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Method for producing high-safety caramel color through twice catalytic reaction

A secondary catalysis, high-safety technology, applied in chemical instruments and methods, azo dyes, organic dyes, etc., can solve the problem of high residues of 4-methylimidazole, large amount of reaction catalyst, and high residues of 3-chloropropanol and other problems, to achieve the effect of improving market competitiveness, saving catalyst dosage, and good coloring performance

Active Publication Date: 2014-05-28
QIANHE CONDIMENT & FOOD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

One of the disadvantages of this process is that the amount of reaction catalyst is large, and the residues of sulfur dioxide, ammonium salt, total sulfur, and total nitrogen in the product are high
In addition, a catalytic reaction often requires high pressure or high temperature to make the reaction go smoothly. When the reaction pressure exceeds 0.25 MPa and the temperature exceeds 140 ° C, the decomposition of lipids is accelerated, and more glycerol is produced, which promotes the synthesis of 3-chloropropanol. Formation, resulting in high residue of 3-chloropropanol; at the same time, high temperature causes ammonia and reducing sugar to react to produce 4-methylimidazole, resulting in high residue of 4-methylimidazole

Method used

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  • Method for producing high-safety caramel color through twice catalytic reaction
  • Method for producing high-safety caramel color through twice catalytic reaction
  • Method for producing high-safety caramel color through twice catalytic reaction

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0034] Such as figure 1 As shown, 1 ton of rice is crushed, and the rice crushing fineness is 100 mesh, and then the high-temperature-resistant amylase produced by Novozymes China Biological Co., Ltd. is used, and the optimum temperature is 95-105 degrees, and 1000 grams of crushed rice are added. and spray liquefaction at 103°C, add 900 grams of glucoamylase to the liquefied rice, and saccharify at 58°C for 16 hours. degree or degree of saccharification, the reducing sugar in the saccharification liquid is all counted as glucose, and the percentage of the dry matter is called DE value) ≥ 95% to stop saccharification, and use a plate and frame filter press to filter the saccharified glucose liquid until it is clear Transparent; the filtered solution is concentrated to 70% of the glucose solution on a dry basis through a three-effect concentration equipment, and the first catalytic reaction is performed. Calculated based on the mass ratio to the dry basis, 40% of the catalyst d...

Embodiment 2

[0038]Grind 1 ton of rice with a fineness of 100 meshes, then add 1,000 grams of high-temperature-resistant amylase to the crushed rice, spray and liquefy it at 105°C, and add 900 grams of glucoamylase to the liquefied rice , saccharified at 59°C for 16 hours, when the DE value (the DE value used in industry, also known as glucose value, indicates the degree of hydrolysis or saccharification of starch, all reducing sugars in the saccharification solution are calculated as glucose, the percentage of dry matter called DE value) ≥ 95% to stop saccharification, use plate and frame filter press to filter the saccharified glucose liquid until it is clear and transparent; use the three-effect concentration equipment to concentrate the glucose solution to 72% on a dry basis , carry out the first catalytic reaction, calculated by mass percentage, according to a catalytic reaction, 40% of the catalyst dosage is used to add the catalyst, and then the reaction is carried out by pressurizin...

Embodiment 3

[0040] Grind 1 ton of rice with a fineness of 100 meshes, then add 1,000 grams of high-temperature-resistant amylase to the crushed rice, spray and liquefy it at 107°C, and add 900 grams of glucoamylase to the liquefied rice , saccharified at 60°C for 16 hours, when the DE value (the DE value used in industry, also known as the glucose value, indicates the degree of hydrolysis or saccharification of starch, all the reducing sugars in the saccharification solution are calculated as glucose, the percentage of dry matter The saccharification is terminated after the DE value) ≥ 95%, and the saccharified glucose liquid is filtered with a plate and frame filter press until it is clear and transparent; the filtered solution is concentrated to 74% on a dry basis through a three-effect concentration equipment , carry out the first catalytic reaction, calculated by mass percentage, according to a catalytic reaction, 40% of the catalyst dosage is used to add the catalyst, and then the rea...

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Abstract

The invention relates to a method for producing high-safety caramel color through twice catalytic reaction. The method comprises the following steps of: a, rice pulverization; b, spraying liquefaction; c, diastatic enzyme addition into liquefied rice for saccharification; d, filtering; e, concentration; f, primary catalytic reaction: through being metered by the mass percentage content of dry basis, catalysts accounting for 40 percent of the catalyst consumption are adopted and added in the primary catalytic reaction, then, through the pressurization and temperature rise reaction, the reaction pressure is controlled to a value being smaller than or equal to 0.1 MPa, the temperature is smaller than or equal to 110 DEG C, and the primary catalytic reaction is stopped when the reaction is carried out to reach 60 percent of the total required color rate; g, secondary catalytic reaction: the secondary catalytic reaction is stopped when the reaction is carried out to reach the required color rate; h, cooling; and i, finished product blending. Through the twice catalytic reaction, the reaction temperature and the reaction pressure are reduced, the reaction conditions are milder, the single consumption of steam is reduced, the reaction process and the control are easier and more stable, each ton of products can save 100kg of steam, and the method is favorable for improving the market competitiveness of products.

Description

technical field [0001] The invention relates to a method for producing caramel color in food production, in particular to a method for producing high-safety caramel color by secondary catalytic reaction. Background technique [0002] Caramel color, commonly known as caramel color, is a natural food coloring obtained from sugar substances through caramelization or Maillard reaction. Caramel color is widely used in the preparation of condensed milk, frozen drinks, jams, cocoa products, ready-to-eat cereals, biscuits, prepared meat products, flavored syrups, vinegar, soy sauce, sauces and sauce products, compound seasonings, oyster sauce, fruit and vegetable beverages, prepared wine, Wine, rice wine, beer, jelly and other fields. Caramel color not only has a wide range of applications, but also a huge amount. According to the statistics of the China Colorant Professional Committee, the total output of edible colorants nationwide in 2009 was about 330,000 tons, of which carame...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C12P1/00C12P19/20C12P19/14C09B61/00
Inventor 伍学明徐义
Owner QIANHE CONDIMENT & FOOD CO LTD
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