Humic acid composite material and preparation method thereof

A composite material and humic acid technology, applied in the field of humic acid composite material and its preparation, can solve the problems of complicated processing process, high cost, low utilization rate of humic acid, etc., and achieve the effect of broad industrial application prospect and convenient processing.

Inactive Publication Date: 2013-10-23
SOUTH CHINA UNIV OF TECH +1
View PDF3 Cites 7 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The above methods all react humic acid monomers with other active monomers under specific conditions to make polymer materials. Although the product value is high, the utilization rate of humic acid is low, and the processing process is cumbersome and costly.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Humic acid composite material and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A; soil humic acid, polylactic acid, and polybutylene succinate are dried, the drying temperature is 80°C, and the drying time is 5 hours;

[0024] B: Glycerin, phthalates, 2,6-di-tert-butyl-4-methylphenol and soil humic acid, polylactic acid, and polybutylene succinate after drying in step A were dried Stir evenly in a high-speed mixer, and then put it into an internal mixer for blending. The blending temperature is 160 ° C, the rotor speed is 60 rpm, and the blending time is 8 minutes to obtain a solid mixture; wherein the weight percentage of each component is as follows : Soil humic acid content is 40%, polylactic acid content is 30%, polybutylene succinate content is 21.5%, glycerin content is 5%, epoxy fatty acid ester content is 3%, 2,6-diol The content of tert-butyl-4-methylphenol is 0.5%;

[0025] C: The solid mixture is subjected to hot-compression composite molding on a hot press: the temperature is 160° C., the pressure is 15 MPa, and the time is 6 minutes ...

Embodiment 2

[0027] A; Coal sodium humate and polypropylene are dried, the drying temperature is 90°C, and the drying time is 4 hours;

[0028] B: Combine isocyanate crosslinking agent, aliphatic dibasic acid esters, stearic acid, β-(3,5-di-tert-butyl-4-hydroxyphenyl) propionate n-octadecyl alcohol with step A The dried coal sodium humate and polypropylene are stirred evenly in a dry high-speed mixer, and then put into an internal mixer for blending. The blending temperature is 180°C, the rotor speed is 50rpm, and the blending time is 25 minutes. , to obtain a solid mixture; wherein the weight percentages of each component are as follows: the content of coal sodium humate is 60%, the content of polypropylene is 16%, the content of isocyanate crosslinking agent is 8%, and the content of aliphatic dibasic acid esters The content of stearic acid is 7%, the content of stearic acid is 8%, and the content of β-(3,5-di-tert-butyl-4-hydroxyphenyl) n-octadecyl propionate is 1%;

[0029] C: The sol...

Embodiment 3

[0031] A: Drying bio-fermented humic acid, acrylonitrile / butadiene / styrene copolymer, polycarbonate, and polyamide, the drying temperature is 55°C, and the drying time is 12 hours;

[0032]B: Combine citrates, oleamide, N,N'-bis-(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionyl)hexamethylenediamine with the dried Biologically fermented humic acid, acrylonitrile / butadiene / styrene copolymer, polycarbonate, and polyamide are stirred evenly in a dry high-speed mixer, and then put into an internal mixer for blending. The blending temperature is 230°C, and the rotor The rotation speed was 140rpm, and the blending time was 5 minutes to obtain a solid mixture; wherein the weight percentages of each component were as follows: the content of bio-fermented humic acid was 30%, and the content of acrylonitrile / butadiene / styrene copolymer was 25%. , the polycarbonate content is 20%, the polyamide content is 15.5%, the citrate content is 3%, the oleamide content is 5%, N, N'-bis-(3-(3,5-di-ter...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention provides a humic acid composite material and a preparation method thereof. The humic acid composite material is formed by mixing of the following components by weight: 1%-60% of humic acid, 10%-99% of a polymer, 0%-10% of a compatibilizer, 0%-10% of a plasticizer, 0%-12% of a lubricant, and 0%-1.5% of an antioxidant. In the invention, the abundant and cheap renewable degradable biological resource humic acid is adopted as a substrate, at least one polymer is compounded, and melt blending of the polymer is conducted to form the composite material. Therefore, the application scope of humic acid is broadened, its utilization rate is enhanced, and insufficiency of petroleum based polymer resources is relieved, so that the humic acid composite material has broad industrial application prospects. With a low production cost, the humic acid composite material provided in the invention has mechanical properties meeting the requirements of actual use and is degradable.

Description

technical field [0001] The invention belongs to the technical field of biomass composite polymer materials, and in particular relates to a humic acid composite material and a preparation method thereof, which expands the application field of humic acid. Background technique [0002] Humic acid is a kind of amorphous and multi-molecular-weight biomass macromolecule widely present in soil, river mud, marine sediment, peat, weathered coal and lignite. The complex and stable heterogeneous organic matter formed by copolymerization with amino acids is a rich and cheap renewable and degradable biological resource. As an organic raw material, humic acid is widely used in various fields such as agriculture, forestry, animal husbandry, petroleum, chemical industry, building materials, medicine, sanitation, and environmental protection. The main products developed in China include fertilizers, pesticides, veterinary drugs, drought-resistant agents, feed additives; pharmaceuticals, hea...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/04C08L67/02C08L23/12C08L55/02C08L69/00C08L3/02C08L99/00
Inventor 瞿金平陈福泉刘环裕赵永青冯彦洪
Owner SOUTH CHINA UNIV OF TECH
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic.

© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap