene di...

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Abstract

The invention discloses an antistatic polyamide composite material and a preparation method thereof. The antistatic polyamide composite is prepared from the following raw materials in parts by weight: 40-50 parts of polyamide, 20-30 parts of polyphenylene sulfide, 20-30 parts of poly (4-vinylpyridine), 30-80 parts of polyimide, 40-60 parts of calcium acetate, 20-30 parts of carbon black, 20-70 parts of sulfur, 30-60 parts of barium sulfate, 4-15 parts of toluene diisocyanate, 10-30 parts of stabilizer, 10-30 parts of titanium dioxide and 40-90 parts of resin. The preparation method comprises the following steps: adding polyamide, polyphenylene sulfide and polyvinyl pyridine in a reaction kettle, uniformly stirring, heating, and raising the temperature to 115-120 DEG C; adding polyimide, calcium acetate, carbon black and sulfur within 15-45min, raising temperature to 200-250 DEG C, and reacting for 1-2h; adding the rest of components, uniformly mixing, and carrying out extrusion pelletizing. The antistatic polyamide composite has surface resistance of 3.2*10<6>-3.8*10<6> omega and arc resistance of 120-125s and also has good antistatic effect.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to an antistatic polyamide composite material and a preparation method thereof. Background technique [0002] Polyamide, the English name is polyamide, referred to as PA. Commonly known as nylon (Nylon), it is the variety with the largest output, the largest variety and the widest application among the five major engineering plastics. The main varieties of nylon are nylon 6 and nylon 66, which occupy an absolute dominant position. Nylon 6 is polycaprolactam, while nylon 66 is polyhexamethylene adipate. Nylon 66 is 12% harder than nylon 6; followed by nylon 11, Nylon 12, nylon 610, nylon 612, and nylon 1010, nylon 46, nylon 7, nylon 9, nylon 13, new varieties include nylon 6I, nylon 9T and special nylon MXD6 (barrier resin), etc., nylon modification Variety. The main varieties are nylon 6, nylon, nylon 11, nylon 12, nylon 610, nylon 612, nylon 4fi, nylon 1010, etc. A...

Claims

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Application Information

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IPC IPC(8): C08L61/06C08L83/04C08L27/12C08L79/08C08L77/00C08L81/02C08L39/08C08K13/02C08K5/098C08K3/04C08K3/30C08K3/22
Inventor 翟红波杨振枢韦洪屹
Owner SUZHOU POLYMER NEW MATERIALS TECH
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