Ink composition, ink set and image forming method
A technology of ink composition and imaging method, applied in the directions of ink, copy/marking method, heating method, etc., can solve the problems of deterioration of image formability, narrowing of nozzle holes, deviation of ink jetting direction, etc., to achieve high-resolution images, The effect of stable formation and suppression of image defects
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[0068] Regarding the production method of self-dispersing pigments, according to physical treatment (for example, vacuum plasma treatment) or chemical treatment, it can be achieved by chemically bonding (for example, coordination, grafting, etc.) functional groups or molecules containing functional groups to the surface of pigments, etc. To obtain self-dispersing pigments. For example, self-dispersing pigments can be obtained by the method described in JP-A No. 8-3498.
[0069] In addition, commercially available self-dispersing pigments can also be used. Preferable examples thereof include MICROJET series (trade name) produced by Orient Chemical Industries Co., Ltd., and CAB-O-JET series (trade name) produced by Cabot Corporation.
[0070] The self-dispersing pigment is preferably a self-dispersing pigment having a carboxyl group (—COOH) on the surface of the pigment in consideration of improving ink cohesion and scratch resistance by reacting with an aggregating component whe...
Embodiment 1
[0362]
[0363] -Synthesis of water-insoluble polymer 1-
[0364] Add 88 g of methyl ethyl ketone into a 1000 mL three-necked flask equipped with a stirrer and a condenser, and heat to 72° C. in a nitrogen atmosphere. Add dropwise therein by dissolving 0.85g 2,2'-azobis(isobutyrate) dimethyl ester, 60g benzyl methacrylate, 10g methacrylic acid and 30g methyl methacrylate in 50g methyl ethyl ketone The resulting solution was added dropwise over 3 hours. After completion of the dropwise addition, the mixture was allowed to react for an additional 1 hour, and then a solution obtained by dissolving 0.40 g of dimethyl 2,2'-azobis(isobutyrate) in 2 g of methyl ethyl ketone was added thereto. The temperature was raised to 80°C, and the mixture was heated for 4 hours. The resulting reaction solution was precipitated twice in excess hexane, and then the separated resin was dried to obtain 95 g of a water-insoluble polymer 1 .
[0365] pass 1 H-NMR confirmed the composition of the...
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