Adhesive film
An adhesive film and adhesive layer technology, applied in the direction of adhesives, film/sheet adhesives, adhesive products, etc. Small increase in resultant force, small change in adhesive force, and excellent processing suitability
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Embodiment 1
[0130] (Preparation of substrate layer)
[0131] 100 wt% of a homopolypropylene polymer (manufactured by Sumitomo Chemical Co., Ltd.: FLX80E4, tensile modulus: 1500 MPa) was melt-extruded with a 60 mmφ single-screw extruder (L / D: 22.4) to prepare a base layer.
[0132] (Preparation of adhesive layer)
[0133] Olefin-based elastomer (manufactured by Mitsubishi Chemical: Zealous MC707) 98wt%, heat stabilizer masterbatch (MB) 2wt% containing 50000ppm Irganox1076 were melt-extruded with a 45mmφ twin-screw extruder (L / D: 19) to produce became the adhesive layer.
[0134] (production of release layer)
[0135] 50 wt% of propylene-ethylene block copolymer (POLYPRO BC3HF in Japan) and 50 wt% of propylene-ethylene random copolymer (manufactured by Sumitomo Chemical: WF836DG3) were melt-extruded with a 65mmφ single-screw extruder (L / D: 25), A release layer was made.
[0136] (film production)
[0137] In the state where the base material layer, the adhesive layer, and the release l...
Embodiment 2
[0140] In addition to making the resin of the substrate layer propylene-1-butene copolymer (manufactured by Sumitomo Chemical: SPX78J1, tensile modulus: 530MPa) 50wt% and a homopolypropylene polymer (manufactured by Sumitomo Chemical: FLX80E4, tensile modulus : 1500 MPa) Except for 50 wt%, a film was produced in the same manner as in Example 1. The film also forms a smooth adhesive layer, has adhesiveness at room temperature, does not have uneven contact between the adherend and the adhesive layer, and has a small increase in the adhesive force after sticking to the adherend. Excellent, no blocking between the release layer and the adhesive layer, and a film with good handling properties.
Embodiment 3
[0142] The production of the base material layer and the release layer was the same as in Example 1. The adhesive layer and film were fabricated as follows. The film also forms a smooth adhesive layer, has adhesiveness at room temperature, does not have uneven contact between the adherend and the adhesive layer, and has a small increase in the adhesive force after sticking to the adherend. Excellent, no blocking between the release layer and the adhesive layer, and a film with good handling properties.
[0143] (adhesive layer)
[0144] Amorphous PP (manufactured by Sumitomo Chemical: Tafcelene H3522A, heat of crystallization fusion and heat of crystallization: 28 J / g) and homopolypropylene resin (manufactured by Sumitomo Chemical: FLX80E4, tensile modulus: 1500 MPa) were mixed at 50 / 50 wt % The ratio is mixed, and the product is melt-extruded with a 45mmφ twin-screw extruder (L / D: 19) to make an adhesive layer.
[0145] (film production)
[0146]In the state where the bas...
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