Binding material for filling fine-grain tailings

A technology of cementitious materials and fine-grained tailings, which is applied in the field of mine filling materials, can solve the problems of low cementation and cementation strength of tailings, and achieve the effects of reducing costs, construction investment and maintenance costs, and simple production processes

Active Publication Date: 2014-11-05
SINOSTEEL MAANSHAN INST OF MINING RES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The task of the present invention is to provide a cementitious material for filling fine-grained tailings with low cost and simple construction in view of the above-mentioned problems in the prior art. Tailings and high mud (-10μm content ≥ 30% in materials) tailings are difficult to cement and the cementation strength is not high, so all kinds of tailings can be used as filling aggregates for mine room filling and open-pit mining Backfill reclamation

Method used

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  • Binding material for filling fine-grain tailings
  • Binding material for filling fine-grain tailings
  • Binding material for filling fine-grain tailings

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] Belite-sulfoaluminate cement is compounded according to the ratio of 1:3 between sulfoaluminate cement and ordinary Portland cement, and the components in Example 1 are mixed and ground to obtain a cementitious material. The cementitious materials were subjected to cementation tests with the whole tailings of fine ore and the graded tailings of -200 mesh copper ore respectively. The compressive strengths are shown in Table 2 and Table 3.

[0033] Table 2 Full tailings of fine ore (40% mud content), compressive strength of gel (MPa)

[0034]

[0035] The mortar ratio refers to the mass ratio of the cementitious material of the present invention to the tailings slurry, the same below.

[0036] Table 3 -200 mesh copper ore graded tailings, gel compressive strength (MPa)

[0037]

Embodiment 2

[0039] Belite-sulfoaluminate cement is compounded according to the ratio of 1:3 between sulfoaluminate cement and ordinary Portland cement, and the components in Example 1 are mixed and ground to obtain a cementitious material. The cementitious material was subjected to cementation tests with the whole tailings of powder ore and the graded tailings of -200 mesh copper ore respectively. The compressive strengths are shown in Table 4 and Table 5.

[0040] Table 4 Whole tailings of powder ore (40% mud content), compressive strength of gel

[0041]

[0042] Table 5 -200 mesh copper ore graded tailings, gel compressive strength

[0043]

Embodiment 3

[0045] 25.26% Belite-sulfoaluminate cement (sulfoaluminate cement and ordinary Portland cement are compounded at a ratio of 1:3), 4% anhydrite, 2% quicklime, 60% slag micropowder, 5 % fly ash, 4% sodium silicate, 0.4% sodium fluorosilicate, 0.14% lithium hydroxide, and 0.2% polycarboxylate water reducer are mixed and milled to obtain a gelled material. The cementitious material was subjected to cementation tests with the whole tailings of fine ore and the graded tailings of -200 mesh copper ore respectively. The compressive strengths are shown in Table 6 and Table 7.

[0046] Table 6 Full tailings of fine ore (40% mud content), compressive strength of gel (MPa)

[0047]

[0048] Table 7 -200 mesh copper ore graded tailings, gel compressive strength (MPa)

[0049]

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Abstract

The invention discloses a binding material for filling fine-grain tailings. The binding material is prepared by milling and mixing the following components in percentage by mass: 15-40% of belite-sulphate aluminum cement, 2-10% of gypsum, 2-8% of quick lime, 40-70% of superfine-grain slag powder, 2-10% of coal ash, 1-6% of activating agent, 0.1-0.5% of activating accelerant, 0.1-0.5% of coagulant, and 0.1-0.5% of water reducer, wherein the activating agent is Na2SiO3, the activating accelerant is sodium fluosilicate, and the coagulant is any one or a mixture of two or more of LiOH, LiCO3 and LiCl; and the water reducer is a naphthalene water reducer or a polycarboxylic acid water reducer. According to the binding material for filling the fine-grain tailings, the problems that -0.074-mm fine-grain tailings and high-silt-content tailings are difficultly solidified and are low in strength after being solidified, and the strength of a filling body can meet a strength requirement on cut and fill of a mine on the filling body by using the binding material; the liquidity of slurry can be improved, and roof-contacting performance of the filling body can be improved; and the water retention capacity can be improved, and the water seepage of the slurry is reduced.

Description

technical field [0001] The invention relates to the technical field of mine filling materials, in particular to a cementitious material using whole tailings and fine-grained tailings with a content of -0.074mm ≥ 95% as aggregates. Background technique [0002] With the improvement of people's awareness of environmental protection, non-renewable resources and the continuous development of circular economy, the filling method mining has become the development trend of the mining industry in the future. Goaf filling is an important way to consume a large amount of tailings, reduce tailings discharge, and store up land. This technology prepares concentrated tailings and cementitious materials into filling mortar with a certain concentration and fills it into the goaf, forming a certain Strong filling. [0003] In order to fully recover underground resources, most underground mines adopt multi-step mining in the mining sequence. Therefore, reducing the mine filling cost, improvi...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B7/26
CPCY02P40/10
Inventor 杨晓军徐修平海冰曾申进于先坤徐静
Owner SINOSTEEL MAANSHAN INST OF MINING RES CO LTD
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