A method for manufacturing a base material having gold-coated metallic fine pattern, a base material having gold-coated metallic fine pattern, a printed wiring board, an interposer and a semiconductor device
A printed wiring board and micro-pattern technology, applied in semiconductor devices, metal material coating processes, semiconductor/solid-state device components, etc., can solve problems such as the inability to fully prevent abnormal metal precipitation, and achieve excellent peel strength and prevent abnormality. Excellent effect of precipitation and adhesion
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Embodiment 1
[0279] (Example 1: (a) Treatment, ENEPIG process)
[0280] 1. Preparation of Primer Resin
[0281]In a mixed solvent of dimethylacetamide and methyl ethyl ketone, 31.5 parts by weight of a methoxynaphthalene aralkyl type epoxy resin (manufactured by DIC Corporation, EPICLON HP-5000) as an epoxy resin, as a cyanide 26.7 parts by weight of a novolak-type cyanate ester resin (Primaset PT-30, manufactured by LONZA), 31.5 parts by weight of a polyamide resin (KAYAFLEX BPAM01, manufactured by Nippon Kayaku Co., Ltd.), and imidazole ( Shikoku Chemicals Co., Ltd., CUREZOL 1B2PZ) 0.3 parts by weight, stirred for 30 minutes, and dissolved. Furthermore, 0.2 parts by weight of an epoxysilane coupling agent (manufactured by Unicar Japan, A187) as a coupling agent and spherical fused silica as an inorganic filler (manufactured by Fuso Chemical Industry Co., Ltd., SP-7, average particle diameter 0.75 μm) and 9.8 parts by weight were stirred for 10 minutes using a high-speed stirring device...
Embodiment 2
[0317] (Example 2: (b) treatment, ENEPIG process)
[0318] In the surface treatment process of embodiment 1, do not carry out the surface treatment that uses the liquid medicine that contains nitric acid and chloride ion, after the test piece is immersed in the solution containing KCN of concentration 20g / liter, liquid temperature 25 ℃ for 1 minute, carry out 3 Second water wash (treatment with KCN).
Embodiment 3
[0319] (Example 3: (c) treatment, ENEPIG process)
[0320] In the surface treatment process of Example 1, the surface treatment using a chemical solution containing nitric acid and chloride ions was not performed, and the desmearing treatment using a chemical solution (surface treatment using a solution containing sodium permanganate) was performed as follows.
[0321] (1) Resin surface swelling treatment
[0322] The test piece was immersed in a mixed solution (pH 12) of a commercially available sodium hydroxide solution containing an ethylene glycol-based solvent (Securiganth P preparation solution manufactured by ATOTECH Corporation) at a liquid temperature of 60°C for 2 minutes, and then washed three times with water.
[0323] (2) Resin surface roughening treatment
[0324] After immersing the test piece in a roughening treatment solution containing sodium permanganate (concentrate compact CP preparation solution manufactured by ATOTECH Co., Ltd.) at a liquid temperature ...
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