Sandwich tandem pin structure α-irradiated battery and preparation method thereof
A tandem battery technology, applied in the field of microelectronics, can solve the problems of easy introduction of surface defects, low energy conversion rate, large device leakage current, etc., to achieve improved energy utilization rate, improved energy conversion rate, and large band gap Effect
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Embodiment 1
[0048] Embodiment 1, the preparation sandwich radioactive source is Am 241 , a sandwich tandem PIN structure α-irradiated cell with an α-radiation source layer thickness of 4 μm.
[0049] Step 1: Make the upper PIN knot.
[0050] refer to Figure 4 , the implementation of this step is as follows:
[0051] (1a) Clean the p-type SiC substrate to remove surface contaminants such as Figure 4 As shown in (a):
[0052] (1a.1) Set the doping concentration to 8x 10 17 cm -3 The highly doped p-type 4H-SiC substrate in NH 4 OH+H 2 o 2 Soak in the reagent for 10 minutes, take it out and dry it to remove the organic residue on the surface of the sample;
[0053] (1a.2) Use HCl+H on the p-type SiC substrate after removing the surface organic residues 2 o 2 Soak the reagents for 10 minutes, take them out and dry them to remove ionic pollutants.
[0054] (1b) Epitaxial growth of P-type low-doped epitaxial layer, such as Figure 4 (b) as shown:
[0055] An aluminum-doped P-type...
Embodiment 2
[0078] Embodiment 2, the preparation sandwich radioactive source is Am 241 , a sandwich tandem PIN structure α-irradiated cell with an α-radiation source layer thickness of 6 μm.
[0079] Step 1: Make the upper PIN knot.
[0080] refer to Figure 4 , the implementation of this step is as follows:
[0081] 1a) cleaning the p-type SiC substrate to remove surface contaminants, the doping concentration of the p-type SiC substrate is 8x10 17 cm -3 ,Such as Figure 4 As shown in (a):
[0082] This step is the same as step (1a) of Embodiment 1.
[0083] 1b) Epitaxial growth of P-type low-doped epitaxial layer, such as Figure 4 (b) as shown:
[0084] An aluminum-doped P-type doped epitaxial layer is epitaxially grown on the cleaned p-type SiC substrate by chemical vapor deposition CVD. The process conditions are as follows: the epitaxy temperature is 1550°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, the impurity source i...
Embodiment 3
[0102] Embodiment 3, preparation of sandwich radioactive source α is Pu 238 , a sandwich tandem PIN structure α-irradiated battery with a radioactive source layer thickness of 8 μm.
[0103] Step A: Make the upper PIN knot.
[0104] refer to Figure 4 , the implementation of this step is as follows:
[0105] A1) Clean the p-type SiC substrate to remove surface pollutants, the doping concentration of the p-type SiC substrate is 8×10 17 cm -3 ,Such as Figure 4 (a).
[0106] This step is the same as step (1a) of Embodiment 1.
[0107] A2) Epitaxial growth of P-type low-doped epitaxial layer, such as Figure 4 (b).
[0108] An aluminum-doped P-type doped epitaxial layer is epitaxially grown on the cleaned p-type SiC substrate by chemical vapor deposition CVD. The process conditions are: the epitaxy temperature is 1550°C, the pressure is 100mbar, the reaction gas is silane and propane, the carrier gas is pure hydrogen, the impurity source is trimethylaluminum, and the alu...
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