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Fabrication method of gate dielectric layer, fabrication method of transistor

A fabrication method and gate dielectric layer technology are applied in the field of transistor fabrication and gate dielectric layer fabrication, which can solve the problem of poor interface characteristics, affecting the interface properties between the interface layer and the high-k gate dielectric layer, affecting the electrical performance and reliability of transistors, etc. problem, to achieve the effect of improving interface characteristics

Active Publication Date: 2016-03-16
SEMICON MFG INT (SHANGHAI) CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The interface layer formed by the thermal growth method has better quality, but its disadvantages are: the high-k gate dielectric layer is difficult to nucleate on its surface and the coverage on its surface is low, resulting in the interface layer and the high-k gate dielectric There is a large amount of interface charge between the layers, which affects the interface characteristics between the interface layer and the high-k gate dielectric layer
The surface of the interface layer formed by the chemical growth method has a large number of OH bonds, which facilitates the growth of the high-k gate dielectric layer and improves the coverage of the high-k gate dielectric layer, but its disadvantages are: the quality of the interface layer is not good, and The interface characteristics between the interface layer and the substrate are poor, resulting in a large amount of interface charge between the substrate and the interface layer
[0007] It can be seen that the existing gate dielectric layer manufacturing methods cannot simultaneously have the advantages of good interface layer quality, good interface characteristics between the interface layer and the substrate, and between the interface layer and the high-k gate dielectric layer, so as to affect the electrical performance of the transistor. and reliability

Method used

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  • Fabrication method of gate dielectric layer, fabrication method of transistor
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Embodiment 1

[0047] figure 1 It is the fabrication flowchart of the gate dielectric layer in Embodiment 1 of the gate dielectric layer fabrication method of the present invention, as shown in figure 1 As shown, the method includes:

[0048] Step S100: removing natural oxides on the surface of the substrate.

[0049] Step S110: forming an interface layer made of silicon oxide or silicon oxynitride on the substrate by thermal growth method.

[0050] Step S120: Using the 3 or contain H 2 SO 4 、H 2 o 2 The aqueous solution of the interface layer is subjected to the first surface treatment.

[0051] Step S130: forming a high-k gate dielectric layer on the interface layer.

[0052] Combine below figure 1 The method for fabricating the gate dielectric layer of the present invention will be described in detail.

[0053] execute first figure 1 Step S100 in: removing the native oxide on the surface of the substrate.

[0054] When the substrate is exposed to air, the surface of the substr...

Embodiment 2

[0070] figure 2 It is the fabrication flowchart of the gate dielectric layer in Embodiment 2 of the gate dielectric layer fabrication method of the present invention, as shown in figure 2 As shown, the method includes:

[0071] Step S200: removing natural oxides on the surface of the substrate.

[0072] Step S210: forming an interface layer made of silicon oxide or silicon oxynitride on the substrate by thermal growth method.

[0073] Step S220: forming a high-k gate dielectric layer on the interface layer, and in the process of forming the high-k gate dielectric layer, using 3 or contain H 2 SO 4 、H 2 o 2 The aqueous solution of the high-k gate dielectric layer is subjected to the second surface treatment.

[0074] Combine below figure 2 The method for fabricating the gate dielectric layer of the present invention will be described in detail.

[0075] execute first figure 2 Step S200 in: removing the natural oxide on the surface of the substrate.

[0076] When ...

Embodiment 3

[0094] image 3 It is the fabrication flowchart of the gate dielectric layer in Embodiment 3 of the gate dielectric layer fabrication method of the present invention, as shown in image 3 As shown, the method includes:

[0095] Step S300: removing natural oxides on the surface of the substrate.

[0096] Step S310: forming an interface layer made of silicon oxide or silicon oxynitride on the substrate by thermal growth method.

[0097] Step S320: Using the 3 or contain H 2 SO 4 、H 2 o 2 The aqueous solution of the interface layer is subjected to the first surface treatment.

[0098] Step S330: forming a high-k gate dielectric layer on the interface layer, and in the process of forming the high-k gate dielectric layer, using 3 or contain H 2 SO 4 、H 2 o 2 The aqueous solution of the high-k gate dielectric layer is subjected to the second surface treatment.

[0099] Combine below image 3 The method for fabricating the gate dielectric layer of the present invention ...

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Abstract

The invention provides a manufacturing method for a gate dielectric layer and a manufacturing method for a transistor. The manufacturing method for the gate dielectric layer comprises the steps that an interface layer is formed on a substrate by the adoption of a thermal growth method; a high-k gate dielectric layer is formed on the interface layer; surface processing is conducted on the interface layer or the high-k gate dielectric layer by the adoption of aqueous solution containing O3 or H2SO4 and H2O2. According to the manufacturing method for the gate dielectric layer and the manufacturing method for the transistor, due to the facts that the best interface layer is formed by the adoption of the thermal growth method, and the surface processing is conducted on the interface layer or the high-k gate dielectric layer by the adoption of the aqueous solution containing O3 or H2SO4 and H2O2, a large number of OH keys which are suitable for improving the coverage rate of the high-k gate dielectric layer are formed on the surface of the interface layer or the high-k gate dielectric layer, the high-k gate dielectric layer can nucleate more easily on the interface layer, and interfacial characterization between the interface layer and the high-k gate dielectric layer is improved.

Description

technical field [0001] The invention belongs to the field of manufacturing semiconductor integrated circuits, and in particular relates to a method for manufacturing a gate dielectric layer. In addition, the invention also relates to a method for manufacturing a transistor. Background technique [0002] Since the 1960s, the integrated circuit manufacturing process has been developing rapidly following Moore's Law. The feature size of CMOS devices has been continuously reduced according to a certain ratio, while its performance and power consumption have been continuously optimized. According to the prediction of ITRS in 2007, after 2009, the EOT (Equivalent Oxide Thickness, equivalent oxide layer thickness) of the gate dielectric layer of high-performance CMOS devices will be reduced to below 1nm. At this size, conventional SiO 2 The gate dielectric material exposes serious problems such as excessive gate leakage current, reduced reliability, and easy diffusion of impuriti...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01L21/283
Inventor 何永根陈勇
Owner SEMICON MFG INT (SHANGHAI) CORP
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