Additive for chromium-free passivation treatment solution on aluminum and its alloy surface and its application method

A technology of chrome-free passivation and additives, which is applied in the coating process of metal materials, etc., can solve the problems of no automatic repair of the cutting end surface layer, high operation cost, bursting, etc. large span effect

Active Publication Date: 2016-08-24
上海新大余氟碳喷涂材料有限公司
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  • Abstract
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  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But the cut end surface layer of this kind of film has no automatic repair function, the cut end is easy to corrode, so the paint on the end surface is easy to fall off and burst
Therefore, manufacturers with a daily processing capacity of more than 500 square meters generally have high operating costs and difficult control of the conversion film quality, especially the conversion film cutting port does not have an automatic repair function, which ultimately affects the quality of finished products after coating

Method used

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Embodiment Construction

[0030] The specific material components of the additives are as follows: methyltriethoxysilane: 48%; alkyl sulfate: 26%; sodium benzoate: 16%; polyethylene glycol: 10%.

[0031] The using method of additive of the present invention:

[0032] (1) Composition and technical parameters of bath preparation:

[0033] Polyacrylic acid: 11-15 liters / 1000 liters, fluorozirconic acid: 11-13 liters / 1000 liters, additives: 4-8 liters / 1000 liters;

[0034] Free acidity: 9-11ml;

[0035] pH value: between 2.6-2.9;

[0036] Bath temperature: 15-30°C;

[0037] (2) Surface passivation treatment to form a passivation film. When using the spray type, the surface passivation treatment time is 30-120 seconds; when using the immersion type, the surface passivation treatment time is 120-300 seconds.

[0038] The process steps that aluminum and its alloys must undergo surface treatment before painting are:

[0039] (1) Degreasing, (2) Washing, (3) Lighting, (4) Washing with deionized water, (5)...

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Abstract

The invention belongs to the technical field of metal surface treatment, in particular to an additive for a chromium-free passivation treatment solution on the surface of aluminum and its alloys and a method for using the same. The composition of additives includes: coupling agent: methyltriethoxysilane, which can increase the hardness of the network structure film formed by fluorozirconic acid; active agent: alkyl sulfate, which can improve the uniform thickness and smoothness of the converted film; stabilizer : Sodium benzoate, which can prolong the service life of the bath solution; Wetting agent: Polyethylene glycol, which can form hydrophilic groups on the surface of aluminum materials, reduce surface tension, and make the film of network structure more flexible and Dense. The additive can stabilize the passivation solution without being affected by harsh external conditions, facilitate the formation of nano-scale zirconium compound particles in the chromium-free passivation solution, change the density of the grid-like film layer, and increase the automatic repair function of the cutting port. Conducive to the stability of the coating network structure.

Description

technical field [0001] The invention belongs to the technical field of metal surface treatment, and in particular relates to an additive for a chromium-free passivation treatment solution on the surface of aluminum and its alloys and a method for using the same. Background technique [0002] Aluminum and its alloys must undergo surface treatment before painting, and the process steps are: (1) Degreasing; (2) Washing; (3) Lighting; (4) Deionized water washing; (5) Treatment with chrome-free passivation solution; (6) dry. [0003] A colorless corrosion-resistant passivation layer is formed on the aluminum surface by spraying or soaking, but the process requirements are quite strict, such as water temperature, water quality, time, the strength of the airflow stirred with air bubbles, etc., will form on the aluminum surface. The quality of the passivation film is affected, and the passivation film is colorless and cannot be judged by the naked eye, which brings inconvenience to...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C22/34
Inventor 朱美玉朱玉冲陈剑锋邵春华
Owner 上海新大余氟碳喷涂材料有限公司
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