Flame-retardant ceramic silicone rubber and preparation method thereof
A technology of vitrified silicone rubber and silicone rubber, which is applied in the field of rubber, can solve the problems of cumbersome and complicated laying and installation, short circuit of lines, fluorine content, etc., and achieve the effects of improving the reaction speed of preparation, reducing sintering temperature and reducing production cost
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[0063] There are two preparation methods for the flame-retardant ceramicized silicone rubber of this embodiment. The first preparation method includes the following steps:
[0064] ① 100 parts of said silicone rubber, 1-100 parts of silica, 0-30 parts of silicone oil, platinum complex and / or platinum compound are calculated as 0.00001-10 parts of platinum, 0-10 parts of coupling agent, flame retardant 1~100 parts of agent are mixed in a kneader;
[0065] ② Vacuum the kneader, keep the vacuum at -0.1~-0.04Mpa, and keep the temperature at 100~200℃;
[0066] ③Add 1 to 150 parts of porcelain powder to the kneader to mix the porcelain powder with the mixed silicone rubber, silicon dioxide, silicone oil, platinum complex and / or platinum compound, coupling agent, and flame retardant Homogeneous, ceramized rubber formed into a lump;
[0067] ④ Remove the ceramized rubber in the form of a dough from the kneader and cool it;
[0068] ⑤After cooling, the ceramized rubber is smelted on an open mi...
Embodiment 1
[0090] Take 100 parts of dimethyl silicone rubber (MQ), 20 parts of silicon dioxide, 1 part of methyl silicone oil, 0.01 part of 1000 ppm isopropanol solution of chloroplatinic acid, 0.1 part of KH560 coupling agent, 20 parts of red phosphorus, 20 parts 1 part of aluminum oxide, according to the first preparation method of the above-mentioned flame-retardant ceramic silicone rubber to prepare the flame-retardant ceramic silicone rubber. When the flame-retardant ceramic silicone rubber is vulcanized and molded, add 1 part of 2,5-dimethyl ~2,5~Bis(tert-butylperoxy)hexane.
Embodiment 2
[0092] Take 100 parts of methyl vinyl silicone rubber (VMQ), 100 parts of silica, 30 parts of hydroxy silicone oil, 10 parts of 1000ppm chloroplatinic acid in isopropanol, 0.1 part of A171 coupling agent, 100 parts of red phosphorus, 150 parts of silicon dioxide were prepared according to the first preparation method of the above-mentioned flame-retardant ceramic silicone rubber. When the flame-retardant ceramic silicone rubber was vulcanized and molded, 2 parts of 2,4-dichloride were added. Benzoyl oxide (commonly known as double to two four).
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