A kind of thermally conductive plastic using modified carbon material and preparation method thereof
A technology of thermally conductive plastics and modified carbon, applied in thermally conductive plastics and their preparation, thermally conductive plastics using modified carbon materials and their preparation fields, can solve the effect of changing the surface properties of carbon fibers, fully mixing nano-carbon materials, and thermally conducting plastics Excellent effect and other problems, to achieve the effect of improving compatibility, uniform internal structure and low cost
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Embodiment 1
[0038] a. Preparation of modified carbon material: mix water: graphite: sodium chloride: surfactant: silane coupling agent at a mass ratio of 100:1:1:0.5:1 at room temperature to form a premix, and then put it into an ultrasonic Ultrasonic is carried out in the ultrasonic frequency range of 250W in the cleaner, polycationic polymer is slowly added during the ultrasonic process, and the ultrasonic is continued for 45 minutes, then stirred for 20 hours, and then filtered and dried to obtain the modified carbon material;
[0039] b. Preparation of heat-conducting plastics using modified carbon materials: 30% of the modified carbon materials prepared in step a, 20% of magnesium oxide, 15% of boron nitride, 30% of the main plastic, 1% of polyanionic polymers, After blending 2% of the dispersant and 2% of the silane coupling agent, extrude and granulate with a twin-screw extruder at an extrusion temperature of 200-210°C and a melt processing torque of 70N·m.
Embodiment 2
[0041] a. Preparation of modified carbon material: mix water: carbon black: sodium chloride: surfactant: silane coupling agent at a mass ratio of 100:1:1:0.5:1 at room temperature to form a premix, and then put Ultrasonic in the ultrasonic cleaner within the ultrasonic frequency range of 300W, slowly add polycationic high polymer during the ultrasonic process, continue to ultrasonic for 30min, then stir for 24h, then filter and dry to obtain the modified carbon material;
[0042] b. Preparation of heat-conducting plastics using modified carbon materials: 20% of the modified carbon materials prepared in step a, 15% of magnesium oxide, 20% of boron nitride, 39% of the main plastic, 2% of polyanionic polymers, After blending 3% of the dispersant and 1% of the silane coupling agent, extrude and granulate with a twin-screw extruder at an extrusion temperature of 220-230°C and a melt processing torque of 60N·m.
Embodiment 3
[0044] a. Preparation of modified carbon material: Mix water: carbon fiber: sodium chloride: surfactant: silane coupling agent at a mass ratio of 100:1:1:0.5:1 at room temperature to form a premix, and then put it into an ultrasonic Ultrasonic is carried out in the cleaning device within the ultrasonic frequency range of 200W. During the ultrasonic process, polycationic high polymer is slowly added, and the ultrasonic is continued for 60 minutes, then stirred for 22 hours, and then filtered and dried to obtain the modified carbon material;
[0045] b. Preparation of heat-conducting plastics using modified carbon materials: 20% of the modified carbon materials prepared in step a, 25% of magnesium oxide, 15% of boron nitride, 30% of the main plastic, 3% of polyanionic polymers, After blending 5% of the dispersant and 2% of the silane coupling agent, it can be extruded and granulated by a twin-screw extruder under the conditions of an extrusion temperature of 240-250° C. and a mel...
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