Preparation method of environment-friendly adhesive
An adhesive, environmentally friendly technology, applied in the direction of adhesives, adhesive types, graft polymer adhesives, etc., can solve the problems of mildew, affect the appearance and use, unavoidable formaldehyde, etc., to increase the sterilization. and mildew resistance, good stability and dispersibility, and the effect of preventing the binder from falling off
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Embodiment 1
[0040] Preparation of nano silver:
[0041] (1) Add sodium dodecyl sulfonate solution, water-based polyacrylate and hydrazine hydrate solution to silver nitrate aqueous solution to obtain a mixed solution. The molar ratio of sodium dodecyl sulfonate to silver nitrate is 4:1; water-based The molar ratio of polyacrylate to silver nitrate is 0.4:1; the molar ratio of hydrazine hydrate to silver nitrate is 0.2:1;
[0042] (2) Add dicyclohexyl-18-crown-6 and sodium metaphosphate to the mixture, the molar ratio of dicyclohexyl-18-crown-6 to silver nitrate is 3:1; sodium metaphosphate and The molar ratio of silver nitrate is 0.8:1, and the pH value is controlled to be 8-9 to obtain nano silver.
[0043] The composition ratio of the preparation method of environmental protection adhesive:
[0044] 25 parts of phthalic anhydride, 7 parts of furfuryl alcohol extracted from corncob residue, 10 parts of triethylene glycol, 15 parts of glutaric acid, 8 parts of butanetriol, 5 parts of zi...
Embodiment 2
[0054] Preparation of nano silver:
[0055] (1) Add sodium dodecyl sulfonate solution, water-based polyacrylate and hydrazine hydrate solution to silver nitrate aqueous solution to obtain a mixed solution. The molar ratio of sodium dodecyl sulfonate to silver nitrate is 6:1; The molar ratio of polyacrylate to silver nitrate is 0.6:1; the molar ratio of hydrazine hydrate to silver nitrate is 0.3:1;
[0056] (2) Add dicyclohexyl-18-crown-6 and sodium metaphosphate to the mixture, the molar ratio of dicyclohexyl-18-crown-6 to silver nitrate is 5:1; sodium metaphosphate and The molar ratio of silver nitrate is 1.3:1, and the pH value is controlled to be 8-9 to obtain nano silver.
[0057] The composition ratio of the preparation method of environmental protection adhesive:
[0058] 35 parts of phthalic anhydride, 11 parts of furfuryl alcohol extracted from oat or wheat bran, 12 parts of triethylene glycol, 18 parts of glutaric acid, 10 parts of butanetriol, 7 parts of zinc oxide...
Embodiment 3
[0066] Preparation of nano silver:
[0067] (1) Add sodium dodecyl sulfonate solution, water-based polyacrylate and hydrazine hydrate solution to silver nitrate aqueous solution to obtain a mixed solution. The molar ratio of sodium dodecyl sulfonate to silver nitrate is 5:1; water-based The molar ratio of polyacrylate to silver nitrate is 0.5:1; the molar ratio of hydrazine hydrate to silver nitrate is 0.25:1;
[0068] (2) Add dicyclohexyl-18-crown-6 and sodium metaphosphate to the mixture, the molar ratio of dicyclohexyl-18-crown-6 to silver nitrate is 4:1; sodium metaphosphate and The molar ratio of silver nitrate is 1:1, and the pH value is controlled to be 8-9 to obtain nano silver.
[0069] The composition ratio of the preparation method of environmental protection adhesive:
[0070] 30 parts of phthalic anhydride, 7-11 parts of furfuryl alcohol extracted from bamboo sawdust, 11 parts of triethylene glycol, 16 parts of glutaric acid, 9 parts of butanetriol, 6 parts of z...
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